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Calculation of the Equilibrium Distribution of Nicotinic Acid and Iron(III) Between an Aqueous Solution and Sulfocationite Dowex-50

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Abstract

The equilibrium distribution of nicotinic acid and iron(III) between an aqueous solution and Dowex-50 sulfonic cation exchanger has been investigated. The equilibrium constants of ligand sorption of nicotinic acid by sulfonic cation Dowex-50 containing protons or cations of iron have been determined. An algorithm is proposed for calculating the equilibrium composition of an aqueous solution of a mixture of nicotinic acid and FeCl3 allowing one to get sulfonic cation exchanger Dowex-50 with a predetermined counter-ionic composition. The predictive ability of the proposed algorithm is confirmed by experimental studies of the process of sorption of complexes of nicotinic acid and iron(III) from aqueous solutions of H and Fe(III) forms of Dowex-50 sulfonic cation exchanger. It has been shown that, in a sulfonic cation exchanger equilibrated with an aquatic solution having a ratio of molarities of cations Н+ : [H2L]+ : Fe3+ : [FeL]2+equal to 1 : 1 : 0.16 : 0.1, the content of complex cations [FeL]2+ is 44.5 wt %.

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Funding

This work was carried out as part of the State Task of the Institute of Coal Chemistry and Chemical Materials Science of the Federal Research Center for Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences (no. 121031500194-5), using equipment from the Shared Use Center of the Federal Research Center for Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences.

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Authors and Affiliations

  1. Federal Research Center for Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences, Kemerovo, Russia

    G. N. Altshuler & E. V. Ostapova

  2. Kemerovo State University, Kemerovo, Russia

    O. G. Altshuler

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  1. G. N. Altshuler
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  2. E. V. Ostapova
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  3. O. G. Altshuler
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Correspondence to G. N. Altshuler.

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Altshuler, G.N., Ostapova, E.V. & Altshuler, O.G. Calculation of the Equilibrium Distribution of Nicotinic Acid and Iron(III) Between an Aqueous Solution and Sulfocationite Dowex-50. Theor Found Chem Eng 56, 124–130 (2022). https://doi.org/10.1134/S0040579521060014

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  • DOI: https://doi.org/10.1134/S0040579521060014

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