Skip to main content
SpringerLink
Log in

Novel application of the esterification product of 2,3-dihydroxybutanedioic acid and cellulosic biomass for cobalt ion adsorption

  • Environmental Engineering
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

A novel biosorbent (‘Manna_COOH’) was synthesized via dual reaction stages of direct carbonylation of hydroxyl groups of richly cellulosic manna root powder and subsequent esterification of the resultant anhydride analogue into an ester of high carboxyl content. Both the biosorbent precursor and the 2,3-dihydroxybutanedioic acid sustain complementary features that ensured their efficient complexation. The biosorbent depicted a carboxyl content of 412.36 m.eq -COOH/100 g sample and was characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier-transform infrared spectroscopy (FTIR). The study further evaluated the cobalt ion adsorption capacity of the synthesized ‘Manna_COOH’ under the effect of some process variable via batch mode. The Freundlich and pseudo-second-order models emerged as the best fit for the equilibrium and kinetic data, respectively. The rich oxygen-based surface functional groups entrenched on the ‘Manna_COOH’ sequel to its functionalization played a major role in making it a promising biosorbent for aqueous Co (II) uptake.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. Chen, Y. Zhang, L. Shen, X. Wang, J. Chen, A. Ma and W. Jiang, Chem. Eng. J., 268, 348 (2015).

    Article  CAS  Google Scholar 

  2. S. Zhuang, K. Zhu and J. Wang, J. Clean. Prod., 285, 124911 (2020).

    Article  CAS  Google Scholar 

  3. M. Abbas, S. Kaddour and M. Trari, J. Ind. Eng. Chem., 20(3), 745 (2014).

    Article  CAS  Google Scholar 

  4. A. R. Lucaci, D. Bulgariu, I. Ahmad, G. Lisă, A. M. Mocanu and L. Bulgariu, Water, 11(8), 1565 (2019).

    Article  CAS  Google Scholar 

  5. M. He, Y. Zhu, Y. Yang, B. Han and Y. Zhang, Appl. Clay Sci., 54(3–4), 292 (2011).

    Article  CAS  Google Scholar 

  6. D. Joksimovic, I. Tomic, A. R. Stankovic, M. Jovic and S. Stankovic, Food Chem., 127(2), 632 (2011)

    Article  CAS  PubMed  Google Scholar 

  7. N. B. Haq, K. Rubina and A. H. Muhammad, Iran. J. Chem. Chem. Eng., 30(4), 81 (2011).

    CAS  Google Scholar 

  8. C. O. Aniagor and M. C. Menkiti, Sigma, 38(3), 1073 (2020).

    Google Scholar 

  9. A. Hashem, Polym. Plast. Technol. Eng., 45(1), 35 (2006).

    Article  CAS  Google Scholar 

  10. A. Hashem, A. Abdel-Lateff, S. Farag and D. Hussein, Adsorp. Sci. Technol., 26(9), 661 (2008).

    Article  CAS  Google Scholar 

  11. A. Hashem, E. Abdel-Halim, K. F. El-Tahlawy and A. Hebeish, Adsorp. Sci. Technol., 23(5), 367 (2005).

    Article  CAS  Google Scholar 

  12. A. Hashem, A. Al-Anwar, N. M. Nagy, D. M. Hussein and S. Eisa, Green Process. Synth., 5(2), 213 (2016).

    CAS  Google Scholar 

  13. Z. Hubicki and D. Kołodyńska, Ion exchange technologies, Intech-Open, UK (2012).

    Google Scholar 

  14. Z. Wang, Y. Feng, X. Hao, W. Huang and X. Feng, J. Mater. Chem., 2(26), 10263 (2014).

    Article  CAS  Google Scholar 

  15. N. Abdullah, N. Yusof, W. Lau, J. Jaafar and A. Ismail, J. Ind. Eng. Chem., 76, 17 (2019).

    Article  CAS  Google Scholar 

  16. X. Fang, J. Li, X. Li, S. Pan, X. Zhang, X. Sun, J. Shen, W. Han and L. Wang, Chem. Eng. J., 314, 38 (2017).

    Article  CAS  Google Scholar 

  17. C. Blöcher, J. Dorda, V. Mavrov, H. Chmiel, N. Lazaridis and K. Matis, Water Res., 37(16), 4018 (2003).

    Article  PubMed  CAS  Google Scholar 

  18. M. T. Yagub, T. K. Sen, S. Afroze and H. M. Ang, Adv. Colloid Interface Sci., 209, 172 (2014).

    Article  CAS  PubMed  Google Scholar 

  19. C. O. Aniagor and M. Menkiti, Appl. Water Sci., 9(4), 77 (2019).

    Article  CAS  Google Scholar 

  20. C. O. Aniagor and M. Menkiti, J. Environ. Chem. Eng., 6(2), 2105 (2018).

    Article  CAS  Google Scholar 

  21. M. C. Menkiti and C. O. Aniagor, Arab. J. Sci. Eng., 43(5), 2375 (2018).

    Article  CAS  Google Scholar 

  22. S. Hua and A. Wang, Polym. Adv. Technol., 19(8), 1009 (2008).

    Article  CAS  Google Scholar 

  23. A. Hashem, C. Aniagor, G. Taha and M. Fikry, Current Res. Green Sustain. Chem., 4, 100056 (2021).

    Article  Google Scholar 

  24. S. Ayuba, A. A. Mohammadib, M. Yousefic and F. Changanic, Desalination Water Treat., 142, 293 (2019).

    Article  CAS  Google Scholar 

  25. J. Wang and C. Chen, Bioresour. Technol., 160, 129 (2014).

    Article  CAS  PubMed  Google Scholar 

  26. R. Wang, R. Liang, T. Dai, J. Chen, X. Shuai and C. Liu, Trends Food Sci. Technol., 91, 319 (2019).

    Article  CAS  Google Scholar 

  27. X. Liu, X. Xu, X. Dong and J. Park, Pol. J. Environ. Stud., 29(1), 749 (2020).

    Article  CAS  Google Scholar 

  28. V. Thakur, E. Sharma, A. Guleria, S. Sangar and K. Singh, Mater. Today: Proceedings, 32, 608 (2020).

    CAS  Google Scholar 

  29. E. Abdel-Halim and S. S. Al-Deyab, React. Funct. Polym., 75, 1 (2014).

    Article  CAS  Google Scholar 

  30. K. Junlapong, P. Maijan, C. Chaibundit and S. Chantarak, Int. J. Biol. Macromol., 158, 258 (2020).

    Article  CAS  PubMed  Google Scholar 

  31. F. Balaska, M. Bencheikh-Lehocine, A.-H. Meniai, M. Chikhi and A. Bouledjouidja, Energy Procedia, 18, 622 (2012).

    Article  CAS  Google Scholar 

  32. A. Hashem, S. Badawy, S. Farag, L. Mohamed, A. Fletcher and G. Taha, J. Environ. Chem. Eng., 8(4), 103966 (2020).

    Article  CAS  Google Scholar 

  33. A. Ebrahimi, M. Ehteshami and B. Dahrazma, Process Saf. Environ., 98, 374 (2015).

    Article  CAS  Google Scholar 

  34. M. Khalil, A. Hashem and A. Hebeish, Starch-Stärke, 42(2), 60 (1990).

    Article  CAS  Google Scholar 

  35. W. Gan, L. Gao, X. Zhan and J. Li, RSC Adv., 6(44), 37600 (2016).

    Article  CAS  Google Scholar 

  36. M. L. Dianu, A. Kriza, N. Stanica and A. M. Musuc, J. Serb. Chem. Soc., 75(11), 1515 (2010).

    Article  CAS  Google Scholar 

  37. B. Wang, M. Sain and K. Oksman, Appl. Compos. Mater., 14(2), 89 (2007).

    Article  CAS  Google Scholar 

  38. A. Hashem, C. O. Aniagor, M. Nasr and A. Abou-Okeil, Int. J. Biol. Macromol., 176, 201 (2021).

    Article  CAS  PubMed  Google Scholar 

  39. C. O. Aniagor, M. Elshkankery, A. Fletcher, O. M. Morsy, E. Abdel-Halim and A. Hashem, Water Conserv. Sci. Eng., 6, 95 (2021).

    Article  Google Scholar 

  40. C. A. Igwegbe, S. N. Oba, C. O. Aniagor, A. G. Adeniyi and J. O. Ighalo, J. Ind. Eng. Chem., 93, 57 (2020).

    Article  CAS  Google Scholar 

  41. S. N. Oba J. O. Ighalo, C. O. Aniagor and C. A. Igwegbe, Sci. Total Environ., 780, 146608 (2021).

    Article  CAS  PubMed  Google Scholar 

  42. C. O. Aniagor, C. A. Igwegbe, J. O. Ighalo and S. N. Oba, J. Mol. Liq., 334, 116124 (2021).

    Article  CAS  Google Scholar 

  43. Y. Kuang, X. Zhang and S. Zhou, Water, 12(2), 587 (2020).

    Article  Google Scholar 

  44. E. Asuquo, A. Martin, P. Nzerem, F. Siperstein and X. Fan, J. Environ. Chem. Eng., 5(1), 679 (2017).

    Article  CAS  Google Scholar 

  45. F. Gorzin and M. Bahri Rasht Abadi, Adsorp. Sci. Technol., 36(1–2), 49 (2018).

    Google Scholar 

  46. N. Thi Minh Tam, Y. Liu, H. Bashir, Z. Yin, Y. He and X. Zhou, Int. J. Environ. Res. Public Health, 17(1), 291 (2020).

    Article  CAS  Google Scholar 

  47. J. Elliott and C. Ward, Langmuir, 13(5), 951 (1997).

    Article  CAS  Google Scholar 

  48. C. O. Aniagor, E. Abdel-Halim and A. Hashem, J. Environ. Chem. Eng., 9(4), 105703 (2021).

    Article  CAS  Google Scholar 

  49. I. Langmuir, J. Am. Chem. Soc., 38(11), 2221 (1916).

    Article  CAS  Google Scholar 

  50. A. W. Adamson and A. P. Gast, Physical chemistry of surfaces, John Wiley & Sons, Inc., New York (1967)

    Google Scholar 

  51. J. Wang and X. Guo, J. Hazard. Matet., 390, 122156 (2020).

    Article  CAS  Google Scholar 

  52. X. Guo and J. Wang, J. Mol. Liq., 288, 111100 (2019).

    Article  CAS  Google Scholar 

  53. A. Kadam, R. G. Saratale, S. Shinde, J. Yang, K. Hwang, B. Mistry, G. D. Saratale, S. Lone, D. Y. Kim and J. S. Sung, Bioresour. Technol., 273, 386 (2019).

    Article  CAS  PubMed  Google Scholar 

  54. A. Hashem, C. Aniagor, D. Hussein and S. Farag, Cellulose, 28, 3599 (2021).

    Article  CAS  Google Scholar 

  55. X. Li, Y. Tang, X. Cao, D. Lu, F. Luo and W. Shao, Colloids Surf. A Physicochem. Eng., 317(1–3), 512 (2008).

    Article  CAS  Google Scholar 

  56. S. Singh and S. Shukla, Int. J. Environ. Sci. Technol., 13(1), 165 (2016).

    Article  CAS  Google Scholar 

  57. E. C. Silva Filho, L. S. Santos Júnior, M. M. F. Silva, M. G. Fonseca, S. A. A. Santana and C. Airoldi, Mat. Res., 16(1), 79 (2013).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Textile Research Division, National Research Centre, Dokki, Cairo, Egypt

    Ali Hashem & Ghada Mohamed Taha

  2. Department of Chemical Engineering, Nnamdi Azikiwe University, P.M.B. 5025, Awka, Nigeria

    Chukwunonso Onyeka Aniagor

  3. National Center for Clinical and Environmental Toxicology, Faculty of Medicine, Cairo University, Cairo, Egypt

    Sayed Mohamed Badawy

Authors
  1. Ali Hashem
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Chukwunonso Onyeka Aniagor
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Sayed Mohamed Badawy
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ghada Mohamed Taha
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Ali Hashem or Chukwunonso Onyeka Aniagor.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Hashem, A., Aniagor, C.O., Badawy, S.M. et al. Novel application of the esterification product of 2,3-dihydroxybutanedioic acid and cellulosic biomass for cobalt ion adsorption. Korean J. Chem. Eng. 38, 2256–2264 (2021). https://doi.org/10.1007/s11814-021-0872-7

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-021-0872-7

Keywords

Search

Navigation