Abstract
Microinclusions of Re-, Mo-, Cu-, Pb-, and Bi-bearing sulfides are found for the first time in Cu sulfide ores of the Maike occurrence, northern Ulytau. The microinclusions are characterized by various morphologies and chemical compositions. According to microprobe data, eight sulfides contain up to 49.46 wt % Re, as well as Fe, Cu, Mo, Pb, and Bi. The formulas of sulfides are (Re,Mo,Cu ± Fe,Os,Pt)2S3, (Re,Mo)S2, ReS3, Re2S7, (Pb,Re,Zn)S2, (Pb,Re,Fe)S2, (Pb,Re,Fe)2S3, and (Re,Fe)(Pb,Bi)S3. For the first time, we identified a previously unknown Pb–Re–Zn–S phase, a Rh and Sb assemblage in a Re–Fe–Pb–Bi–S mineral phase, and ReS3 and Re2S7 sulfides.
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REFERENCES
Barkov, A.Y. and Lednev, A.I., A rhenium-molybdenum-copper sulfide from the Lukkulaisvarra layered intrusion, northern Karelia, Russia, Eur. J. Mineral., 1993, vol. 6, pp. 1227–1233.
Bernard, A., and Dumortier, P., Identification of natural rhenium sulfide (ReS2) in volcanic fumaroles from Usu yolcaпo, Hokkaido, Japan, Proc. XI Int. Cong. oп Electron Microscopy, Kyoto, 1986, pp. 691–693.
Betekhtin, A.G., Mineralogy, Moscow: Gosgeolizdat, 1950.
Bobrov, A.B., Gursky, D.S., Goshovsky, S.V., Merkushin, I.E., Voloshin, A.V., Stepanyuk, L.N., Lysenko, A.A., and Fedorishin, Yu.I., Metal rhenium in natural geological systems: the first world experience of description on the example of the ultrabasic massifs of the Middle Pobuzh’ya (Ukrainian shield), Sb. Nauk. Pr. Ukr. Gos. Geologorazved. Inst., 2007, no. 2, pp. 60–82.
Bulakh, A.G., Rukovodstvo i tablitsy dlya rascheta formul mineralov (Manual and Tables for the Calculation of Mineral Formulas), Moscow: Nedra, 1964.
Chudin, S.S. and Voinov, V.N., Natural fullerenes of Northern Kazakhstan, Gorno-Geol. Zh., 2013, no. 1, pp. 7–10.
Dare, S.A.S., Barnes, S.-J., Prichard, H.M., and Fisher, P.C., The timing and formation of platinum-group minerals from the Creighton Ni–Cu–platinum-group element sulfide deposit, Sudbury, Canada: Early crystallization of PGE-rich sulfarsenides, Soc. Econ. Geologists, Inc. Econ. Geol., 2010, vol. 105, pp. 1071–1096.
Drábek, M., Rieder, M.B., and Hmova, V., The Re-Mo-S system: new data on phase relations between 400 and 1200°C, Eur. J. Mineral., 2010, vol. 22, pp. 479–484.
Ekström, M. and Hålenius, U., A new rhenium-rich sulfide from two Swedish localities, N. Jb. Mineral. Mn, 1982, vol. 1, pp. 6–10.
Fine, E.E., Rhenium and radiogenic osmium in the natural objects and technological processes, Extended Abstract of Doctoral (Geol.-Min) Dissertaion, Almaty, 1996.
Genkin, A.D., Poplavko, E.M., Gorshkov, A.N., Tsepin, A.N., and Sivtsov, A.V., New data on dzhezkazganite—sulfide of rhenium, molybdenum, copper, lead from the Dzhezkazgan deposit (Kazakhstan), Geol. Rudn. Mestorozhd., 1994, vol. 36, no. 26, pp. 536–544.
Grachev, A.F., Borisovskiy, S.E., and Grigor’eva, A.V., The first find of native rhenium in the transition layer of clays at the border of the Cretaceous and Paleogene in the Gams section (Eastern Alps, Austria), Dokl. Earth Sci., 2008, vol. 422, no. 1, pp. 1065–1067.
Gursky, D.S., Bobrov, O.B., Nakhlupin, V.G., Merkushin, I.E., Voloshin, O.V., Stepanyuk, L.M., and Lysenko, O.A., The first finding of noble rhenium in ultrabasic massifs of the Middle Bug area (Ukrainian shield), Mineral. Res. Ukr., 2007, no. 1, pp. 23–32.
Knunyants, I.L., Khimicheskaya Entsiklpediya (Soviet Encyclopedia), 1995, vol. 4, p. 639.
Kojonen, K.K., Roberts, A.C., Isomaki, O.P., Knauff, V.V., Johanson, B., and Pakkanen, L., Tarkianite, (Cu,Fe)(Re,Mo)4S8, a new mineral species from the Hitura mine, Nivala, Finland, Can. Mineral., 2004, vol. 42, pp. 539–544.
Korzhinsky, M.A., Tkachenko, S.I., Shmulovich, K.I., Taran, Yu.A., and Shteinberg, G.S., Discovery of pure rhenium mineral at Kudriavy volcano, Nature, 1994, vol. 369, pp. 51–52.
Kosyak, E.A., Composition of rhenium mineral from Dzhezkazgan ores, Zap. Vsesoyuz. Mineral. O-va, 1968, vol. 97, no. 2, pp. 213–216.
Kuleshevich, L.V., Lavrov, O.B., and Golubev, A.I., Voronov Bor gold-bearing copper–sulphide deposit and the prospects for the copper–sulfide occurrences of Karelia, In: Geologiya i poleznye iskopaemye Karelii (Geology and Minerals of Karelia), Petrozavodsk: KarRC RAS, 2009, vol. 12, pp. 27–47.
Lavrov, O.B. and Kuleshevich, L.V., The first finds of rhenium minerals in Karelia, Dokl. Earth Sci., 2010, vol. 432, no. 1, pp. 598–601.
Mitchell, R.H., Laflamme, J.H., and Cabri, L.J., Rhenium sulfide from the Coldwell Complex, northwester Ontario, Mineral. Mag., 1989, vol. 53, pp. 635–637.
Nsanov, R.A., Yttrium–Rare-Earth Mineralization in the Weathering Crust of the Mayatass Ore Field, Extended Abstract of Cand. (Geol.-Min) Diss., 1993.
Panagiotis, V., Vasilios, M., Paul, G.S., Luca, B., Robert, M., Melissa, O., and Tamara, K., Extremely Re-rich molybdenite from porphyry Cu–Mo–Au prospects in Northeastern Greece: Mode of occurrence causes of enrichment, and Implications for gold exploration, Minerals, 2013, vol. 3, pp. 165–191.
Peltonen, P., Pakkanen, L., and Johanson, B., Re–Mo–Cu–Os sulphide from the Ekojoki Ni-Cu deposit, SW Finland, Mineral. Petrol., 1995, vol. 52, pp. 257–264.
Poplavko, E.M., Ivanov, V.V., and Serkis, Yu.G., On geochemical features and conditions for the formation of copper sandstones and shale, Geokhimiya, 1977, no. 8, pp. 1217–1233.
Power, M.R., Pirrie, D., Jedwab, J., and Stanley, C.J., Platinum-group element mineralization in an As-rich magmatic sulfide system, Talnotry, southwest Scotland, Mineral. Mag., 2004, vol. 68, pp. 395–411.
Rafalson, M.B. and Sorokin, N.D., Determination of native rhenium in wolframite by the method of local X-ray spectral analysis, In: Voprosy geokhimii i tipomorfism mineralov (Problems of Geochemistry and Mineral Typomorphism), Leningrad: LSU, 1976, vol. 1, pp. 62–66.
Samotoin, N.D., Magazina, L.O., and Znamenskii, V.S., Structural and morphological characteristics of natural rhenium disulfide from fumarole of Kudryavyi volcano, Iturup Island, Kuril Islands, Dokl. Akad. Nauk, 1995, vol. 345, no. 4, pp. 518–522.
Samsonov, G.V. and Drozdova, S.V., Sul’fidy (Sulfides), Moscow: Metallurgy, 1972.
Stepanets, V.G., Levin, V.L., Bekenova, G.K., Li, E.S., Zhukov, N.M., and Khakimzhanov, M., Minerals of noble and rare elements in Karaturgay and Mayke ore types of Mayatas ore region (North Ulytau, Kazakhstan), News NAN PR. Series Geol. Techn., 2019, vol. 2, pp. 21–29.
Tarkian, M., Housley, R.M., Volborth, R.M., Greis, O., and Moh, G., Unnamed Re-Mo-Cu sulfide from the Stillwater Complex, and crystal chemistry of its synthetic equivalent spinel type (Cu, Fe)(Re, Mo)4S8, Eur. J. Mineral., 1991, vol. 3, pp. 977–982.
Turesebekov, A.Kh., Sharipov, Kh.T., Turamuratov, I.B., Luzanovsky, A.G., Vasilevsky, B.B., and Rakhimov, R.R., Rhenium of Uzbekistan, Gorn. Vestn. Uzbekistana, 2007, no. 1, pp. 14–21.
Vishnevskaya, I.I. and Trusova, I.F., West Ulytau belt of ultrabasic and basic rocks, Geol. Razvedka, 1967, no. 11, pp. 32–43.
Voudouris, P.C., Melfos, V., Spry, P.G., Bindi, L., Kartal, T., Arikas, K., Moritz, R., and Ortelli, M., Rheniumrich molybdenite and rheniite (ReS2) in the Pagoni Rachi-Kirki Mo–Cu–Te–Ag–Au deposit, Northern Greece: Implications for the rhenium geochemistry of porphyry style Cu–Mo and Mo mineralization, Can. Mineral., 2009, vol. 47, pp. 1013–1036.
Znamenskii, V.S., Korzhinsky, M.A., Shteinberg, G.S., Tka-chenko, S.I., Yakushev, A.I., Laputina, I.P., Bryzgalov, I.A., Samotoin, N.D., Magazina, L.O., Kuzmina, O.V., Organova, N.I., Rassulov, V.A., and Chaplygin, I.V., Rhenite, ReS2—natural rhenium disulphide from the fumarol of the Kudryavy volcano (Iturup island, Kuril Islands), Zap. Ross. Mineral. O-va, 2005, vol. 134, no. 5, pp. 32–391.
Znamenskii, V.S. and Yakushev, A.I., Das erste rhenium–mineral vom Vukan Kudriavy, Kurilen, Lapis, 2000, Jg. 25, no.1, pp. 21.
ACKNOWLEDGMENTS
The authors are grateful to the reviewers of the journal Zapiski RMO for friendly criticism that significantly improved the quality of the manuscript.
Funding
This work was supported by the Committee of Science of the Ministry of Education and Science of the Republic of Kazakhstan (project no. 0302/GF 4) “Creation of a Database on Unique, Rare, and Weakly Studied Minerals of Precious and Rare Metal Deposits of Kazakhstan for Comprehensive Exploration of Mineral Raw Materials.”
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Levin, V.L., Stepanets, V.G., Li, E.S. et al. Finding of Re Sulfides in Copper-Sulfide Ores of the Maike Occurrence, Ulytau, Central Kazakhstan. Geol. Ore Deposits 63, 830–841 (2021). https://doi.org/10.1134/S1075701521080067
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DOI: https://doi.org/10.1134/S1075701521080067