Issue 14, 2022

Mansfieldite (AlAsO4·2H2O): a new white pigment in Himalayan artwork

Abstract

An unusual arsenate mineral, mansfieldite (AlAsO4·2H2O), was identified as a pigment for the first time as the principal white colorant on two Himalayan thangka paintings at the Indianapolis Museum of Art at Newfields. The co-occurrence of this unusual mineral pigment provides support for the belief that the two artworks are members of a cycle of paintings originating from the same workshop, perhaps from Chamdo, Tibet. The complete palettes of both artworks are identical, including the use of mansfieldite, brochantite, malachite, azurite, vermilion, gold, orpiment, and a carbon-based black in a glue binder on a calcite and gypsum-primed cotton fabric.

Graphical abstract: Mansfieldite (AlAsO4·2H2O): a new white pigment in Himalayan artwork

Article information

Article type
Paper
Submitted
03 May 2022
Accepted
07 Jun 2022
First published
08 Jun 2022

Analyst, 2022,147, 3266-3275

Author version available

Mansfieldite (AlAsO4·2H2O): a new white pigment in Himalayan artwork

G. D. Smith, C. L. Hoevel, P. D. Cavanagh and G. K. Druschel, Analyst, 2022, 147, 3266 DOI: 10.1039/D2AN00760F

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