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Recent progress in dehydrogenation catalysts for heterocyclic and homocyclic liquid organic hydrogen carriers

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Abstract

Liquid organic hydrogen carriers (LOHC) are recently recognized as an attractive solution for H2 storage and transportation. Among several challenging tasks for practical application, the most stringent limitations stem from the dehydrogenation reaction requiring high temperatures thermodynamically. Unlike previous reviews focusing on the LOHC concept, LOHC molecules, and process integration, this review highlights the state-of-the-art catalysts reported for the dehydrogenation of homocyclic and heterocyclic LOHC molecules. In the conversion of heterocyclic LOHC, Pd-based catalysts overnumbered Pt-based ones owing to preferential adsorption of heteroatoms onto the Pd surface. However, because of low stability of C-heteroatom bonds, catalyst development needs to concentrate on inhibiting the generation of byproducts while maintaining superior performance under mild conditions. In the case of homocyclic LOHC, Pt is overwhelmed in single metal and bimetallic catalysts owing to pronounced C-H bond cleavage. Nevertheless, the ability of Pt in C-C bond cleavage should be diminished for higher H2 selectivity, better catalyst stability, and steady LOHC recyclability, which is possible by tuning electronic and geometric effects of main active metals, as well as adding metal promoters. Consequently, great efforts will be diversely devoted to achieving an active and stable dehydrogenation catalyst for future LOHC demonstration.

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Acknowledgements

This work was financially supported by the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT, Republic of Korea (NRF-2019M3E6A1064908), and by the Ministry of Education, Republic of Korea (NRF-2016R1A6A1 A03013422).

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  1. Equal contribution.

Authors and Affiliations

  1. Department of Chemical Engineering, Hanyang University, Seoul, 04763, Korea

    Yeongin Jo, Donghyeon Kim & Young-Woong Suh

  2. Center for Environment & Sustainable Resources Research, Korea Research Institute of Chemical Technology, Daejeon, 34114, Korea

    Jinho Oh & Ji Hoon Park

  3. Department of Chemical and Biological Engineering, Sookmyung Women’s University, Seoul, 04310, Korea

    Joon Hyun Baik

  4. Research Institute of Industrial Science, Hanyang University, Seoul, 04763, Korea

    Young-Woong Suh

Authors
  1. Yeongin Jo
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  2. Jinho Oh
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  3. Donghyeon Kim
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  4. Ji Hoon Park
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  5. Joon Hyun Baik
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Corresponding authors

Correspondence to Joon Hyun Baik or Young-Woong Suh.

Additional information

Young-Woong Suh obtained B.S. degree in Chemical Engineering from Hanyang University, Korea, in 1997, and received M.S. and Ph.D. degrees in Chemical Engineering from Seoul National University, Korea, in 1999 and 2003, respectively. From 2003 to 2006, he was a postdoctoral research associate at Northwestern University. He worked as a senior research scientist at the Korea Institute of Science and Technology until 2011. Then, he joined Hanyang University in 2011 and is currently a full professor in the Department of Chemical Engineering. He has published over 120 manuscripts in SCI journals, and 30 international and domestic patents. His research interests are in the area of heterogeneous catalysis including biomass conversion, chemical hydrogen storage, environmentally-friendly catalytic processing.

Joon Hyun Baik obtained B.S. degree in Chemical Engineering from Hanyang University, Korea, in 2001. He received M.S. and Ph.D. degrees in Chemical Engineering from Pohang University of Science and Technology (POSTECH), Korea, in 2003 and 2007, respectively. From 2007 to 2009, he was a postdoctoral fellow at MIT and Pennsylvania State University. He worked at Research Institute of Industrial Science and Technology (RIST) as senior researcher for 11 years from 2009 to 2020. He is currently an assistant professor in Department of Chemical & Biological Engineering of Sookmyung Women’s University. He has 37 papers and 38 patents regarding environmental catalysis, CO2 utilization, and catalytic hydrogenation technologies.

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Jo, Y., Oh, J., Kim, D. et al. Recent progress in dehydrogenation catalysts for heterocyclic and homocyclic liquid organic hydrogen carriers. Korean J. Chem. Eng. 39, 20–37 (2022). https://doi.org/10.1007/s11814-021-0947-5

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  • DOI: https://doi.org/10.1007/s11814-021-0947-5

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