Skip to main content
SpringerLink
Log in

Complexes of Dioxomolybdenum(VI) with Acylhydrazones. Crystal Structures of Nicotinoylhydrazone 5-Nitrosalicylic Aldehyde (H2L) and Solvate Complex МоО2(L)·Me2SO

  • COORDINATION COMPOUNDS
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Nicotinoylhydrazone 5-nitrosalicylic aldehyde (H2L) and solvate complex МоО2(L)⋅Me2SO (I) have been synthesized and their structures have been studied by IR spectroscopy and X-ray diffraction. According to X-ray diffraction data, the molybdenum atom in I has an octahedral coordination built of two cis-O2(oxo) ligands, N(L),O(Solv) atoms in trans-positions to O(oxo) and two O(L) atoms in cis-positions to O(oxo) and in trans-positions to each other. The Mo atom coordinates ligand L2– in the tridentate (2O, N) bis-chelate manner. Average bond lengths in I are: Mo–O(oxo) 1.690 Å, Mo–N(L) 2.249 Å, Mo–O(L) 1.965 Å, Mo–O(Me2SO) 2.260 Å, the O(oxo)MoO(oxo) bond angle is 105.1°. Changes in the geometric parameters of ligand L2– when passing from H2L and coordination by the Mo atom in complex I are considered. Adduct МоО2Сl2⋅2H2L (II) has been obtained, and its structure is discussed based on IR spectroscopy data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. Mashkovskii M.D. Medicines (Novaya volna, Moscow, 2019) [in Russian].

  2. L. X. Xia, Y. F. Xia, L. R. Huang, et al., Eur. J. Med. Chem 97, 83 (2015). https://doi.org/10.1016/j.ejmech.2015.04.042

    Article  CAS  PubMed  Google Scholar 

  3. D. Cvijanović, J. Pisk, G. Pavlović, et al., New J. Chem. 43, 1791 (2019).

    Article  Google Scholar 

  4. H. B. Küçük, E. Mataraci, and B. Ö. Çelik, Turkish J. Chem. 1, 1 (2015). https://doi.org/10.3906/kim-1502-122

    Article  CAS  Google Scholar 

  5. R. Kaplanek, M. Havlik, B. Dolensky, et al., Bioorg. Med. Chem. 23, 1651 (2015). https://doi.org/10.1016/j.bmc.2015.01.029

    Article  CAS  PubMed  Google Scholar 

  6. V. P. Singh and P. Gupta, J. Enzym. Inhib. 23, 797 (2008). https://doi.org/10.1080/14756360701733136

    Article  CAS  Google Scholar 

  7. V. P. Singh, S. Singh, and D. P. Singh, J. Enzym. Inhib. 27, 319 (2012). https://doi.org/10.3109/14756366.2011.588228

    Article  CAS  Google Scholar 

  8. G. L. Backes, D. M. Neuman, and B. S. Jursic, Bioorg. Med. Chem. 22, 4629 (2014). https://doi.org/10.1016/j.bmc.2014.07.022

    Article  CAS  PubMed  Google Scholar 

  9. R. Bikas, V. Lippolis, N. Noshiranzadeh, et al., Eur. J. Inorg. Chem. 6, 999 (2017).

    Article  Google Scholar 

  10. V. Vrdoljak, M. Mandarić, T. Hrenar, et al., Cryst. Crowth Des. 19, 3000 (2019). https://doi.org/10.1021/acs.cgd.9b0023

    Article  CAS  Google Scholar 

  11. J. Pisk, L. Bilić, M. Đaković, et al., Polyhedron 145, 70 (2018).

    Article  CAS  Google Scholar 

  12. C. M. Cordas and J. J. G. Moura, Coord. Chem. Rev. 394, 53 (2019).

    Article  CAS  Google Scholar 

  13. T. M. Asha and M. R. P. Kurup, Polyhedron 169, 151 (2019).

    Article  CAS  Google Scholar 

  14. D. Kuriakose and M. R. P. Kurup, Polyhedron 170, 749 (2019).

    Article  CAS  Google Scholar 

  15. V. Jaiswal, S. R. Gupta, R. B. Rastogi, et al., J. Mater. Chem. A 3, 5092 (2015). https://doi.org/10.1039/c4ta05663a

    Article  CAS  Google Scholar 

  16. R. B. Rastogi, J. L. Maurya, and V. Jaiswal, Tribol. Trans. 56, 592 (2013). https://doi.org/10.1080/10402004.2012.748115

    Article  CAS  Google Scholar 

  17. V. A. Kogan, V. V. Zelentsov, G. M. Larin, and V. V. Lukov, Complexes of Transition Metals with Hydrazones: Physicochemical Properties and Structure (Nauka, Moscow, 1990) [in Russian].

    Google Scholar 

  18. A. S. Burlov, V. G. Vlasenko, B. V. Chal’tsev, et al., Russ. J. Coord. Chem. 47, 439 (2021). https://doi.org/10.1134/S1070328421070010

    Article  CAS  Google Scholar 

  19. V. L. Abramenko, A. D. Garnovskii, and Yu. V. Abramenko, Koord. Khim. 20, 39 (1994).

    CAS  Google Scholar 

  20. G. M. Sheldrick, SADABS. Program for Scaling and Correction of Area Detector Data (University of Göttingen, Göttingen, Germany, 1996).

    Google Scholar 

  21. G. M. Sheldrick, Acta Crystallogr. C 71, 3 (2015).

    Google Scholar 

  22. V. S. Sergienko, V. L. Abramenko, and M. D. Surazhskaya, Russ. J. Inorg. Chem. 65, 495 (2020). https://doi.org/10.1134/S0036023620040166

    Article  CAS  Google Scholar 

  23. L. J. Bellamy, The Infrared Spectra of Complex Molecules (Springer, 1980).

    Book  Google Scholar 

  24. V. S. Sergienko, V. L. Abramenko, and L. Kh. Minacheva, Koord. Khim. 19, 28 (1993).

    CAS  Google Scholar 

  25. V. S. Sergienko, Russ. J. Inorg. Chem. 54, 2031 (2009). https://doi.org/10.1134/S00360236091.30014

    Article  Google Scholar 

  26. A. D. Garnovskii, Koord. Khim. 18, 675 (1992).

    CAS  Google Scholar 

  27. A. D. Garnovskii, I. S. Vasil’chenko, D. A. Garnovskii, Modern Aspects of the Synthesis of Metal Complexes. Main Ligands and Methods (LaPO, Rostov-on-Don, 2000) [in Russian].

  28. V. S. Sergienko, V. L. Abramenko, A. V. Churakov, and M. D. Surazhskaya, Russ. J. Inorg. Chem. 66, 1732 (2011). https://doi.org/10.1134/S0036023621120159

    Article  Google Scholar 

  29. M. Nandy, S. Shit, C. Rizzoli, et al., Polyhedron 88, 63 (2015). https://doi.org/10.1016/j.poly.2014.12.017

    Article  CAS  Google Scholar 

  30. W. Banße, E. Ludwig, U. Schilde, and E. Uhlemann, Z. Anorg. Allg. Chem. 621, 1275 (1995).

    Article  Google Scholar 

  31. H. Kargar, P. Forootan, M. Fallah-Mehrjjatdi, et al., Inorg. Chim. Acta 523, 120414 (2021). https://doi.org/10.1016/j.ica.2021.120414

  32. V. G. Yusupov, S. D. Nasirdinov, S. I. Yakimovich, and N. Ya. Parpiev, Koord. Khim. 10, 387 (1984).

    CAS  Google Scholar 

  33. E. Ludwig, H. Hefele, E. Uhlemann, et al., Z. Anorg. Allg. Chem. 621, 23 (1995).

    Article  CAS  Google Scholar 

  34. H. Hefele, E. Ludwig, E. Uhlemann, et al., Z. Anorg. Allg. Chem. 621, 1431 (1995).

    Article  CAS  Google Scholar 

  35. W. Banße, E. Ludwig, U. Schilde, et al., J. Inorg. Biochem. 59, 730 (1995).

    Article  Google Scholar 

Download references

Funding

This work was carried out within the framework of the State Assignment of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Science in the field of fundamental scientific research.

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    V. S. Sergienko & M. D. Surazhskaya

  2. Lugansk State University, 910341, Lugansk, Ukraine

    V. L. Abramenko

Authors
  1. V. S. Sergienko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. L. Abramenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. D. Surazhskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. S. Sergienko.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by V. Avdeeva

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sergienko, V.S., Abramenko, V.L. & Surazhskaya, M.D. Complexes of Dioxomolybdenum(VI) with Acylhydrazones. Crystal Structures of Nicotinoylhydrazone 5-Nitrosalicylic Aldehyde (H2L) and Solvate Complex МоО2(L)·Me2SO. Russ. J. Inorg. Chem. 67, 636–642 (2022). https://doi.org/10.1134/S0036023622050151

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023622050151

Keywords:

Search

Navigation