Abstract
An efficient method was presented to perform the hydrothermal synthesis of a nanocrystalline SrWO4 powder with the scheelite structure and the spark plasma sintering (SPS) of ceramics based on it. The composition, morphology, and structure of samples under various synthesis temperature conditions were studied by X-ray powder diffraction analysis, scanning electron microscopy, and energy-dispersive spectroscopy. The efficiency of the ultrafast (several minutes long) sintering of the nanocrystalline SrWO4 powder was described by the dynamics of its consolidation as a function of the SPS time and temperature. The temperature of formation was determined for a single-phase SrWO4 ceramic with a high relative density and a low strontium leaching rate of less than 10–6 g/(cm2 day), which is in demand as matrices for the reliable immobilization of the high-energy radionuclide strontium-90. For the first time, a method was implemented to produce a sample of a SrWO4 ceramic–high-alloy steel coupled composite by SPS as a test article of an open ionizing radiation source. The method consists in the diffusion sintering of materials within a single step at 1000°C for 5 min with the mandatory use of a sintering additive in the form of a mixture of metals (70 wt % Ti + 30 wt % Ag). The results of this work showed the possibility of developing a high-tech solution for the production of high-performance radioisotope products by SPS.
Similar content being viewed by others
REFERENCES
V. S. Semenishchev and A. V. Voronina, Isotopes of Strontium: Properties and Applications, Ed. by P. Pathak and D. K. Gupta (Springer Nature, 2020). https://doi.org/10.1007/978-3-030-15314-4_2).
E. V. Steinfelds, M. A. Prelas, S. K. Loyalka, et al., in Proceedings of the International Congress on Advances in Nuclear Power Plants ICAPP’06, 2006, p. 2696.
O. H. Kyuhak, M. A. Prelas, J. B. Rothenberger, et al., Nucl. Technol. 179, 234 (2012). https://doi.org/10.13182/nt12-a14095
S. J. DeNardo and G. L. DeNardo, Int. J. Radiat. Oncol. Biol. Phys. 66, 89(2006). https://doi.org/10.1016/j.ijrobp.2006.03.066
H. S. Chong, X. Sun, Y. Chen, et al., Bioorg. Med. Chem. 23, 1169 (2015). https://doi.org/10.1016/j.bmc.2014.12.035
R. M. V. Silva, W. Belinato, W. S. Santos, et al., Radiat. Phys. Chem. 167, 108235 (2020). https://doi.org/10.1016/j.radphyschem.2019.03.039
C. M. Jantzen, Radioactive Waste Management and Contaminated Site Clean-Up, Ed. by W. Lee, M. Ojovan, and C. Jantzen (Woodhead Publishing Limited, 2013). https://doi.org/10.1533/9780857097446.1.171
I. W. Donald, Waste Immobilization in Glass and Ceramic Based Hosts Radioactive, Toxic and Hazardous Wastes (John Wiley & Sons Ltd, Chichester, 2010). https://doi.org/10.1002/9781444319354
D. Caurant, P. Loiseau, O. Majerus, et al., Glasses, Glass-Ceramics and Ceramics for Immobilization of Highly Radioactive Nuclear Wastes (Nova Publishers, 2009).
A. I. Orlova, A. A. Lizin, S. V. Tomilin, et al., Radiochemistry 53, 63 (2011). https://doi.org/10.1134/S1066362211010085
D. J. Gregg, I. Karatchevtseva, G. J. Thorogood, et al., J. Nucl. Mater. 446, 224 (2014). https://doi.org/10.1016/j.jnucmat.2013.11.048
A. I. Orlova, Structural Chemistry of Inorganic Actinide Compounds, Ed. by S. V. Krivovichev, P. C. Burns, and I. G. Tananaev (Elsevier, 2007). https://doi.org/10.1016/B978-044452111-8/50009-0
A. I. Orlova, N. V. Malanina, V. N. Chuvil’deev, et al., Radiochemistry 56, 380 (2014). https://doi.org/10.1134/S1066362214040043
A. I. Orlova and M. I. Ojovan, Materials (Basel) 12, 2638 (2019). https://doi.org/10.3390/ma12162638
Dos. Damascena, R. H. Passos, M. Arab, De. Pereira, C. Souza, et al., Acta Crystallogr., Sect. B 73, 466 (2017). https://doi.org/10.1107/S2052520617002827
E. A. Potanina, A. I. Orlova, A. V. Nokhrin, et al., Ceram. Int. 44, 4033 (2018). https://doi.org/10.1016/j.ceramint.2017.11.199
E. A. Potanina, A. I. Orlova, A. V. Nokhrin, et al., Russ. J. Inorg. Chem. 64, 296 (2019). https://doi.org/10.1134/S0036023619030161
E. A. Potanina, A. I. Orlova, D. A. Mikhailov, et al., J. Alloys Compd. 774, 182 (2019). https://doi.org/10.1016/j.jallcom.2018.09.348
G. Flor, V. Massarotti, and R. Riccardi, J. Phys. Sci. 29, 503 (1974). https://doi.org/10.1515/zna-1974-0322
T. Thongtem, S. Kungwankunakorn, B. Kuntalue, et al., J. Alloys Compd. 506, 475 (2010). https://doi.org/10.1016/j.jallcom.2010.07.033
X. Li, Z. Song, and B. Qu, Ceram. Int. 40, 1205 (2014). https://doi.org/10.1016/j.ceramint.2013.05.102
L. D. Feng, X. B. Chen, and C. J. Mao, Mater. Lett. 64, 2420 (2010). https://doi.org/10.1016/j.matlet.2010.08.024
A. Lan, B. Li, H. Shen, et al., J. Mater. Sci. Mater. Electron. 26, 1695 (2015). https://doi.org/10.1007/s10854-014-2595-6
L. S. Cavalcante, J. C. Sczancoski, N. C. Batista, et al., Adv. Powder Technol. 24, 344 (2013). https://doi.org/10.1016/j.apt.2012.08.007
H. Feng, Y. Yang, and X. Wang, Ceram. Int. 40, 10115 (2014). https://doi.org/10.1016/j.ceramint.2014.01.129
J. Liao, B. Qiu, H. Wen, et al., Mater. Res. Bull. 44, 1863 (2009). https://doi.org/10.1016/j.materresbull.2009.05.013
E. A. Olevsky and D. V. Dudina, Field-Assisted Sintering: Science and Applications (Springer, 2018). https://doi.org/10.1007/978-3-319-76032-2
E. A. Olevsky, S. Kandukuri, and L. Froyen, J. Appl. Phys. 102, 114913 (2007). https://doi.org/10.1063/1.2822189
Z. Y. Hu, Z. H. Zhang, X. W. Cheng, et al., Mater. Des. 191, 108662 (2020). https://doi.org/10.1016/j.matdes.2020.108662
V. G. Sevastyanov, E. P. Simonenko, A. N. Gordeev, et al., Russ. J. Inorg. Chem. 59, 1361 (2014).
T. L. Simonenko, M. V. Kalinina, N. P. Simonenko, et al., Int. J. Hydrogen Energy 44, 20345 (2019). https://doi.org/10.1016/j.ijhydene.2019.05.231
N. A. Safronova, O. S. Kryzhanovska, M. V. Dobrotvorska, et al., Ceram. Int. 46, 6537 (2020). https://doi.org/10.1016/j.ceramint.2019.11.137
E. K. Papynov, O. O. Shichalin, M. A. Medkov, et al., Glass Phys. Chem. 44, 632 (2018). https://doi.org/10.1134/S1087659618060159
D. V. Dudina and A. K. Mukherjee, J. Nanomater. 2013, 625218 (2013). https://doi.org/10.1155/2013/625218
E. K. Papynov, O. O. Shichalin, I. Y. Buravlev, et al., Russ. J. Inorg. Chem. 65, 263 (2020). https://doi.org/10.1134/S0036023620020138
E. P. Simonenko, N. P. Simonenko, E. K. Papynov, et al., J. Sol-Gel Sci. Technol. 82, 748 (2017). https://doi.org/10.1007/s10971-017-4367-2
N. P. Shapkin, E. K. Papynov, O. O. Shichalin, et al., Russ. J. Inorg. Chem. 66, 629 (2021). https://doi.org/10.1134/S0036023621050168
A. I. Orlova, A. N. Troshin, D. A. Mikhailov, et al., Radiochemistry 56, 98 (2014). https://doi.org/10.1134/S1066362214010196
V. I. Pet’kov, E. A. Asabina, A. A. Lukuttsov, et al., Radiochemistry 57, 632 (2015). https://doi.org/10.1134/S1066362215060119
O. O. Shichalin, E. K. Papynov, V. Y. Maiorov, et al., Radiochemistry 61, 185 (2019). https://doi.org/10.1134/S1066362219020097
E. K. Papynov, Glass-Ceramics: Properties, Applications and Technology, Ed. by K. N. Y. Narang (Nova Science Publishers, 2018).
A. I. Orlova, A. K. Koryttseva, A. E. Kanunov, et al., Inorg. Mater. 48, 313 (2012). https://doi.org/10.1134/S002016851202015X
E. A. Potanina, A. I. Orlova, A. V. Nokhrin, et al., Ceram. Int. 44, 4033 (2018). https://doi.org/10.1016/j.ceramint.2017.11.199
M. C. Stennett, I. J. Pinnock, and N. C. Hyatt, J. Nucl. Mater. 414, 352 (2011). https://doi.org/10.1016/j.jnucmat.2011.04.041
R. C. O’Brien, R. M. Ambrosi, N. P. Bannister, et al., J. Nucl. Mater. 393, 108 (2009). https://doi.org/10.1016/j.jnucmat.2009.05.012
J. Amoroso, J. C. Marra, M. Tang, et al., J. Nucl. Mater. 454, 12 (2014). https://doi.org/10.1016/j.jnucmat.2014.07.035
B. M. Clark, P. Tumurugoti, J. W. Amoroso, et al., Metall. Mater. Trans. E 1, 341 (2014). https://doi.org/10.1007/s40553-014-0035-4
E. K. Papynov, O. O. Shichalin, I. Y. Buravlev, et al., Vacuum 180, 109628 (2020). https://doi.org/10.1016/j.vacuum.2020.109628
E. K. Papynov, A. A. Belov, O. O. Shichalin, et al., Nucl. Eng. Technol. 53, 2289 (2021). https://doi.org/10.1016/j.net.2021.01.024
S. K. Sun, M. C. Stennett, C. L. Corkhill, et al., J. Nucl. Mater. 500, 11 (2018). https://doi.org/10.1016/j.jnucmat.2017.12.021
L. C. Harnett, L. J. Gardner, S. K. Sun, et al., J. Nucl. Sci. Technol. 56, 891 (2019). https://doi.org/10.1080/00223131.2019.1602484
E. K. Papynov, A. A. Belov, O. O. Shichalin, et al., 66, 645 (2021). https://doi.org/10.1134/S0036023621050132
E. K. Papynov, O. O. Shichalin, V. Y. Mayorov, et al., J. Hazard. Mater. 369, 25 (2019). https://doi.org/10.1016/j.jhazmat.2019.02.016
T. Ungár, Mater. Sci. Forum 278–281, 151 (1998). https://doi.org/10.4028/www.scientific.net/msf.278-281.151
C. Thieme, A. Erlebach, C. Patzig, et al., CrystEngComm 20, 4565 (2018). https://doi.org/10.1039/c8ce00512e
O. M. Ivasishin, S. V. Shevchenko, N. L. Vasiliev, et al., Acta Mater. 51, 1019 (2003). https://doi.org/10.1016/S1359-6454(02)00505-0
F. Wakai, N. Enomoto, and H. Ogawa, Acta Mater. 48, 1297 (2000). https://doi.org/10.1016/S1359-6454(99)00405-X
H. Eichelkraut, G. Abbruzzese, and K. Lucke, Acta Metall. 36, 55 (1988). https://doi.org/10.1016/0001-6160(88)90028-4
V. N. Chuvil’deev, Y. V. Blagoveshchenskiy, A. V. Nokhrin, et al., J. Alloys Compd. 708, 547 (2017). https://doi.org/10.1016/j.jallcom.2017.03.035
A. V. Nokhrin, Tech. Phys. Lett. 38, 630 (2012). https://doi.org/10.1134/S1063785012070073
J. D. Fan, H. J. Zhang, J. Y. Wang, et al., J. Appl. Phys. 100, 063513 (2006). https://doi.org/10.1063/1.2335510
V. Y. Ilichev, V. P. Popov, L. V. Skibina, et al., Cryogenics (Guildf) 18, 90 (1978). https://doi.org/10.1016/0011-2275(78)90116-9
ACKNOWLEDGMENTS
The studies in this work were made using the equipment at the Shared Equipment Center, the Far Eastern Federal University, Vladivostok, Russia, and the Interdisciplinary Center for Nanotechnology and New Functional Materials, Far Eastern Federal University, Vladivostok, Russia. Some of the measurements of experimental data (X-ray powder diffraction and atomic absorption analysis) were carried out on instruments of the Shared Equipment Center “Far Eastern Center for Structural Research” (Institute of Chemistry, Far Eastern Branch, Russian Academy of Science, Vladivostok, Russia) within the framework of mutual cooperation.
The authors are grateful to the staff of the Institute of Chemistry of the Far East Branch of the Russian Academy of Sciences, Ph.D. Parot’kina Yu.A. and Ph.D. Shlyk D.Kh. for carrying out X-ray powder diffraction and atomic absorption studies and provision of experimental data obtained on devices.
Funding
This work was supported under a state assignment of the Ministry of Science and Higher Education of the Russian Federation (subject no. 00657-2020-0006).
The X-ray powder diffraction analysis and atomic adsorption analysis of samples was performed under a state assignment of the Institute of Chemistry, Far-Eastern Branch, Russian Academy of Sciences, Vladivostok, Russia (subject 0205-2021-0001).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Additional information
Translated by V. Glyanchenko
Rights and permissions
About this article
Cite this article
Papynov, E.K., Shichalin, O.O., Belov, A.A. et al. Synthesis of Mineral-Like SrWO4 Ceramics with the Scheelite Structure and a Radioisotope Product Based on It. Russ. J. Inorg. Chem. 66, 1434–1446 (2021). https://doi.org/10.1134/S0036023621090114
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023621090114