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Assembly of Two New Coordination Polymers: Luminescent Properties and Application Values on Postoperative Infectious Endophthalmitis

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Abstract

The solvothermal reactions via the self-assemble approach produced two new metal–organic compounds, i.e., [Zn(4-cptpy)(HCOO)(H2O)]n·(DMF)n (1) and [Cd3(btc)2(4-cptpyH)(DMF)(H2O)3]n (2) (DMF is N,Nʹ-dimethylformamide, H3btc is benzene-1,3,5-tricarboxylic acid, and 4-Hcptpy is 4-[2,6-bis(pyridine-4-yl)pyridine-4-yl]benzoic acid). Furthermore, the compounds’ luminescent performances have also been studied. Their application values against postoperative infectious endophthalmitis (PIE) were assessed and the related mechanism was explored at the same time. First of all, the activation levels of nuclear factor kappa-B (NF-κb) signaling pathway was measured with real time reverse transcription-polymerase chain reaction (RT-PCR) assay. In addition to this, the enzyme linked immunosorbent assay (ELISA) detection kit was further conducted and the and the content of inflammatory cytokines released after the cataract surgery was determined. The cytotoxicity of the compounds was also detected with CCK-8 assay.

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Data Availability

Selected bond lengths (Å) and angles (°) for compound 1 (Table S1); The hydrogen bonding parameters for compound 1 (Table S2); The coordination modes of the organic ligands (a) for compound 1 (b) and (c) for compound 2 (Fig. S1); The twofold interpenetrated hcb network for 1 (Fig. S2); The dinuclear [Cd2(COO)2] subunit in compound 2 (Fig. S3); The PXRD patterns (a) for compound 1 and (b) for compound 2 (Fig. S4); IR spectra of complexes 1 and 2 (Fig. S5); SEM diagram for the treated complexes 1 and 2 (Fig. S6); DLS data of DMSO dispersed solution of complexes 1 and 2 (Fig. S7), the information could be found in the supporting information file.

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Author notes

  1. Guang-Qing Bian and Shi-Xi Zhang contributed equally to this work.

Authors and Affiliations

  1. Department of Ophthalmology, The First Affiliated Hospital of Shandong First Medical University & Shandong Provincial Qianfoshan Hospital, Jinan, Shandong, China

    Guang-Qing Bian & Xiao-Li Qu

  2. Department of Ophthalmology, Aier Eye Hospital of Dezhou, Dezhou, Shandong, China

    Shi-Xi Zhang

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  1. Guang-Qing Bian
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Correspondence to Guang-Qing Bian.

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Bian, GQ., Zhang, SX. & Qu, XL. Assembly of Two New Coordination Polymers: Luminescent Properties and Application Values on Postoperative Infectious Endophthalmitis. J Inorg Organomet Polym 32, 75–84 (2022). https://doi.org/10.1007/s10904-021-02107-w

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  • DOI: https://doi.org/10.1007/s10904-021-02107-w

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