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Phase Equilibria in the Cu2Se–GeSe2–SnSe2 System

  • PHYSICOCHEMICAL ANALYSIS OF INORGANIC SYSTEMS
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Abstract

Phase equilibria in the Cu2Se–GeSe2–SnSe2 quasi-ternary system were studied by differential thermal analysis (DTA) and X-ray powder diffraction analysis. A series of polythermal sections, the 750-K isothermal section of the phase diagram, and the liquid surface projection were plotted. Primary crystallization and homogeneity areas of phases were determined, as well as the characters and types of invariant and monovariant equilibria. Extensive Cu2GeSe3-base and Cu2SnSе3-base solid solutions were found to exist in the system along the Cu2GeSe3–Cu2SnSe3 section.

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REFERENCES

  1. X. L. Sanghoon, L. J. Tengfei, and L. Zhang, Y-H. Chalcogenide: From 3D to 2D and Beyond (Elsevier, 2019). https://doi.org/10.1016/C2017-0-03585-1.

  2. X. Chen, J. Yang, T. Wu, et al., Nanoscale 10, 15130 (2018). https://doi.org/10.1039/C8NR05558

    Article  CAS  PubMed  Google Scholar 

  3. E. Peccerillo and K. Durose, MRS Energy Sustainability 5, 1 (2018). https://doi.org/10.1557/mre.2018.10

    Article  Google Scholar 

  4. B. Yun, H. Zhu, J. Yuan, et al., J. Mater. Chem. B 8, 4778 (2020). https://doi.org/10.1039/D0TB00182A

    Article  CAS  PubMed  Google Scholar 

  5. Z. Xia, H. Fang, X. Zhang, et al., Chem. Mater. 30, 1121 (2018).https://doi.org/10.1021/acs.chemmater.7b05104

  6. T. R. Wei, Y. Qin, T. Deng, et al., Sci. China Mater. 62, 8 (2019). https://doi.org/10.1007/s40843-018-9314-5

    Article  CAS  Google Scholar 

  7. A. Mikula, K. Mars, P. Nieroda, and P. Rutkowski, Materials 14, 2635 (2021). https://doi.org/10.3390/ma14102635

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  8. T. Deng, P. Qiu, and T. Xing, J. Mater. Chem. A 9, 7946 (2021). https://doi.org/10.1039/D0TA12042A

    Article  CAS  Google Scholar 

  9. B. Jiang, P. Qiu, E. Eikeland, et al., J. Mater. Chem. C 5, 943 (2017). https://doi.org/10.1039/c6tc05068a

    Article  CAS  Google Scholar 

  10. M. Siyar, J. -Y. Cho, Y. Youn, et al., J. Mater. Chem. C 6, 1780 (2018). https://doi.org/10.1039/C7TC05180H

    Article  CAS  Google Scholar 

  11. R. Chetty, D. S. Prem-Kumar, M. Falmbigl, et al., Intermetallics 54, 1 (2014). https://doi.org/10.1016/j.intermet.2014.05.006

    Article  CAS  Google Scholar 

  12. A. K. Ivanov-Shchits and I. V. Murin, Solid State Ionics, vol. 1 (Izd-vo St. Peterb. Univ., St. Petersburg, 2000) [in Russian].

    Google Scholar 

  13. V. M. Berezin and G. P. Vyatkin, Superionic Semiconductor Chalcogenides (Chelyabinsk, 2001) [in Russian].

    Google Scholar 

  14. H. Liu, X. Shi, F. Xu, et al., Nature Materials 11, 422 (2012). https://doi.org/10.1038/nmat3273

    Article  CAS  PubMed  Google Scholar 

  15. M. B. Babanly, Yu. A. Yusibov, and V. T. Abishev, Three-Component Chalcogenides Based on Copper and Silver (Baku, 1993) [in Russian].

    Google Scholar 

  16. M. B. Babanly, Yu. A. Yusibov, and N. B. Babanly, in Electromotive Force and Measurement in Several Systems, Ed. by S. Kara (IntechOpen, 2011). https://doi.org/10.5772/28934

    Book  Google Scholar 

  17. X. Liang, Appl. Phys. Lett. 111, 133902 (2017). https://doi.org/10.1063/1.4997501

    Article  CAS  Google Scholar 

  18. P. Qiu, M. T. Agne, Y. Liu, et al., Nature Commun. 9 (2910) (2018). https://doi.org/10.1038/s41467-018-05248-8

  19. M. B. Babanly, L. F. Mashadiyeva, D. M. Babanly, et al., Russ. J. Inorg. Chem. 64, 1134 (2019). https://doi.org/10.1134/S0036023619130035

    Article  Google Scholar 

  20. M. B. Babanly, E. V. Chulkov, Z. S. Aliev, et al., Russ. J. Inorg. Chem. 62, 1703 (2017). https://doi.org/10.1134/S0036023617130034

    Article  CAS  Google Scholar 

  21. V. P. Zlomanov, A. M. Khoviv, and A. Yu. Zavrazhnov, in Materials Science – Advanced Topics (IntechOpen, 2013). https://doi.org/10.5772/56700

  22. S. Z. Imamaliyeva, D. M. Babanly, D. B. Tagiev, and M. B. Babanly, Russ. J. Inorg. Chem. 13, 1703 (2018). https://doi.org/10.1134/S0036023618130041

    Article  Google Scholar 

  23. I. J. Alverdiyev, Z. S. Aliev, S. M. Bagheri, et al., J. Alloys Compd. 691, 255 (2017). https://doi.org/10.1016/j.j

    Article  CAS  Google Scholar 

  24. L. F. Mashadiyeva, Z. T. Gasanova, Yu. A. Yusibov, and M. B. Babanly, Russ. J. Inorg. Chem. 62, 598 (2017). https://doi.org/10.1134/S0036023617050151

    Article  Google Scholar 

  25. Z. T. Gasanova, L. F. Mashadiyeva, Yu. A. Yusibov, and M. B. Babanly, Russ. J. Inorg. Chem. 62, 591 (2017). https://doi.org/10.1134/S0036023617050126

    Article  CAS  Google Scholar 

  26. L. F. Mashadieva, Z. T. Gasanova, Yu. A. Yusibov, and M. B. Babanly, Inorg. Mater. 54, 8 (2018). https://doi.org/10.1134/S0020168518010090

    Article  CAS  Google Scholar 

  27. E. N. Ismailova, L. F. Mashadieva, I. B. Bakhtiyarly, and M. B. Babanly, Russ. J. Inorg. Chem. 64, 801 (2019). https://doi.org/10.1134/S0036023619060093

    Article  CAS  Google Scholar 

  28. Binary Alloy Phase Diagrams, Ed. by T. B. Massalski T. B. (ASM International, Materials Park, Ohio, 1990). https://doi.org/10.1002/adma.19910031215

  29. N. Kh. Abrikosov, in Semiconductor Physics (Springer, 2013). https://doi.org/10.1007/978-1-4899-6373-4.

  30. L. Gulay, M. Daszkiewicz, O. Strok, and A. Pietraszko, Chem. Met. Alloys 4, 200 (2011). https://doi.org/10.30970/cma4.0184

    Article  Google Scholar 

  31. G. Dittmar and H. Schafer, Acta Crystallogr. 32, 2726 (1976). https://doi.org/10.1107/s0567740876008704

    Article  Google Scholar 

  32. V. Tomashik, Copper-Germanium-Selenium, Ternary Alloys VCH 2, 288 (2015).

    Google Scholar 

  33. M. Onoda, M. Ishii, P. Pattison, et al., J. Solid State Chem. 146, 355 (1999). https://doi.org/10.1006/jssc.1999.8362

    Article  CAS  Google Scholar 

  34. V. N. Moroz, Izv. Akad. Nauk SSSR, Neorg. Mater. 26, 1830 (1990).

    CAS  Google Scholar 

  35. G. Marcano and L. Ieves, J. Appl. Phys. 87, 1284 (2000). https://doi.org/10.1063/1.372010

    Article  CAS  Google Scholar 

  36. O. V. Parasyuk, L. D. Gulay, Ya. E. Romanyuk, and L. V. Piskach, J. Alloys Compd. 329, 202 (2001). https://doi.org/10.1016/s0925-8388(01)01606-1

    Article  CAS  Google Scholar 

  37. O. S. Lychmanyuk, L. D. Gulay, I. D. Olekseyuk, et al., Pol. J. Chem. 81, 353 (2007).

    CAS  Google Scholar 

  38. B. B. Sharma, Phys. Status Solidi A 2, 13 (1970). https://doi.org/10.1002/pssa.19700020125

    Article  Google Scholar 

  39. J. Rivet, P. Laruelle, and J. Flahaut, Bull. Soc. Chim. Fr. 5, 1667 (1970).

    Google Scholar 

  40. L. I. Berger and E. K. Kotina, Inorg. Mater. (Engl. Trans.) 9, 330 (1973).

  41. T. V. Zotova and Yu. A. Karagodin, Sb. Nauchn. Trudov Probl. Mikroel. 21, 57 (1975).

    Google Scholar 

  42. I. D. Olekseyuk, O. V. Parasyuk, L. V. Piskach, et al., Quasi-Ternary Systems of Chalcogenides (Vega Publish, Lutsk, 1999).

    Google Scholar 

  43. L. S. Palatnik, Yu. F. Komnik, E. K. Belova, and L. V. Atroshchenko, Kristallografiya 6, 960 (1961).

    CAS  Google Scholar 

  44. B. B. Sharma, R. Ayyar, and H. Singh, Phys. Status Solidi A 40, 691 (1977). https://doi.org/10.1002/pssa.2210400237

    Article  CAS  Google Scholar 

  45. G. Marcano, L. M. de Chalbaud, C. Rincon, and G. Sanchez-Perez, Mater. Lett. 53, 151 (2002). https://doi.org/10.1016/S0167-577X(01)00466-9

    Article  CAS  Google Scholar 

  46. M. I. Karakhanova, L. P. Sokolova, and A. V. Novoselova, Izv. Akad. Nauk SSSR, Neorgan. Mater. 12, 1221 (1976).

    Google Scholar 

  47. J. Emsley, The Elements (Clarendon Press, Oxford, 1991).

    Google Scholar 

  48. V. I. Lutsyk, V. P. Vorob’eva, and S. Ya. Shodorova, Russ. J. Phys. Chem. 89, 2331 (2015). https://doi.org/10.1134/S0036024415130245

    Article  CAS  Google Scholar 

  49. V. I. Lutsyk and V. P. Vorob’eva, Russ. J. Phys. Chem. A 91, 2593 (2017). https://doi.org/10.1134/S0036024417130131

    Article  CAS  Google Scholar 

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Funding

The work was supported by the Science Development Foundation under the President of the Azerbaijan Republic (project No. EİF-BGM-4-RFTF-1/2017-21/11/4-M-12).

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Correspondence to L. F. Mashadieva.

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Translated by O. Fedorova

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Mashadieva, L.F., Alieva, Z.M., Mirzoeva, R.D. et al. Phase Equilibria in the Cu2Se–GeSe2–SnSe2 System. Russ. J. Inorg. Chem. 67, 670–682 (2022). https://doi.org/10.1134/S0036023622050126

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