Abstract
The effect of equal channel angular pressing (ECAP) on the structure, static, and cyclic strength of zirconium alloy E110 (Zr–1% Nb) is studied. The ECAP procedure is applied to samples with a diameter of 20 mm and a length of 100 mm along the BC route with an angle of 110° between the channels in six passes with a stepwise decrease in temperature from 400 to 300°C. A highly inhomogeneous ultrafine-grained microstructure that is comprised of regions filled with cells and fragments with low misorientation and a high density of dislocations and regions with predominantly equiaxial structural units is formed in the alloy after ECAP. As a result of ECAP, the tensile strength of the alloy increases by 40%, the yield point increases by 22%, and the relative elongation decreases by a factor of 2. Equal channel angular pressing leads to a decrease in the endurance fatigue limit based on 107 cycles from 225 to 150 MPa and to a change in the fracture mechanism from a quasi-ductile microgrooved mechanism to a predominantly brittle one with secondary cracking. With high stresses in the cycle (above 280 MPa), the durabilities of the alloy both in the initial state and after ECAP are comparable.
Similar content being viewed by others
REFERENCES
S. G. Steinemann, Corrosion of Surgical Implants—In Vivo and In Vitro Tests, Evaluation of Biomaterials (Wiley, New York, 1980), pp. 1–34.
A. Yu. Fadeev, “Zirconium in orthopedic dentistry,” Medtekhnika I Medizdeliya, No. 4, 26–30 (2002).
Yu. G. Shaposhnikov, K. M. Sherepo, V. Yu. Gorokhov, and G. N. Berchenko, “Zirconium for explants in traumatology and orthopedics,” Ortopediya, Travmatologiya i Protezirovanie, No. 1, 31–33 (1993).
S. A. Nikulin, A. B. Rozhnov, S. O. Rogachev, V. M. Khatkevich, V. A. Turchenko, and E. S. Khotulev, “Investigation of structure, phase composition, and mechanical properties of Zr–2.5% Nb alloy after ECAP,” Mater. Lett. 169, 223–226 (2016).
V. F. Terent’ev, S. V. Dobatkin, S. A. Nikulin, V. I. Kopylov, D. V. Prosvirnin, S. O. Rogachev, and I. O. Bannykh, “Effect of equal-channel angular pressing on the fatigue strength of titanium and a zirconium alloy,” Metally 2011, No. 10, 981–988 (2011).
S. A. Nikulin, S. O. Rogachev, A. B. Rozhnov, V. I. Kopylov, S. V. Dobatkin, “Corrosion damage under stress corrosion cracking tests of Zr-2,5% Nb alloy after equal-channel angular pressing, Fiz. Khim. Obr. Met., No. 1, 74–80 (2012).
M. V. P. Companhoni, J. R. G. Matheus, T. L. Marcondes, and A. L. Pinto, “Analysis of microstructure and microhardness of Zr–2.5Nb processed by High-Pressure Torsion (HPT),” J. Mater. Sci. 47, 7835–7840 (2012).
A. P. Zhilyaev, I. Sabirov, G. Gonzalez-Doncel, J. Molina-Aldareguia, B. Srinivasarao, and M. T. Pérez-Prado, “Effect of Nb additions on the microstructure, thermal stability and mechanical behavior of high pressure Zr phases under ambient conditions,” Mater. Sci. Eng., A 528, 3496–3505 (2011).
V. Sklenicka, J. Dvorak, P. Kral, M. Svoboda, M. Kvapilova, V. I. Kopylov, S. A. Nikulin, and S. V. Dobatkin, “Creep behavior of a zirconium alloy processed by equal-channel angular pressing,” Acta Phys. Pol. A 122, 485–489 (2012).
B. S. Lee, M. H. Kim, S. K. Hwang, S. I. Kwun, and S. W. Chae, “Grain refinement of commercially pure zirconium by ECAP and subsequent intermediate heat treatment,” Mater. Sci. Eng., A 449–451, 1087–1089 (2007).
S. O. Rogachev, A. B. Rozhnov, S. A. Nikulin, O. V. Rybal’chenko, M. V. Gorshenkov, V. G. Chzhen, and S. V. Dobatkin, “Effect of torsion conditions under high pressure on the structure and strengthening of the Zr–1% Nb alloy,” Phys. Met. Metallogr. 117, No. 4, 371–377 (2016).
V. M. Segal, V. I. Reznikov, A. E. Drobyshevskii, and V. I. Kopylov, “Plastics processing of metals by simple shearing,” Izv. Akad. Nauk SSSR, Met., No. 1, 115–123 (1981).
R. Z. Valiev, A. P. Zhilyaev, and T. G. Langdon, Bulk Nanostructured Materials: Fundamentals and Applications (Wiley, New York, 2014).
V. F. Terent’ev, “Cyclic strength of submicro- and nanocrystalline metals and alloys (review),” Novye Materialy i Tekhnologii v Metallurgii I Mashinostroenii, No. 1, 8–24 (2010).
T. Sawai, S. Matsuoka, and K. Tsuzaki, “Low-and high-cycle fatigue properties of ultrafine-grained low carbon steels,” J. Iron Steel Inst. Jpn. 89, 726–733 (2003).
A. Vinogradov, S. Hashimoto, and V. I. Kopylov, “Enhanced strength and fatigue life of ultrafine grain Fe-36Ni Invar alloy,” Mater. Sci. Eng., A 355, 277–285 (2003).
A. Vinogradov, V. V. Stolyarov, S. Hashimoto, and R. Z. Valiev, “Cyclic behavior of ultrafine-grain titanium produced by severe plastic deformation,” Mater. Sci. Eng., A 318, 163–173 (2001).
H. K. Kim, M. I. Choi, C. S. Chung, and D. H. Shin, “Fatigue properties of ultrafine grained low carbon steel produced by equal channel angular pressing,” Mater. Sci. Eng., A 340, 243–250 (2003).
Funding
The structural studies were performed using the equipment of Center for Collective Use Materials Science and Metallurgy with the financial support from the Ministry of Education and Science of Russia (project no. 075-15-2021-696).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Additional information
Translated by O. Kadkin
Rights and permissions
About this article
Cite this article
Rozhnov, A.B., Rogachev, S.O., Alsheikh, K. et al. Cyclic Strength of the Zr–1% Nb Alloy after Equal Channel Angular Pressing. Phys. Metals Metallogr. 123, 99–105 (2022). https://doi.org/10.1134/S0031918X22010112
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0031918X22010112