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The MIL-125 Metal–Organic Framework Structure for Adsorption-Based Accumulation of Methane and Hydrogen

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Abstract—

A MIL-125 metal–organic framework structure was synthesized from titanium and 1, 4-benzenedicarboxylic acid. The specific micropore volume of the synthesized sample was found to be W0 = 0.59 cm3/g, and the specific BET surface area was SBET = 1320 m2/g. Analysis of the synthesized material revealed the possibility of its application for accumulating energetically important gases: methane and hydrogen. The adsorption of hydrogen and methane on MIL-125 was experimentally studied within the temperature range of 77−293 K for hydrogen and 213−293 K for methane at absolute pressures up to 1.5 bar. The high heats of methane and hydrogen adsorption on the synthesized sample of about 26 and 14 kJ/mol were evaluated. It was found that, due to narrow pores, the adsorbent may be effective in accumulating methane at high temperatures. MIL-125 exhibited the best adsorption performance for hydrogen. At the temperature of 77 K and atmospheric pressure, the sample can accumulate up to 2.3 wt % hydrogen.

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ACKNOWLEDGMENTS

MOF was synthesized in the laboratory of Photoactive Nanocomposite Materials of St. Petersburg State University within the framework of a project of St. Petersburg State University, pure ID: 51124539.

Funding

This work was carried out in the framework of state assignment no. 0081-2019-0018, Fundamental physicochemical laws of adsorption, adsorption separation, adsorption-electrochemical ion-exchange processes in nanoporous materials and the basis of targeted synthesis of new adsorbents.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    O. V. Solovtsova, A. V. Shkolin, I. E. Men’shchikov, A. A. Fomkin, M. K. Knyazeva, V. Yu. Yakovlev & A. L. Pulin

  2. St. Petersburg State University, 199034, St. Petersburg, Russia

    A. V. Maevsky, D. Yu. Poloneeva & A. V. Emelin

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  1. O. V. Solovtsova
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  2. A. V. Maevsky
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  4. A. V. Emelin
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  5. A. V. Shkolin
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  6. I. E. Men’shchikov
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  8. M. K. Knyazeva
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  9. V. Yu. Yakovlev
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Correspondence to O. V. Solovtsova.

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Translated by E. Khozina

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Solovtsova, O.V., Maevsky, A.V., Poloneeva, D.Y. et al. The MIL-125 Metal–Organic Framework Structure for Adsorption-Based Accumulation of Methane and Hydrogen. Prot Met Phys Chem Surf 57, 672–679 (2021). https://doi.org/10.1134/S2070205121040225

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  • DOI: https://doi.org/10.1134/S2070205121040225

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