Skip to content
Licensed Unlicensed Requires Authentication Published by De Gruyter January 28, 2022

Optimizing the two-stage adsorber of NaOH-activated coconut shell carbon for methylene blue removal

  • Ada Chu Wen Wong , Sirajo Lawal and Muhammad Abbas Ahmad Zaini ORCID logo EMAIL logo

Abstract

This work was aimed at optimizing the adsorbent mass and contact time and evaluating the performance of two-stage batch adsorber of NaOH-activated coconut shell carbon for methylene blue removal. To decrease the dye concentration from 1000 to 89.4 mg/L at any effluent volumes, the two-stage adsorber displays a small mass saving of 0.33% because of the high adsorbent affinity towards methylene blue at 1.80 L/mg. Meanwhile, the contact time can be minimized by 97.6% as opposed to that in one-stage adsorber. The sensitivity analysis of affinity on mass minimization shows a significant saving of 28.5% when the affinity is reduced to 0.01 L/mg. The response surface methodology was used to optimize the two-stage absorber for methylene blue removal, wherein the most significant parameter is the contact time.


Corresponding author: Muhammad Abbas Ahmad Zaini, School of Chemical and Energy Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, Johor Bahru, Johor, Malaysia; and Centre of Lipids Engineering and Applied Research (CLEAR), Ibnu-Sina Institute for Scientific and Industrial Research (ISI-SIR), Universiti Teknologi Malaysia, Johor Bahru, Johor, Malaysia, E-mail:

Award Identifier / Grant number: UTM-ICONIC 09G54

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was supported by Universiti Teknologi Malaysia, UTM-ICONIC Grant No. 09G54.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

Amran, F., and M. A. A. Zaini. 2020. “Effects of Chemical Activating Agents on Physical Properties of Activated Carbons – A Commentary.” Water Practice and Technology 15 (4): 863–76, https://doi.org/10.2166/wpt.2020.094.Search in Google Scholar

Bamatraf, S. M. S., and M. A. A. Zaini. 2021. “Optimization in a Two-Stage Sorption of Malachite Green by Date Palm Residue Carbon.” International Congress of Advanced Technology and Engineering (ICOTEN) 2021: 1–5, https://doi.org/10.1109/ICOTEN52080.2021.9493441.Search in Google Scholar

Cazetta, A. L., A. M. M. Vargas, E. M. Nogami, M. H. Kunita, M. R. Guilherme, A. C. Martins, T. L. Silva, J. C. Moraes, and V. C. Almeida. 2011. “NaOH-Activated Carbon of High Surface Area Produced from Coconut Shell: Kinetics and Equilibrium Studies from the Methylene Blue Adsorption.” Chemical Engineering Journal 174 (1): 117–25, https://doi.org/10.1016/j.cej.2011.08.058.Search in Google Scholar

Hijab, M., J. Saleem, P. Parthasarathy, H. R. Mackey, and G. McKay. 2020. “Two-Stage Optimisation for Malachite Green Removal Using Activated Date Pits.” Biomass Conversion and Biorefinery 11 (2): 727–40, https://doi.org/10.1007/s13399-020-00813-y.Search in Google Scholar

Lamido, S., A. U. Alhassan, and S. Lawal. 2021. “Utilization of Response Surface Methodology for the Production of Ethanol from Corn Cob.” International Journal of Scientific Research and Engineering Development 4 (5): 680–5.Search in Google Scholar

Ming-Twang, S., L. Lin-Zhi, M. A. A. Zaini, Q. Zhi-Yong, and A. Y. Pei-Yee. 2015. “Activated Carbon for Dyes Adsorption in Aqueous Solution.” In Advances in Environmental Research, Vol. 36, edited by J. A. Daniels, 217–34. New York: Nova Science Publishers, Inc.Search in Google Scholar

Mohammed, F., E. Roberts, A. Campen, and N. Brown. 2012. “Wastewater Treatment by Multi-Stage Batch Adsorption and Electrochemical Regeneration.” Journal of Electrochemical Science and Engineering 2 (4): 223–36, https://doi.org/10.5599/jese.2012.0019.Search in Google Scholar

Oladipo, A. A., and M. Gazi. 2015. “Two-Stage Batch Sorber Design and Optimization of Biosorption Conditions by Taguchi Methodology for the Removal of Acid Red 25 Onto Magnetic Biomass.” Korean Journal of Chemical Engineering 32 (9): 1864–78, https://doi.org/10.1007/s11814-015-0001-6.Search in Google Scholar

Oladipo, A. A., and A. O. Ifebajo. 2018. “Highly Efficient Magnetic Chicken Bone Biochar for Removal of Tetracycline and Fluorescent Dye from Wastewater: Two-Stage Adsorber Analysis.” Journal of Environmental Management 209: 9–16, https://doi.org/10.1016/j.jenvman.2017.12.030.Search in Google Scholar PubMed

Palanisami, H., M. R. M. Azmi, M. A. A. Zaini, Z. A. Zakaria, M. N. H. Z. Alam, and M. A. C. Yunus. 2021. “Coffee Residue-Based Activated Carbons for Phenol Removal.” Water Practice and Technology 16 (3): 793–805, https://doi.org/10.2166/wpt.2021.034.Search in Google Scholar

Ratan, J. K., M. Kaur, and B. Adiraju. 2018. “Synthesis of Activated Carbon from Agricultural Waste Using a Simple Method: Characterization, Parametric and Isotherms Study.” Materials Today Proceedings 5: 3334–45, https://doi.org/10.1016/j.matpr.2017.11.576.Search in Google Scholar

Yagub, M. T., T. K. Sen, S. Afroze, and H. M. Ang. 2014. “Dye and its Removal from Aqueous Solution by Adsorption: A Review.” Advances in Colloid and Interface Science 209: 172–84, https://doi.org/10.1016/j.cis.2014.04.002.Search in Google Scholar PubMed

Zubir, M. H. M., and M. A. A. Zaini. 2020. “Dyes Removal by Activated Carbons Synthesized via Various Chemical Activation Strategies: An Overview.” In Advances in Environmental Research, Vol. 70, edited by J. A. Daniels, 175–200. New York: Nova Science Publishers, Inc.Search in Google Scholar

Received: 2021-08-22
Accepted: 2022-01-08
Published Online: 2022-01-28

© 2022 Walter de Gruyter GmbH, Berlin/Boston

Downloaded on 24.4.2024 from https://www.degruyter.com/document/doi/10.1515/ijcre-2021-0220/html
Scroll to top button