Issue 79, 2021
From the journal:

Chemical Communications

Organic guest molecule induced ultrafast breathing of an epitaxially grown metal–organic framework on a self-assembled monolayer†

Purna Chandra Rao, ORCID logo ‡a   Prabu Mani, ORCID logo ‡a   Younghu Son, ORCID logo a   Jiyun Kim ORCID logo a  and  Minyoung Yoon ORCID logo *a  

* Corresponding authors

a Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Daegu 41566, Republic of Korea
E-mail: myyoon@knu.ac.kr

Abstract

We report epitaxially grown new two-dimensional metal–organic framework (MOF) thin films on a self-assembled monolayer (SAM). We fabricated these epitaxial thin-films using stepwise layer-by-layer seeding followed by solvothermal treatment. The MOF thin films exhibit ultrafast structural flexibility (through breathing) compared to their bulk samples upon uptake of organic guest molecules.

Graphical abstract: Organic guest molecule induced ultrafast breathing of an epitaxially grown metal–organic framework on a self-assembled monolayer

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Article information

DOI
https://doi.org/10.1039/D1CC03721H
Article type
Communication
Submitted
10 Jul 2021
Accepted
01 Sep 2021
First published
01 Sep 2021

Chem. Commun., 2021,57, 10158-10161

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Organic guest molecule induced ultrafast breathing of an epitaxially grown metal–organic framework on a self-assembled monolayer

P. C. Rao, P. Mani, Y. Son, J. Kim and M. Yoon, Chem. Commun., 2021, 57, 10158 DOI: 10.1039/D1CC03721H

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