Abstract
Reduction of graphene oxide (GO) can be used to improve the physical and electronic characteristics of rGO through de-oxygenation and restoration of π-conjugation. Here, the gradual and controllable thermal reduction of GO film formed by drop-casting method was carried out at low temperatures (100 − 350 °C) in ambient conditions with simultaneous electrical measurements. The conductivity of GO film depended on the level of reduction. Electrical measurements show a decrease and then an increase in electrical current after > 150 °C with a maximum change of five orders in current at 300 °C in comparison to GO. The role of functional groups on the evolution of electrical conductance during reduction has been investigated by correlating the FTIR spectroscopy and electrical conductivity. It is shown that the changes in conductivity is governed by two processes, first process is mainly associated with water and OH groups desorption and second process is mainly associated with restored graphene sp2 network. The process, therefore, lends itself to the production of conductive reduced GO suitable for many applications including flexible electronics, TCO layer in solar cells, gas and temperature sensors.
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References
P. Johari, V.B. Shenoy, ACS Nano 5, 7640 (2011)
S. Chen, N. Ullah, T. Wang, R. Zhang, J. Mater. Chem. C 6, 6875 (2018)
M.D. Purkayastha, S. Sil, N. Singh, P.P. Ray, G.K. Darbha, S. Bhattacharyya, A.I. Mallick, T.P. Majumder, FlatChem 22, 100180 (2020)
M. Soni, P. Kumar, J. Pandey, S.K. Sharma, A. Soni, Carbon 128, 172 (2018)
I. Jung, D.A. Dikin, R.D. Piner, R.S. Ruoff, Nano Lett. 8, 4283 (2008)
Z. Wei, D. Wang, S. Kim, S.-Y. Kim, Y. Hu, M.K. Yakes, A.R. Laracuente, Z. Dai, S.R. Marder, C. Berger, W.P. King, W.A. de Heer, P.E. Sheehan, E. Riedo, Science 328, 1373 (2010)
C. Gómez-Navarro, R.T. Weitz, A.M. Bittner, M. Scolari, A. Mews, M. Burghard, K. Kern, Nano Lett. 9, 2206 (2009)
S.E. Yalcin, C. Galande, R. Kappera, H. Yamaguchi, U. Martinez, K.A. Velizhanin, S.K. Doorn, A.M. Dattelbaum, M. Chhowalla, P.M. Ajayan, G. Gupta, A.D. Mohite, ACS Nano 9, 2981 (2015)
Y. Shen, S. Yang, P. Zhou, Q. Sun, P. Wang, L. Wan, J. Li, L. Chen, X. Wang, S. Ding, D.W. Zhang, Carbon 62, 157 (2013)
V. Lee, L. Whittaker, C. Jaye, K.M. Baroudi, D.A. Fischer, S. Banerjee, Chem. Mater. 21, 3905 (2009)
N. Yadav, B. Lochab, FlatChem 13, 40 (2019)
Y. Jin, Y. Zheng, S.G. Podkolzin, W. Lee, J. Mater. Chem. C 8, 4885 (2020)
V.B. Mohan, K. Jayaraman, M. Stamm, D. Bhattacharyya, Thin Solid Films 616, 172 (2016)
E. Tegou, G. Pseiropoulos, M.K. Filippidou, S. Chatzandroulis, Microelectron. Eng. 159, 146 (2016)
M.F.R. Hanifah, J. Jaafar, M.H.D. Othman, A.F. Ismail, M.A. Rahman, N. Yusof, W.N.W. Salleh, F. Aziz, Materialia 6, 100344 (2019)
V.B. Mohan, R. Brown, K. Jayaraman, D. Bhattacharyya, Mater. Sci. Eng. B 193, 49 (2015)
H.H. Shi, S. Jang, H.E. Naguib, ACS Appl. Mater. Interfaces 11, 27183 (2019)
V. Kumar, V. Kumar, G.B. Reddy, R. Pasricha, RSC Adv. 5, 74342 (2015)
Y. Zeng, T. Li, Y. Yao, T. Li, L. Hu, A. Marconnet, Adv. Func. Mater. 29, 1901388 (2019)
A.C. Faucett, J.N. Flournoy, J.S. Mehta, J.M. Mativetsky, FlatChem 1, 42 (2017)
J. Liu, M. Notarianni, G. Will, V.T. Tiong, H. Wang, N. Motta, Langmuir 29, 13307 (2013)
N.H. Aminuddin Rosli, K.S. Lau, T. Winie, S.X. Chin, C.H. Chia, Mater. Chem. Phys. 262, 124274 (2021)
M. Savchak, N. Borodinov, R. Burtovyy, M. Anayee, K. Hu, R. Ma, A. Grant, H. Li, D.B. Cutshall, Y. Wen, G. Koley, W.R. Harrell, G. Chumanov, V. Tsukruk, I. Luzinov, ACS Appl. Mater. Interfaces 10, 3975 (2018)
M.M. Bernal, M. Tortello, S. Colonna, G. Saracco, A. Fina, Nanomaterials. 7, 428 (2017)
I. Sengupta, S. Chakraborty, M. Talukdar, S.K. Pal, S. Chakraborty, J. Mater. Res. 33, 4113 (2018)
Y. Wang, Y. Chen, S.D. Lacey, L. Xu, H. Xie, T. Li, V.A. Danner, L. Hu, Mater. Today 21, 186 (2018)
C. Gómez-Navarro, J.C. Meyer, R.S. Sundaram, A. Chuvilin, S. Kurasch, M. Burghard, K. Kern, U. Kaiser, Nano Lett. 10, 1144 (2010)
N.R. Wilson, P.A. Pandey, R. Beanland, R.J. Young, I.A. Kinloch, L. Gong, Z. Liu, K. Suenaga, J.P. Rourke, S.J. York, J. Sloan, ACS Nano 3, 2547 (2009)
S. Mao, H. Pu, J. Chen, RSC Adv. 2, 2643 (2012)
R.L.D. Whitby, ACS Nano 8, 9733 (2014)
A.T. Smith, A.M. LaChance, S. Zeng, B. Liu, L. Sun, Nano Mater. Sci. 1, 31 (2019)
Y. Tian, Z. Yu, L. Cao, X.L. Zhang, C. Sun, D.-W. Wang, J. Energy Chem. 55, 323 (2021)
H. Sachdeva, Green Process. Synth. 9, 515 (2020)
N.D.K. Tu, J. Choi, C.R. Park, H. Kim, Chem. Mater. 27, 7362 (2015)
O.M. Slobodian, P.M. Lytvyn, A.S. Nikolenko, V.M. Naseka, O.Yu. Khyzhun, A.V. Vasin, S.V. Sevostianov, A.N. Nazarov, Nanoscale Res. Lett. 13, 139 (2018)
C.K. Chua, M. Pumera, J. Mater. Chem. 22, 23227 (2012)
A.V. Dolbin, M.V. Khlistuck, V.B. Esel’son, V.G. Gavrilko, N.A. Vinnikov, R.M. Basnukaeva, A.I. Prokhvatilov, I.V. Legchenkova, V.V. Meleshko, W.K. Maser, A.M. Benito, Low Temp. Phys. 43, 383 (2017)
P. Zhang, Z. Li, S. Zhang, G. Shao, Energy Environ. Mater. 1, 5 (2018)
B. Muchharla, T.N. Narayanan, K. Balakrishnan, P.M. Ajayan, S. Talapatra, 2D Mater. 1, 011008 (2014)
D.S. Bhaskaram, G. Govindaraj, J. Phys. Chem. C 122, 10303 (2018)
J. Ma, X. Hou, M. Yu, J. Hua, X. Ren, H. Qiu, R. Wang, J. Phys. D: Appl. Phys. 50, 435101 (2017)
T. Anusuya, J. Prakash, D.K. Pathak, K. Saxena, R. Kumar, V. Kumar, Mater. Today Commun. 26, 101930 (2021)
P. Scherrer, Nachrichten von der Gesellschaft der Wissenschaften zu Göttingen. Mathematisch-Physikalische Klasse 1918, 98 (1918)
J.I. Langford, A.J.C. Wilson, J. Appl. Cryst. 11, 102 (1978)
V. Uvarov, I. Popov, Mater. Charact. 85, 111 (2013)
I. Sengupta, S.S.S.S. Kumar, S.K. Pal, S. Chakraborty, J. Mater. Res. 35, 1197 (2020)
Y. Chen, K. Fu, S. Zhu, W. Luo, Y. Wang, Y. Li, E. Hitz, Y. Yao, J. Dai, J. Wan, V.A. Danner, T. Li, L. Hu, Nano Lett. 16, 3616 (2016)
S. Bai, X. Shen, G. Zhu, A. Yuan, J. Zhang, Z. Ji, D. Qiu, Carbon 60, 157 (2013)
Y. Qiu, F. Collin, R.H. Hurt, I. Külaots, Carbon 96, 20 (2016)
A.C. Ferrari, J. Robertson, Phys. Rev. B 64, 075414 (2001)
J.-B. Wu, X. Zhang, M. Ijäs, W.-P. Han, X.-F. Qiao, X.-L. Li, D.-S. Jiang, A.C. Ferrari, P.-H. Tan, Nat. Commun. 5, 1 (2014)
F. Herziger, P. May, J. Maultzsch, Phys. Rev. B 85, 235447 (2012)
A. Merlen, J.G. Buijnsters, C. Pardanaud, Coatings 7, 153 (2017)
A.C. Ferrari, J.C. Meyer, V. Scardaci, C. Casiraghi, M. Lazzeri, F. Mauri, S. Piscanec, D. Jiang, K.S. Novoselov, S. Roth, A.K. Geim, Phys. Rev. Lett. 97, 187401 (2006)
C. Thomsen, S. Reich, Phys. Rev. Lett. 85, 5214 (2000)
R.N. Gontijo, G.C. Resende, C. Fantini, B.R. Carvalho, J. Mater. Res. 34, 1976 (2019)
R. Muzyka, S. Drewniak, T. Pustelny, M. Chrubasik, G. Gryglewicz, Materials 11, 1050 (2018)
H.Y. Nan, Z.H. Ni, J. Wang, Z. Zafar, Z.X. Shi, Y.Y. Wang, J. Raman Spectrosc. 44, 1018 (2013)
H. Feng, R. Cheng, X. Zhao, X. Duan, J. Li, Nat. Commun. 4, 1539 (2013)
J.T. Paci, T. Belytschko, G.C. Schatz, J. Phys. Chem. C 111, 18099 (2007)
R.C. Sinclair, P.V. Coveney, J. Chem. Inf. Model. 59, 2741 (2019)
X. Gao, J. Jang, S. Nagase, J. Phys. Chem. C 114, 832 (2010)
R. David, A. Tuladhar, L. Zhang, C. Arges, R. Kumar, J. Phys. Chem. B 124, 8167 (2020)
R. Larciprete, S. Fabris, T. Sun, P. Lacovig, A. Baraldi, S. Lizzit, J. Am. Chem. Soc. 133, 17315 (2011)
O. Okhay, G. Gonçalves, A. Tkach, C. Dias, J. Ventura, M.F. da Ribeiro Silva, L.M. Valente Gonçalves, E. Titus, J. Appl. Phys. 120, 051706 (2016)
W. Zeng, X.-M. Tao, S. Lin, C. Lee, D. Shi, K. Lam, B. Huang, Q. Wang, Y. Zhao, Nano Energy 54, 163 (2018)
T. Anusuya, V. Kumar, V. Kumar, Chemosphere 282, 131019 (2021)
Acknowledgements
Authors (AT & VK) are thankful to IIITDM Kancheepuram for providing financial support and facilities. Author (VK) acknowledges financial support from Science and Engineering Research Board, Department of Science and Technology (SERB-DST), Govt. of India (Grant No. ECR/2016/001715).
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Author (VK) acknowledges financial support from Science and Engineering Research Board, Department of Science and Technology (SERB-DST), Govt. of India (Grant No. ECR/2016/001715).
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Anusuya, T., Prema, D. & Kumar, V. Reduction-controlled electrical conductivity of large area graphene oxide channel. J Mater Sci: Mater Electron 33, 8935–8945 (2022). https://doi.org/10.1007/s10854-021-06979-z
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DOI: https://doi.org/10.1007/s10854-021-06979-z