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On the Possibility of Obtaining Titanium Nitride Whisker Crystals from the Gas Phase

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The results of an initial assessment of the possibility of obtaining titanium nitride whiskers from the gas phase are reported. A theoretical assessment was made of the possibility of homogeneous formation of different types of micro-substrates with different compositions in the gas phase and the conditions for condensation of the titanium nitride phase and the growth of whiskers. Based on a thermodynamic analysis of the system under investigation, calculations of the existing critical supersaturations were performed and the homogeneous rate of condensation of titanium and titanium nitride in the gas phase was evaluated.

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References

  1. E. N. Kablov, “Innovative development work performed at the Federal State Unitary Enterprise VIAM of the State Scientific Center of the Russian Federation for the implementation of ‘Strategic directions for the development of materials and technologies for their processing for the period up to 2030’,” Aviats. Mater. Tekhnol., No. 1(34), 3 – 33 (2015); DOI: 10.18577/2071-9140-2015-0-1-3-33.

  2. E. N. Kablov, “Marketing of materials science, aircraft construction and industry: present and the future,” Direktor po Marketingu i Sbytu, No. 5 – 6, 40 – 44 (2017).

  3. E. N. Kablov, “New generation materials and digital technologies for their processing,” Vest. Ross. Akad. Nauk, 90(4), 331 – 334 (2020).

    Google Scholar 

  4. H. O. Pierson, Handbook of Refractory Carbides and Nitrides: Properties, Characteristics, Processing, and Applications, William Andrew, Westwood (1996).

  5. D. V. Kiseleva, K. S. Mikhnevich, and Yu. N. Yur’ev, “Deposition of barrier layers based on titanium nitride using dual MSS,” in: 12th Int. Conf. of Students and Young Scientists, Tomsk, April 21 – 24, 2015 [in Russian], Izd. TPU, Tomsk (2015), pp. 125 – 127.

  6. D. A. Alexandrov and D. I. Artemenko, “Wear-resistant coatings for the protection of friction parts of modern gas turbine engines,” Tr. VIAM: Elektron. Nauch.-Tekhn. Zh., No. 10, Art. 6 (2016); URL: http:/www.viam-works.ru (date of access: 11.12.2020); DOI: 10.18577/2307-6046-2016-0-10-6-6.

  7. D. I. Artemenko, V. N. Simonov, and D. V. Vlasova, “Investigation of the titanium nitride deposition process on the MAP-3 ion-plasma spraying unit,” Tr. VIAM: Elektron. Nauch.-Tekhn. Zh., No. 12, Art. 11 (2017); URL: http://www.viam-works.ru (date of access: 11.12.2020); DOI: 10.18577/2307-6046-2017-0-12-11-11.

  8. D. A. Aleksandrov, “Investigation of wear-resistant coatings based on multicomponent titanium nitrides,” Tr. VIAM: Elektron. Nauch.-Tekhn. Zh., No. 4 – 5, 62 – 69 (2020); URL: http://www.viamworks.ru (date of access: 11.12.2020); DOI: 10.18577/2307-6046-2020-0-45-62-69.

  9. V. I. Muravyev, R. A. Fizulakov, D. V. Matveenko, et al., “Method of titanium nitride production, Pat. 2247070 RF, No. 2003129703/15,” Byull. Izobr. Polezn. Modeli, No. 6; app. 10.06.2003; publ. February 27, 2005.

  10. G. P. Shveikin, “Method of obtaining powders of refractory compounds based on titanium, Pat. 2149076 RF,” Byull. Izobr. Polezn. Modeli; app. 09/25/1998, No. 98117637/02; publ. 05/20/2000.

  11. A. P. Il’in, Yu. A. Amelkovich, A. P. Astankova, and L. O. Tolbanova, “Method of obtaining metal nitrides, Pat. 2256604 RF,” Byull. Izobr. Polezn. Modeli, No. 20; app. 02.06.2003, No. 2003116200_15; publ. November 27, 2004.

  12. E. V. Chaplina, Yu. I. Pautova, A. A. Ditz, and A. A. Gromov, “Method of obtaining powder of titanium nitride, Pat. 2488549 RF, No. 2012116353_05,” Byull. Izobr. Polezn. Modeli, No. 21; app. 04/23/2012; publ. 07/27/2013.

  13. S. P. Bogdanov, “Synthesis of titanium nitride from elements in the presence of iodine,” Novye Ogneupory, No. 5, 48 – 51 (2015).

    Google Scholar 

  14. A. V. Leonov, M. A. Sevostyanov, A. S. Lysenkov, et al., “Method of obtaining composite material SiC–TiN, Pat. 2681332 RF, No. 2018111466,” Byull. Izobr. Polezn. Modeli; app. 03/30/2018; publ. 06.03.2019.

  15. R. D. Nixdorf and R. H. Rawlins, Method of Preparation of Titanium Nitride Whiskers, Pat. 4888084 USA; app. 10.24.1988, No. 261375; publ. 19.12.1989.

  16. M. Nygren, M. Johnsson, N. Ahlen, and M. Ekelund, Manufacture of Titanium Carbide, Nitride and Carbonitride Whiskers, Pat. 6110275 USA; app. 12_20_1996, No. 08_772102; publ. 08/29/2000.

  17. A. Goel and V. Revankar, Method for Synthesizing Titanium Nitride Whiskers, Pat. 5665326 USA; app. 13.11.1995, No. 556704; publ. 09.09.1997.

  18. E. I. Givargizov, A Method of Growing Oriented Systems of Whiskers and a Device for Its Implementation (Options), Pat. 2099808 RF; app. 04_01_1996, No. 96106224/09; publ. 12/20/1997.

  19. R. S.Wagner andW. C. Ellis, “Vapor-liquid-solid mechanism of single crystal growth,” Appl. Phys. Lett., 4(5), 89 – 90 (1964).

  20. B. V. Shchetanov, V. N. Gribkov, A. S. Isaikin, et al., “Features of the vapor – liquid – solid phase mechanism during the growth of refractory compound whiskers,” Fiz. Khim. Obrab. Mater., No. 3, 62 – 67 (1973).

    Google Scholar 

  21. E. I. Givargizov, “Growth of monocrystalline nanowires of semiconductors and their potential application,” Pov-st’, Rentgen., Sinkhr. Neitr. Issled., No. 9, 89 – 94 (2007).

  22. B. G. Trusov, “Software system for modeling phase and chemical equilibria at high temperatures,” Vest. MGTU im. N. E. Baumana, Ser. Priborostroenie, No. 1, 240 – 249 (2012); DOI: 10.18698/2308-6033-2012-1-31.

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Authors and Affiliations

  1. All-Russia Research Institute of Aviation Materials, State Scientific Center of the Russian Federation, Moscow, Russia

    V. G. Babashov, N. M. Varrik & T. A. Karaseva

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  1. V. G. Babashov
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  2. N. M. Varrik
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  3. T. A. Karaseva
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Correspondence to N. M. Varrik.

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Translated from Steklo i Keramika, No. 5, pp. 19 – 25, May, 2021.

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Babashov, V.G., Varrik, N.M. & Karaseva, T.A. On the Possibility of Obtaining Titanium Nitride Whisker Crystals from the Gas Phase. Glass Ceram 78, 188–192 (2021). https://doi.org/10.1007/s10717-021-00376-y

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