Abstract
The present work focuses the study of effect of solvent on third-order nonlinear optical (NLO) properties of reactive blue 19 dye dissolved in various polar solvents, namely ethanol, DMF and DMSO, respectively. Fourier Transform Infrared Spectroscopy (FT-IR) was used to find the functional groups present in reactive blue 19 dye. Third-order NLO features of reactive blue 19 dye was examined by a low power continuous wave laser of 650 nm wavelength. Reactive blue 19 dye exhibit negative nonlinear index of refraction of the power of 10−7 cm2/W and the nonlinear coefficient of absorption of the order of 10−3 cm/W. Both positive and negative nonlinear absorption coefficient of reactive blue 19 dye in different polar solvents is due to the characteristic behavior of saturable and reverse saturable absorption. Third-order NLO susceptibility of reactive blue 19 dye in polar solvents was determined to be the power of 10−6 esu. The experimental results reveal that the dye sample reactive blue 19 is a potential material for nonlinear optical applications.
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References
Kramer MA, Tompkin WR, Boyd RW (1986) Nonlinear optical interactions in fluorescein-doped boric acid glass. Phys Rev A 34: 2026–2031. https://doi.org/10.1103/physreva.34.2026
Sreenath MC, Hubert Joe I, Rastogi VK (2018) Third-order optical nonlinearities of 1,-diaminoanthraquinone for optical limiting applications. Opt Laser Technol 108:218–234. https://doi.org/10.1016/j.optlastec.2018.06.056
Jeyaram S, Hemalatha S, Geethakrishnan T (2020) Nonlinear refraction, absorption and optical limiting properties of disperse blue 14 dye. Chem Phys Lett 739:137037. https://doi.org/10.1016/j.cplett.2019.137037
Zongo S, Sanusi K, Britton J, Mthunzi P, Nyokong T, Maaza M, Sahraoui B (2015) Nonlinear optical properties of natural laccaic dye studied using Z-scan technique. Opt Mater 46:270–275. https://doi.org/10.1016/j.optmat.2015.04.031
Jeyaram S (2021) Intermolecular charge transfer in donor-acceptor substituted triarylmethane dye for NLO and optical limiting applications. J Mater Sci Mater Elect 32:9368–9376. https://doi.org/10.1007/s10854-021-05600-7
Ryasnyansky AI, Palpant B, Debrus S, Khalibullin R, Stepanov RL (2006) Nonlinear optical properties of copper nanoparticles synthesized in indium tin oxide matrix by ion implantation. J Opt Soc Am B 23:1348–1353. https://doi.org/10.1364/JOSA.23.001348
Jeyaram S, Geethakrishnan T (2020) Spectral and third-order nonlinear optical characteristics of natural pigments extracted from coriandrum sativum. Opt Mater 107:110148. https://doi.org/10.1016/j.optmat.2020.110148
He GS, Xu GS, Prasad PN, Reinhardt BA, Bhatt JC, Dillard AG (1995) Two-photon absorption and optical limiting properties of novel organic compounds. Opt Lett 20:435–437. https://doi.org/10.1364/ol.20.000435
Bredas JL, Adant C, Tackx P, Persoons A, Pierce BM (1994) Third-order nonlinear optical response in organic materials: theoretical and experimental aspects. Chem Rev 94:243–278. https://doi.org/10.1021/cr00025a0080
Davies RL, Samoc M (1997) Third-order nonlinear optical organic materials for photonic switching. Curr Opin Solid State Mater Sci 2:213–219. https://doi.org/10.1016/S1359-0286(97)80068-X
Jeyaram S, Geethakrishnan T (2017) Third-order nonlinear optical properties of acid green 25 dye using Z-scan method. Opt Laser Technol 89:179–185. https://doi.org/10.1016/j.optlastec.2016.10.006
Liu J, Gao B, Cheng Y, Xie Z, Geng Y, Wang L, Jing X, Wang F (2008) Novel white electroluminescent single polymer derived from fluorine and quinacridone. Macromolecules 41:1162–1167. https://doi.org/10.1021/ma071235z
Pho TV, Zalar P, Garcia A, Nguyen TQ, Wudl F (2010) Electron injection barrier reduction for organic light-emitting devices by quinacridone derivaties. Chem Commun 46:8210–8212. https://doi.org/10.1039/c0cc01596b
Jia J, Feng D, Sha Y, Zhou C, Liang G, She Y (2020) New quinacridone derivatives: synthesis, photophysical and third-order nonlinear optical properties. Tetrahedron 76:131057. https://doi.org/10.1016/j.tet.2020.131057
Jeyaram S, Geethakrishnan T (2020) Solvent dependent linear and nonlinear optical characteristics of acid blue 3 dye. J. Fluores 30: 1161–1169. https://doi.org/10.1007/s10895-020-02580-5
Khadem Sadigh M, Zakerhamidi MS (2017) Environmental effects on the nonlinear absorption properties of Methylene blue under different power of excitation beam. J Mol Liq 229:548–554. https://doi.org/10.1016/j.molliq.2016.12.18
Jeyaram S (2021) Study of third-order nonlinear optical properties of basic violet 3 dye in polar protic and aprotic solvents. J Fluoresc. https://doi.org/10.1007/s10895-021-02796-z
Sheik-Bahae M, Said AA, Wei T, Hagan DJ, Van Stryland EM (1990) Sensitive measurement of optical nonlinearities using a single beam. IEEE J Quant Elect 26:760–769. https://doi.org/10.1109/3.53394
Sheik-Bahae M, Said AA, Van Stryland EM (1989) High-sensitive single beam n2 measurements. Opt Lett 14:955–957. https://doi.org/10.1364/OL.14.000955
Pramodini S, Poornesh P (2013) Thermally induced nonlinear optical response and optical limiting of acid blue 40. Curr Appl Phys 13:1175–1182. https://doi.org/10.1016/j.cap.2013.03.002
Meng Q, Yan W, Yu M, Huang D (2003) A study of third-order nonlinear optical properties for anthraquinone derivaties. Dyes Pigm 56:145–149. https://doi.org/10.1016/S0143-7208(02)00123-7
Jeyaram S, Geethakrishnan T (2017) Low power laser induced NLO properties and optical limiting of an anthraquinone dye using Z-scan technique. J Mater Sci Mater Elect 28:9820–9827. https://doi.org/10.1007/s10854-017-6763-6
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Conceptualization—SJ; Methodology—JN and SJ; Validation—SP and SJ; Writing-review and editing—SP and SJ; Supervision—SJ.
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Jeyaram, S., Naseer, J. & Punitha, S. Effect of Solvent on Third-Order Nonlinear Optical Behavior of Reactive Blue 19 Dye. J Fluoresc 31, 1895–1906 (2021). https://doi.org/10.1007/s10895-021-02808-y
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DOI: https://doi.org/10.1007/s10895-021-02808-y