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Volumetriс Properties of Butyronitrile–Dimethylsulfoxide and Butyronitrile–Diethylsulfoxide Binary Mixtures

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Abstract

Densities of binary mixtures of butyronitrile with dimethylsulfoxide and diethylsulfoxide are measured throughout the range of concentrations and in the temperature range of 298.15–323.15 K at ambient pressure. Volumetric parameters, the parameters of the Redlich–Kister equation, and the standard deviations of the excess molar volumes are calculated. Deviation of the behavior of these solutions from ideal is explained by the presence of competing homo- and hetero-molecular interactions, and by the effect the length of the hydrocarbon chain of sulfoxides has on the values of volumetric parameters.

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Funding

This work was supported by the Science Committee of the Republic of Armenia as part of the scientific program of the Research Laboratory of Physical Chemistry.

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Authors and Affiliations

  1. Yerevan State University, 710000, Yerevan, Armenia

    H. H. Ghazoyan & Sh. A. Markaryan

Authors
  1. H. H. Ghazoyan
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  2. Sh. A. Markaryan
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Correspondence to Sh. A. Markaryan.

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Translated by Z. Smirnova

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Ghazoyan, H.H., Markaryan, S.A. Volumetriс Properties of Butyronitrile–Dimethylsulfoxide and Butyronitrile–Diethylsulfoxide Binary Mixtures. Russ. J. Phys. Chem. 95, 1811–1820 (2021). https://doi.org/10.1134/S0036024421090089

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  • DOI: https://doi.org/10.1134/S0036024421090089

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