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Layered Li–Ni–Mn–Co oxide cathodes

Almost 30 years since the inception of lithium-ion batteries, lithium–nickel–manganese–cobalt oxides are becoming the favoured cathode type in automobile batteries. Their success lies primarily with their superior energy density relative to lithium–cobalt oxide, lithium–manganese oxide and lithium–iron phosphate electrodes.

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References

  1. Goodenough, J. B. & Mizushima, K. Electrochemical cell with new fast ion conductors. US patent 4,302,518 (1980).

  2. Ohzuku, T., Ueda, A., Nagayama, M., Iwakoshi, Y. & Komori, H. Electrochim. Acta 38, 1159–1167 (1993).

    Article  Google Scholar 

  3. Rossen, E., Jones, C. D. W. & Dahn, J. R. Solid State Ionics 57, 311–318 (1992).

    Article  Google Scholar 

  4. Rossouw, M. H., Liles, D. C. & Thackeray, M. M. J. Solid State Chem. 104, 464–466 (1993).

    Article  Google Scholar 

  5. Armstrong, A. R. & Bruce, P. G. Nature 381, 499–500 (1996).

    Article  Google Scholar 

  6. Thackeray, M. M., Johnson, C. S., Amine, K. & Kim, J. Lithium metal oxide electrodes for lithium cells and batteries. US patent 6,677,082 (2004, filed 2000).

  7. Paulsen, J. M., Lieu, K. Y & Ammundsen, B. G. Lithiated oxide materials and methods of manufacture. US patent 6,660,432 (2003, filed 2000).

  8. Lu, Z. & Dahn, J. R. Cathode compositions for Li-ion batteries. US patent 6,964,828 (2005, filed 2001).

  9. Ohzuku, T., Yoshizawa, H. & Nagayama, M. Lithium nickel manganese cobalt oxide positive electrode active material. US patent 7,935,443 (2011, filed 2001).

  10. Ohzuku, T. & Makimura, Y. Chem. Lett. 30, 642–643 (2001).

    Article  Google Scholar 

  11. Thackeray, M. M., Johnson, C. S., Vaughey, J. T., Li, N. & Hackney, S. A. J. Mater. Chem. 15, 2257–2267 (2005).

    Article  Google Scholar 

  12. Ammundsen, B. & Paulsen, J. Adv. Mater. 13, 943–956 (2001).

    Article  Google Scholar 

  13. NMC Lithium-Ion Batteries Patent Landscape (KnowMade, 2017); https://www.knowmade.com/downloads/nmc-lithium-ion-batteries

  14. USABC Low-Cost/Fast-Charge EV Goals (USCAR, 2017); http://www.uscar.org/guest/article_view.php?articles_id=85

  15. Myung, S.-T. et al. ACS Energy Lett. 2, 196–223 (2017).

    Article  Google Scholar 

  16. Sun, Y.-K. et al. Nat. Mater. 11, 942–947 (2012).

    Article  Google Scholar 

  17. Croy, J. R. et al. J. Power Sources 434, 226706 (2019).

    Article  Google Scholar 

  18. Lu, Z. & Dahn, J. R. J. Electrochem. Soc. 149, A815 (2002).

    Article  Google Scholar 

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Correspondence to Michael M. Thackeray or Khalil Amine.

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Thackeray, M.M., Amine, K. Layered Li–Ni–Mn–Co oxide cathodes. Nat Energy 6, 933 (2021). https://doi.org/10.1038/s41560-021-00860-3

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