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Processing Metallic Bismuth to Produce Citrate

  • TECHNOLOGY OF INORGANIC SUBSTANCES AND MATERIALS
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Abstract

Using chemical and XRD phase analysis, along with electron microscopy, the hydrolytic processing of metallic bismuth into high-purity citrate has been studied. A comparison of two synthesis methods is carried out for bismuth(III) citrate of BiC6H5O7 composition by precipitation from technological nitric acid solutions by the addition of a citric acid solution and by the reactions of solid bismuth oxohydroxonitrate–citric acid solution or bismuth oxide–lactic-citric acid solution mixtures.

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REFERENCES

  1. Mashkovskii, M.D., Lekarstvennye sredstva (Pharmaceutical Products), Moscow: Novaya Volna, 2011.

  2. Yukhin, Yu.M., Naydenko, E.S., Karpova, E.M., Frumin, L.E., Savel’eva, K.R., Khlyabich, G.N., and Shestakov, V.N., Antiulcer preparation based on bismuth(III) potassium dicitrate, Butlerovskie Soobshch., 2014, vol. 38, no. 4, pp. 87–93.

    Google Scholar 

  3. Chemnitius, F., Die Fabrikation der Wismutsalze, Pharm. Zentralhalle, 1927, vol. 68, no. 33, pp. 513–518.

    CAS  Google Scholar 

  4. Handbuch der Präparativen Anorganischen Chemie: in drei Bänden, Brauer, G., Ed., Stuttgart: Ferdinand Enke, 1978, vol. 2, 3rd ed.

    Google Scholar 

  5. Karyakin, Yu.V. and Angelov, I.I., Chistye khimicheskie veshchestva (Pure Chemical Substances), Moscow: Khimiya, 1974.

  6. Schwyzer, J., Die Fabrikation pharmazeutischer und chemisch-technischer Produkte, Berlin: Verlag von Julius Springer, 1931.

    Google Scholar 

  7. Turkevich, N.M., Soluble bismuth compounds: I. Bismuth citrate and its aquocompounds and ammine, Ukr. Khim. Zh., 1949, vol. 15, no. 2, pp. 243–247.

    Google Scholar 

  8. Yukhin, Yu.M., Afonina, L.I., Daminova, T.V., and Danilova, L.E., Precipitation of bismuth(III) citrate from nitrate solutions, Russ. J. Appl. Chem., 2000, vol. 73, no. 1, pp. 10–14.

    Google Scholar 

  9. Afonina, L.I., Naydenko, E.S., Yukhin, Yu.M., and Danilova, L.E., Synthesis of high-purity bismuth citrate using the solid–solution reaction, Khim. Interesakh Ustoich. Razvit., 2009, vol. 17, no. 3, pp. 243–249.

    CAS  Google Scholar 

  10. Yukhin, Yu.M., Shcherbakov, V.P., Naydenko, E.S., and Roguleva, T.V., RF Patent 2701013, Izobret., Polezn. Modeli, 2019, no. 27.

  11. Yukhin, Yu.M., Mishchenko, K.V., and Daminov, A.S., Bismuth preoxidation for preparing solutions of salts, Theor. Found. Chem. Eng., 2017, vol. 51, no. 4, pp. 495–502. https://doi.org/10.1134/S0040579517040303

    Article  CAS  Google Scholar 

  12. Daminov, A.S., Yukhin, Yu.M., and Naydenko, E.S., Processing of nitrate solutions for the preparation of basic bismuth nitrate and oxide, Theor. Found. Chem. Eng., 2020, vol. 54, pp. 1020–1025. https://doi.org/10.1134/S0040579520050097

    Article  CAS  Google Scholar 

  13. Korostelev, P.P., Fotometricheskii i kompleksometricheskii analiz v metallurgii (Photometric and Complexometric Analysis in Metallurgy), Moscow: Metallurgiya, 1984.

  14. GOST (State Standard) 18826-73: Drinking Water. Methods for Determination of Nitrates Content, 2003.

  15. Ashworth, M.R.F., Titrimetric Organic Analysis: Part 2. Indirect Methods, Chemical Analysis: A Series of Monographs on Analytical Chemistry and Its Applications, vol. 15, New York: Wiley-Interscience, 1965.

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Authors and Affiliations

  1. Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, 630128, Novosibirsk, Russia

    Yu. M. Yukhin & E. S. Koledova

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  1. Yu. M. Yukhin
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  2. E. S. Koledova
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Correspondence to Yu. M. Yukhin.

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Translated by F. Baron

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Yukhin, Y.M., Koledova, E.S. Processing Metallic Bismuth to Produce Citrate. Theor Found Chem Eng 55, 979–984 (2021). https://doi.org/10.1134/S0040579521050195

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  • DOI: https://doi.org/10.1134/S0040579521050195

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