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Synthesis and Crystal Structure of Cadmium(II) Metal-Organic Coordination Polymers with Octafluorobiphenyl-4,4'-Dicarboxylate

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Abstract

The reaction between equimolar amounts of Cd(OH)2 and octafluorobiphenyl-4,4'-dicarboxylic acid H2oFBPDC in methanol at 40 and 70°С has been investigated. Two new metal-organic coordination polymers have been obtained and structurally characterized, namely chain-like [Cd3(CH3OH)10(oFBPDC)3]⋅2CH3OH (I) and layered [Cd(CH3OH)3(oFBPDC)] (II). It is shown that the increase of the temperature of the synthesis leads to the formation of coordination polymer of higher dimensionality with less amount of guest and coordinated solvent molecules.

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Funding

This work was supported by the Russian Foundation for Basic Research and the Government of the Novosibirsk Region, project no. 20-43-540004.

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Authors and Affiliations

  1. Novosibirsk State University, 630090, Novosibirsk, Russia

    V. S. Gusarov

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    A. M. Cheplakova, D. G. Samsonenko & V. P. Fedin

  3. N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    A. S. Vinogradov

Authors
  1. V. S. Gusarov
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  2. A. M. Cheplakova
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  3. D. G. Samsonenko
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  4. A. S. Vinogradov
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  5. V. P. Fedin
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Corresponding author

Correspondence to V. P. Fedin.

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Translated by V. Avdeeva

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Gusarov, V.S., Cheplakova, A.M., Samsonenko, D.G. et al. Synthesis and Crystal Structure of Cadmium(II) Metal-Organic Coordination Polymers with Octafluorobiphenyl-4,4'-Dicarboxylate. Russ. J. Inorg. Chem. 66, 1374–1379 (2021). https://doi.org/10.1134/S0036023621090035

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  • DOI: https://doi.org/10.1134/S0036023621090035

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