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Characteristic Features of Fixation of Ammonia by Copper(II), Nickel(II), and Cobalt(II) Ions in Pivalates

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Abstract

The reaction of adduct Cu2(OOCBut)4(thf)2 with polynuclear nickel(II) pivalate (prepared from NiCl2, HOOCBut, and KOH) or cobalt(II) pivalate (prepared by thermolysis of Co(II) acetate with excess acid at 160°C) in THF with a large excess of aqueous ammonia at room temperature leads to the formation of the mononuclear molecular complex Cu(OOCBut)2(NH3)2, the ionic complex [Ni(NH3)6](OOCBut)2, and unusual mixed-valence trinuclear complex {CoII(OOCBut)2(NH3)2[(µ-OH)CoIII(NH3)5]2}(OOCBut)4(H2O)2. The products were investigated by chemical analysis, X-ray diffraction, and IR spectroscopy.

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ACKNOWLEDGMENTS

X-ray diffraction and the IR spectral studies were carried out using the equipment of the Center for Collective Use of Physical Methods of Investigation of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, which is supported by the state assignment for the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences.

Funding

This study was performed within the State assignment for the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences in the field of fundamental research.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    S. E. Nefedov & I. L. Eremenko

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  1. S. E. Nefedov
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  2. I. L. Eremenko
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Correspondence to S. E. Nefedov.

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Translated by Z. Svitanko

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Nefedov, S.E., Eremenko, I.L. Characteristic Features of Fixation of Ammonia by Copper(II), Nickel(II), and Cobalt(II) Ions in Pivalates. Russ. J. Inorg. Chem. 66, 1380–1389 (2021). https://doi.org/10.1134/S0036023621090084

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