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Zinc(II) and Cadmium(II) Coordination Compounds with Boron Cluster Anions: Classification of Compounds Depending on Strength of Metal–Boron Cage Interaction and Analysis of Structures (Review)

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Abstract

Data on the synthesis and structures of Zn(II) and Cd(II) complexes with boron cluster anions [BnHn]2– (n = 6, 10, 12), their substituted derivatives, as well as analogs—carboranes and metallaboranes—in the presence of competitive organic ligands are generalized and summarized. The synthesis and structural features of the obtained compounds, isomeric composition of the compounds, and influence of the reaction conditions on the composition and structures of the final products are discussed. A classification of compounds is given depending on the strength of the metal–boron cage interaction.

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Funding

The work was carried out within the framework of the State Assignment of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences in the field of fundamental scientific research.

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  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    S. E. Korolenko, V. V. Avdeeva, E. A. Malinina & N. T. Kuznetsov

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  1. S. E. Korolenko
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Correspondence to S. E. Korolenko.

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Translated by V. Avdeeva

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Korolenko, S.E., Avdeeva, V.V., Malinina, E.A. et al. Zinc(II) and Cadmium(II) Coordination Compounds with Boron Cluster Anions: Classification of Compounds Depending on Strength of Metal–Boron Cage Interaction and Analysis of Structures (Review). Russ. J. Inorg. Chem. 66, 1350–1373 (2021). https://doi.org/10.1134/S0036023621090047

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