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Synthesis of silicone-acrylic-modified high-ortho novolac resin with enhanced thermal resistance and surface coating properties

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Abstract

In the present study, vinyltrimethoxysilane was used to modify high-ortho novolac resin (NR) to obtain a vinyl silicone-modified phenolic oligomer (Si-mod NR). Subsequently, this oligomer is polymerized with methyl methacrylate. The mid-products (NR and Si-mod NR) and synthesized silicone-modified phenolic/acrylic resin (Ac/Si-mod NR) were characterized by Fourier transform infrared spectroscopy, and thermal properties were investigated by using thermal gravimetric analysis and differential scanning calorimetry techniques. In addition, the surface coating properties, including drying, hardness, adhesion, impact resistance, gloss, acid, alkaline, water, and solvent resistance of the films prepared from these products, were comparatively investigated. The results showed that the modification reactions yield a novel resin (Ac/Si-mod NR), which can be easily used as a surface coating material with high thermal resistance, flexibility, and excellent film properties.

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Acknowledgments

The authors thank Prof. Işıl Acar for her assistance in the laboratory and Burak Alptekin for english language editing.

Funding

This work was supported by the Research Fund of the Istanbul University - Cerrahpaşa; Grant Number 14653.

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  1. Chemical Engineering Department, Faculty of Engineering, Istanbul University – Cerrahpaşa, 34320, Avcılar-Istanbul, Turkey

    Serkan Emik, Tülin Banu İyim & Saadet Özgümüş

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  1. Serkan Emik
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  2. Tülin Banu İyim
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SE performed the synthesis and characterization experiments and wrote the paper. All authors discussed the results and commented on the manuscript. The content is solely the responsibility of the authors and does not necessarily represent the official views of the Istanbul University—Cerrahpaşa Research Fund.

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Correspondence to Serkan Emik.

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Emik, S., İyim, T.B. & Özgümüş, S. Synthesis of silicone-acrylic-modified high-ortho novolac resin with enhanced thermal resistance and surface coating properties. J Coat Technol Res 18, 1679–1690 (2021). https://doi.org/10.1007/s11998-021-00527-4

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