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Synthesis and Structure of Bismuth Complexes [(2-MeO)(5-Cl)C6H3]3Bi, [(2-MeO)(5-Cl)C6H3]3Bi[OC(O)CF2Br]2, and [(2-MeO)(5-Br)C6H3]3Bi[OC(O)C6HF4-2,3,4,5]2

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Abstract

In the crystal of [(2-MeO)(5-Cl)C6H3]3Bi (I), obtained from bismuth trichloride and 2-methoxy-5-chlorophenyllithium in ether, bismuth atoms have a trigonal ligand environment. The coordination number of the central atom is 6 (3 + 3), with allowance made for the coordination of the MeO oxygen atom to the metal (the Bi···OMe intramolecular distances are 3.014(6), 3.088(6), and 3.168(6) Å). Treatment of a mixture of I and bromodifluoroacetic acid, or [(2-MeO)(5-Br)C6H3]3Bi and 2,3,4,5-tetrafluorobenzoic acid in ether with tert-butyl hydroperoxide results in the formation of trigonal bipyramidal triarylbismuth dicarboxylates [(2-MeO)(5-Cl)C6H3]3Bi[OC(O)CF2Br]2 (II) and [(2-MeO)(5-Br)C6H3]3Bi[OC(O)C6HF4-2,3,4,5]2 (III), respectively, with carboxyl ligands in the apical positions. In the crystals of II and III, the metal atom is additionally coordinated to the oxygen atoms of the O=C and MeO groups (3.05(16), 3.30(16), and 3.153(5)−3.117(5) Å for II and 3.004(7), 3.230(7), and 3.159(7)−3.199(7) Å for III). The structures of I–III were studied by X-ray diffraction (CIF file CCDC nos. 2044006 (I), 2044005 (II), and 2048153 (III)).

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  1. National Research South Ural State University, 454080, Chelyabinsk, Russia

    V. V. Sharutin, O. K. Sharutina & A. N. Efremov

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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Sharutin, V.V., Sharutina, O.K. & Efremov, A.N. Synthesis and Structure of Bismuth Complexes [(2-MeO)(5-Cl)C6H3]3Bi, [(2-MeO)(5-Cl)C6H3]3Bi[OC(O)CF2Br]2, and [(2-MeO)(5-Br)C6H3]3Bi[OC(O)C6HF4-2,3,4,5]2. Russ J Coord Chem 47, 626–630 (2021). https://doi.org/10.1134/S1070328421070058

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