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Stability of Cobalt(II) Complexes with Glycinate Ion as a Function of Water–Dimethyl Sulfoxide Solvent Composition

  • PHYSICAL CHEMISTRY OF SOLUTIONS
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Abstract

The stability constants cobalt(II) glycylglycinate complexes in a water–DMSO solvent of variable composition have been determined by the potentiometric titration method at 298 K and a solution ionic strength of 0.1 M against the background of sodium perchlorate. It has been established that an increase in the content of DMSO in solution leads to an increase in the stability of cobalt(II) glycylglycinate complexes. Using literature data, we calculated the change in the Gibbs energy of the Co2+ ion transfer from water to its mixtures with DMSO and estimated the contributions of the transsolvation of the reagents in a water–DMSO solvent to the change in the Gibbs energy of the reaction of cobalt(II) glycylglycinate formation. It has been shown that a change in the Gibbs energy of transsolvation of a metal ion in a water–DMSO solution counteracts an increase in the equilibrium constant of the complex formation reaction, while a change in the solvation state of the ligand and the complex species, on the contrary, contributes to an increase in the stability of the complex.

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ACKNOWLEDGMENTS

The study was carried out using equipment of the Shared Facility Center at Ivanovo State University of Chemistry and Technology.

Funding

The study was supported by the Ministry and Education and Science (agreement no. 075-15-2021-671).

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Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

    V. A. Isaeva & V. A. Sharnin

  2. Kostroma State University, 156005, Kostroma, Russia

    A. S. Molchanov & M. V. Shishkin

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  1. V. A. Isaeva
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  2. A. S. Molchanov
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  3. M. V. Shishkin
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  4. V. A. Sharnin
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Correspondence to V. A. Isaeva.

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Translated by G. Kirakosyan

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Isaeva, V.A., Molchanov, A.S., Shishkin, M.V. et al. Stability of Cobalt(II) Complexes with Glycinate Ion as a Function of Water–Dimethyl Sulfoxide Solvent Composition. Russ. J. Inorg. Chem. 67, 699–704 (2022). https://doi.org/10.1134/S0036023622050084

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