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An Electric Circuit Analogy Model for Analyzing the Relation Between CO and H2 in Interfacial Reduction Reactions

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Metallurgical and Materials Transactions B Aims and scope Submit manuscript

Abstract

Clean energies are promising alternatives to fossil fuels in the steel industry to reduce carbon dioxide (CO2) emissions and consequently suppress global warming. The first step for achieving the goal is to partially replace carbon monoxide (CO) by hydrogen (H2) in the iron oxide reduction reactions. Therefore, the competitive interaction between the CO and H2 in gas–solid reactions should be first unraveled. The gaseous reduction experiments in this work employ CO, H2, and their mixture to reduce the wustite (FeO) when the interfacial chemical reaction is the rate-controlling step. We establish an electric circuit analogy model to clarify the gaseous components’ interaction based on experimental kinetics analysis, and a linear relation is highlighted and further validated to model gaseous reduction reaction rates under present experimental conditions. The results are expected to provide quantitative insight into the competitive interaction between gaseous components in the reduction process controlled by the interfacial reaction.

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Acknowledgments

The authors are grateful for the financial support from the Natural Science Foundation of Chongqing, China (cstc2021ycjh-bgzxm0165), the Venture and Innovation Support Program for Chongqing Overseas Returnees (cx2019138) and the National Natural Science Foundation of China (91634106).

Conflict of interest

On behalf of all authors, the corresponding author states that there is no conflict of interest.

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Authors and Affiliations

  1. College of Materials Science and Engineering, Chongqing University, Chongqing, 400044, P.R. China

    Junyi Deng, Lingxiao Bai, Panshuai Ma, Kaihui Ma & Jian Xu

  2. Graduate School of Engineering, Tohoku University, Sendai, Miyagi, 980-8577, Japan

    Junyi Deng

  3. State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization, Panzhihua, 617000, Sichuan, P.R. China

    Kaihui Ma

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  1. Junyi Deng
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  2. Lingxiao Bai
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  3. Panshuai Ma
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Correspondence to Jian Xu.

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Deng, J., Bai, L., Ma, P. et al. An Electric Circuit Analogy Model for Analyzing the Relation Between CO and H2 in Interfacial Reduction Reactions. Metall Mater Trans B 53, 2867–2872 (2022). https://doi.org/10.1007/s11663-022-02570-x

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  • DOI: https://doi.org/10.1007/s11663-022-02570-x

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