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Structural Characteristics of the Resin–Asphaltene Components of the Organic Matter of Oil Shale from the Dmitrievskoe Deposit and the Liquid Products of Its Conversion in Supercritical Benzene

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Abstract

The averaged molecules of asphaltenes and resins of the organic matter of oil shale from the Dmitrievskoe deposit and the liquid products of its conversion in a flow of supercritical benzene were described using structural group analysis based on the joint use of information on the elemental composition, average molecular weights, and 1H NMR-spectrometric data and the results of X-ray diffraction analysis. The results obtained made it possible to expand the understanding of the macromolecular structure of the resin–asphaltene components of oil shale formations and to reveal similarities and differences in their structural organization.

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ACKNOWLEDGMENTS

We are grateful to the following staff members of the Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences: Cand. Sci. (Chem.), Senior Researcher V.D. Ogorodnikov for recording the 1H NMR spectra, Leading Engineer G.A. Tomson for determining the elemental compositions of the samples, and Engineer E. Kovalenko for measuring the molecular weights of the samples.

Funding

This study was funded by the Ministry of Science and Higher Education of the Russian Federation (NIOKTR 1210312000185-6) and carried out within the framework of a state contract at the Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences.

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Authors and Affiliations

  1. Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences, 634055, Tomsk, Russia

    E. Yu. Kovalenko, V. Baishibilova, R. S. Min & T. A. Sagachenko

  2. Federal Research Center of Coal and Coal Chemistry, Institute of Coal, Siberian Branch, Russian Academy of Sciences, 650056, Kemerovo, Russia

    Yu. F. Patrakov

Authors
  1. E. Yu. Kovalenko
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  2. V. Baishibilova
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  3. R. S. Min
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  4. T. A. Sagachenko
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  5. Yu. F. Patrakov
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Corresponding authors

Correspondence to E. Yu. Kovalenko, V. Baishibilova, R. S. Min, T. A. Sagachenko or Yu. F. Patrakov.

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The authors declare that they have no conflicts of interest.

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Translated by V. Makhlyarchuk

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Kovalenko, E.Y., Baishibilova, V., Min, R.S. et al. Structural Characteristics of the Resin–Asphaltene Components of the Organic Matter of Oil Shale from the Dmitrievskoe Deposit and the Liquid Products of Its Conversion in Supercritical Benzene. Solid Fuel Chem. 56, 87–92 (2022). https://doi.org/10.3103/S0361521922020033

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  • DOI: https://doi.org/10.3103/S0361521922020033

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