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Thermodynamic and Electrochemical Studies of Aniline and Phenylhydrazine and Their Derivatives Substituted POCl3-Based Compounds as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Solution

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Abstract

The achievement of high corrosion inhibition performances by manipulating the molecular structure of organic substances has gained much attention in recent years. In this paper, POCl3 was synthesized and Cl atoms in phosphoryl chloride (POCl3) were replaced by aniline or phenyl hydrazine and their derivatives; the effect of the substitution on the corrosion inhibition performance for mild steel immersed in 1 M HCl solution was investigated. Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance (NMR) and ultraviolet-visible (UV–Vis) spectroscopy were used to determine the molecular structure of the synthesized organic substances. Electrochemical impedance spectroscopy (EIS) and polarization measurements were employed to investigate the corrosion inhibition performance of the organic molecules for the immersed mild steel samples in the acid solution. The obtained results indicated that the inhibition efficiency of the synthesized inhibitors was increased by increasing the molecular size of the organic substances as well as increasing the number of nitrogen and oxygen heteroatoms in the structure of the organic molecules. The maximum amount of inhibition efficiency of the synthesized organic inhibitors in this paper was obtained about 93%.

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Authors and Affiliations

  1. Department of Chemistry, College of Science, Malek-ashtar University of Technology, P.O. Box 83145/115, Tehran, Islamic Republic of Iran

    Fariborz Atabaki &  Shahrzad Jahangiri

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  1. Fariborz Atabaki
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  2. Shahrzad Jahangiri
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Correspondence to Fariborz Atabaki.

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Fariborz Atabaki, Shahrzad Jahangiri Thermodynamic and Electrochemical Studies of Aniline and Phenylhydrazine and Their Derivatives Substituted POCl3-Based Compounds as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Solution. Prot Met Phys Chem Surf 57, 820–833 (2021). https://doi.org/10.1134/S2070205121040055

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