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Electrochemical analysis of monoethylene glycol using rGO/AuPd-np-modified glassy carbon electrode

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Abstract

An electrode for monoethylene glycol analysis was developed based on the modification of the surface of the glassy carbon electrode with electrochemically reduced graphene oxide and gold and palladium nanoparticles (GCE/rGO/AuPd-np). Its analytical performance was assessed by determining some analytical figures of merit. Graphene oxide was reduced electrochemically as well as the metal particles with gold deposited by chronopotentiometry and palladium by cyclic voltammetry (CV). The electrode was characterized by MET, TEM and EDS techniques. The study of alcohol behaviour was performed electrochemically using CV technique. The positive synergistic effect of metals provided greater electrocatalytic response, stability and resistance to poisoning. The GCE/rGO/AuPd-np sensor presented a detection limit equal to 31.48 µmol l–1 for a linear range of 89.5–179 µmol l–1 with a linear correlation coefficient of 0.9096 and high stability, not losing response even after 650 cycles.

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Acknowledgements

We thank Fundação de Amparo à Pesquisa do Estado do Rio de Janeiro (FAPERJ), Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) and Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) for financial support. Victor Paiva would like to thank CNPq for the Master’s Fellowship support.

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Authors and Affiliations

  1. Institute of Chemistry, Federal University of Rio de Janeiro, University City, Rio de Janeiro, 21941-909, Brazil

    Victor Magno Paiva, Emerson Schwingel Ribeiro & Eliane D’elia

  2. National Institute of Metrology, Quality and Technology, Duque de Caxias, 25250-020, Brazil

    Kelly Leite Santos Castro Assis, Bráulio Soares Archanjo & Carlos Alberto Senna

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  1. Victor Magno Paiva
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  2. Kelly Leite Santos Castro Assis
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  3. Bráulio Soares Archanjo
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  6. Eliane D’elia
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Correspondence to Eliane D’elia.

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Paiva, V.M., Assis, K.L.S.C., Archanjo, B.S. et al. Electrochemical analysis of monoethylene glycol using rGO/AuPd-np-modified glassy carbon electrode. Bull Mater Sci 44, 248 (2021). https://doi.org/10.1007/s12034-021-02517-z

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