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Synthesis of Nickel–Carbon Nanocomposites Using the Mechanical Treatment of Polyvinyl Chloride in the Presence of Nickel Nitrate and Diethylamine

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Abstract

The dehydrochlorination of polyvinyl chloride with diethylamine in the presence of nickel nitrate was carried out on mechanical processing in a high-energy planetary mill. The subsequent heat treatment of the resulting product to 400°C led to the formation of a metal–carbon nanocomposite, in which nickel nanoparticles 50–100 nm in diameter were distributed in an amorphous carbon matrix. The nickel–carbon nanocomposite exhibited catalytic activity in the process of methane conversion at 800°C. Deposits of ordered nanosized carbon structures of two types were observed on metal particles: a graphite-like shell containing up to 80 layers with an interlayer distance of 0.36 nm and bamboo-like nanotubes with a diameter of 30–80 nm. The structure of the resulting products was investigated by transmission and scanning electron microscopy.

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ACKNOWLEDGMENTS

Physicochemical research methods were carried out using the instrumentation base of the Omsk Regional Center for Collective Use of the Siberian Branch of the Russian Academy of Sciences. We are grateful to T.I. Gulyaeva and R.R. Izmailov for their assistance in the experiments.

Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of a state contract of the Institute of Catalysis, Siberian Branch, Russian Academy of Sciences (project no. AAAA-A21-121011490008-3).

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Authors and Affiliations

  1. Center of New Chemical Technologies, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 644040, Omsk, Russia

    E. S. Zapevalova, M. V. Trenikhin & Yu. G. Kryazhev

Authors
  1. E. S. Zapevalova
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  2. M. V. Trenikhin
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  3. Yu. G. Kryazhev
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Corresponding authors

Correspondence to E. S. Zapevalova, M. V. Trenikhin or Yu. G. Kryazhev.

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Translated by V. Makhlyarchuk

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Zapevalova, E.S., Trenikhin, M.V. & Kryazhev, Y.G. Synthesis of Nickel–Carbon Nanocomposites Using the Mechanical Treatment of Polyvinyl Chloride in the Presence of Nickel Nitrate and Diethylamine. Solid Fuel Chem. 55, 374–379 (2021). https://doi.org/10.3103/S036152192106015X

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