Abstract
Photochemical processes in thin surface layers of solutions of compounds of the copper subgroup elements leading to the formation of dispersed metal particles on the surface of dielectrics are investigated. It is shown that dispersed particles of elemental gold are formed on dielectrics moistened with AuCl3 solution and exposed to sunlight. At the same time, there is no need to use any chemical reducing agents. On cotton fabrics moistened with solutions of AgNO3, CuBr2, when exposed to sunlight, silver and copper monohalides are formed, respectively. These processes take place with the participation of terminal cellulose molecules and also do not require the use of chemical reducing agents. In addition, it was found that copper monohalides can be converted into elemental copper particles by a photochemical reaction involving ascorbic acid. Examples of metallization of a number of dielectrics using photochemical activation using sunlight are given.
-
Author contributions: Conceptualization – M.S.; Software, Formal analysis – K.A., Y.R.; Investigation – B.S.; Resources, Writing - Original Draft – S.K.; Writing - Review & Editing – P.A., Y.R.; Visualization, Data Curation – V.D.
-
Research funding: The authors received no specific funding for this article.
-
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
References
Boitsova, T., and E. Volkova. 2005. “Metody Poluchenija Nanochastic Metallov [in Russian: Methods for the Production of Metal Nanoparticles].” Sorosovskij zhurnal 9: 1–6.Search in Google Scholar
Fan, X., L. Yahia, and E. Sacher. 2021. “Antimicrobial Properties of the Ag, Cu Nanoparticle System.” Biology 10: 137, https://doi.org/10.3390/biology10020137.Search in Google Scholar PubMed PubMed Central
Finaenov, A. I., S. M. Zakirova, L. A. Rahmetulina, V. V. Krasnov, and O. G. Nevernaja. 2016. Method for Non-palladium Activation of Plastic Surface. Russian Federation Patent No.2588918, Publ. 10.07.2016. https://yandex.ru/patents/doc/RU2588918C1_20160710.Search in Google Scholar
Furno, F., K. S. Morley, and B. Wong. 2004. “Silver Nanoparticles and Polymeric Medical Devices: A New Approach to Prevention of Infection?” Journal of Antimicrobial Chemotherapy 54: 1019–24, https://doi.org/10.1093/jac/dkh478.Search in Google Scholar PubMed
Gorji, M., S. Mazinani, A.-R. Faramarzi, S. Ghadimi, M. Kalaee, A. Sadeghianmaryan, and L. D. Wilson. 2021. “Coating Cellulosic Material with Ag Nanowires to Fabricate Wearable IR-Reflective Device for Personal Thermal Management: The Role of Coating Method and Loading Level.” Molecules 26: 3570, https://doi.org/10.3390/molecules26123570.Search in Google Scholar PubMed PubMed Central
Gapparov, H. G., J. J. Homidov, and G. K. Fajzieva. 2016. “Types and Methods of Metallized Textile Materials for Sewing Special Clothing.” Molodoj uchenyj 11: 310–3. https://moluch.ru/archive/115/30702/.Search in Google Scholar
Gamburg, Yu.D. 2006. Electroplating Coatings. Application Reference. Moscow: Technosphera.Search in Google Scholar
Isaeva, E., V. Gorbunova, T. Boitsova, A. Shukarev, and N. Sirotinkin. 2006. “Investigation of the Processes of Photochemical Formation of Silver Nanoparticles in Elastomeric Films.” Journal of General Chemistry 76: 723–9, https://doi.org/10.1134/s1070363206050045.Search in Google Scholar
Kapitsa, M. 2005. “Aktivacija Poverhnosti Dijelektrika [in Russian: Activation of the Dielectric Surface].” Technologies in the Electronic Industry 5: 22–5. http://tech-e.ru/pdf/2005-05-22.pdf.Search in Google Scholar
Kochemirovsky, V. A., S. V. Safonov, M. D. Bal’makov, I. I. Tumkin, Y. S. Tver’yanovich, and L. G. Menchikov. 2011. “Laser-induced Chemical Liquid Phase Deposition of Metals: Chemical Reactions in Solution and Activation of Dielectric Surfaces.” Russian Chemical Reviews 9 (80): 869882. https://elibrary.ru/item.asp?id=18013953, https://doi.org/10.1070/rc2011v080n09abeh004224.Search in Google Scholar
Kapitsa, M. 2005. “Podgotovka Poverhnosti V Proizvodstve Pechatnyh Plat [in Russian: Surface Preparation in the Production of Printed Circuit Boards].” Technologies in the Electronic Industry 4: 18–21. http://tech-e.ru/pdf/20050418.pdf.Search in Google Scholar
Melnikov, V. 2011. Renewable Sources of Energy. Teaching Materials for People Making Decisions in Central Asian Region. UNESCO. http://www.unesco.org/almaty.Search in Google Scholar
Rjashenceva, G. N., and O. I. Lomovskij. 1998. “Kataliticheskaja Aktivnost’ Mednyh Chastic V Reakcii Himicheskogo Mednenija [in Russian: Catalytic Activity of Copper Particles in Chemical Copper Plating Reaction].” Russian Journal of Applied Chemistry 2 (71): 264–7.Search in Google Scholar
Shkundina, S. 2009. “Novye Processy I Materialy V Proizvodstve Pechatnyh Plat [in Russian: New Processes and Materials in the Production of Printed Circuit Boards].” Technologies in the Electronic Industry 4: 16–20. http://www.tech-e.ru/pdf/2009_04_16.pdf.Search in Google Scholar
Smith, W. C. 2018. Smart Textile Coatings and Laminates. Sawston: Woodhead Publishing. https://www.elsevier.com/books/smart-textile-coatings-and-laminates/smith/978-0-08-102428-7.Search in Google Scholar
Volkov, A. I., and I. M. Zharskij. 2005. Large Chemical Reference Book. Minsk: Sovremennaya Shkola.Search in Google Scholar
Wang, K., Q. Ma, Y. Zhang, S. Wang, and G. Han. 2020. “Ag NPs-Assisted Synthesis of Stable Cu NPs on PET Fabrics for Antibacterial and Electromagnetic Shielding Performance.” Polymers 12: 783, https://doi.org/10.3390/polym12040783.Search in Google Scholar PubMed PubMed Central
© 2022 Walter de Gruyter GmbH, Berlin/Boston