Issue 26, 2022
From the journal:

Dalton Transactions

Reversible binding of dinitrogen on a thiolate-bridged cobalt–ruthenium complex supported by a flexible bidentate phosphine ligand†

Wenjing Dong,a   Dawei Yang, ORCID logo *a   Tao Mei,a   Baomin Wang ORCID logo a  and  Jingping Qu ORCID logo a  

* Corresponding authors

a State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, P. R. China
E-mail: yangdw@dlut.edu.cn

Abstract

A well-defined thiolate-bridged cobalt–ruthenium complex is demonstrated to reversibly bind N2 by modulation of the auxiliary phosphine ligand, which is evidenced by time-dependent 1H NMR spectroscopy at different temperatures. Notably, this heterobimetallic system represents the first example that can realize N2 coordination on a sulfur-rich Co–Ru cooperative scaffold.

Graphical abstract: Reversible binding of dinitrogen on a thiolate-bridged cobalt–ruthenium complex supported by a flexible bidentate phosphine ligand

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Article information

DOI
https://doi.org/10.1039/D2DT01534J
Article type
Communication
Submitted
17 May 2022
Accepted
06 Jun 2022
First published
07 Jun 2022

Dalton Trans., 2022,51, 9978-9982

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Reversible binding of dinitrogen on a thiolate-bridged cobalt–ruthenium complex supported by a flexible bidentate phosphine ligand

W. Dong, D. Yang, T. Mei, B. Wang and J. Qu, Dalton Trans., 2022, 51, 9978 DOI: 10.1039/D2DT01534J

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