Issue 38, 2021

Palladium-catalyzed carbonylation of iminoquinones and aryl iodides to access aryl p-amino benzoates

Abstract

A palladium-catalyzed carbonylation of iminoquinones and aryl iodides has been developed for the construction of aryl p-amino benzoates. Using benzene-1,3,5-triyl triformate (TFBen) as the CO source, the reaction proceeded well to give various aryl p-amino benzoates in good to excellent yields. Additionally, control experiments were conducted to gain more insights into the reaction mechanism.

Graphical abstract: Palladium-catalyzed carbonylation of iminoquinones and aryl iodides to access aryl p-amino benzoates

Supplementary files

Article information

Article type
Communication
Submitted
18 Aug 2021
Accepted
06 Sep 2021
First published
06 Sep 2021

Org. Biomol. Chem., 2021,19, 8246-8249

Palladium-catalyzed carbonylation of iminoquinones and aryl iodides to access aryl p-amino benzoates

S. Wang, L. Yao, J. Ying and X. Wu, Org. Biomol. Chem., 2021, 19, 8246 DOI: 10.1039/D1OB01623G

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