Issue 24, 2021
From the journal:

Organic Chemistry Frontiers

Metal-hydride hydrogen atom transfer (MHAT) reactions in natural product synthesis

Jinghua Wua  and  Zhiqiang Ma ORCID logo *a  

* Corresponding authors

a Key Lab of Functional Molecular Engineering of Guangdong Province, School of Chemistry & Chemical Engineering, South China University of Technology, Wushan Road-381, Guangzhou 510641, People's Republic of China
E-mail: cezqma@scut.edu.cn

Abstract

The metal-hydride hydrogen atom transfer (MHAT) reaction plays an important role in the field of natural product synthesis. MHAT, as a powerful method, has been employed by chemists to construct C–C, C–H, and C–heteroatom bonds. In this review, we summarize the recent total synthesis of natural products using MHAT to functionalize olefins with first-row transition metal catalysts such as cobalt, manganese and iron.

Graphical abstract: Metal-hydride hydrogen atom transfer (MHAT) reactions in natural product synthesis

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Article information

DOI
https://doi.org/10.1039/D1QO01139A
Article type
Review Article
Submitted
02 Aug 2021
Accepted
05 Oct 2021
First published
09 Oct 2021

Org. Chem. Front., 2021,8, 7050-7076

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Metal-hydride hydrogen atom transfer (MHAT) reactions in natural product synthesis

J. Wu and Z. Ma, Org. Chem. Front., 2021, 8, 7050 DOI: 10.1039/D1QO01139A

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