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Synthesis and Optical Properties of Ethyl 2-Cyano-2-[3,4-dicyanopyridin-2(1H)-ylidene]acetate Derivatives

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Abstract

Derivatives of ethyl 2-cyano-2-[3,4-dicyanopyridin-2(1H)-ylidene]acetate have been synthesized by reaction of 2-chloropyridine-3,4-dicarbonitriles with ethyl cyanoacetate. The synthesized compounds showed solid state fluorescence with the emission maxima located in the range λ 619–641 nm; the emission maxima in solution range from λ 392 to 486 nm, depending on the solvent.

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Funding

This study was performed under financial support by the Ministry of Science and Higher Education of the Russian Federation (project no. 0849-2020-0003).

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Authors and Affiliations

  1. I.N. Ul’yanov Chuvash State University, 428015, Cheboksary, Russia

    S. S. Chunikhin & O. V. Ershov

Authors
  1. S. S. Chunikhin
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  2. O. V. Ershov
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Correspondence to S. S. Chunikhin.

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The authors declare no conflict of interest.

Additional information

Translated from Zhurnal Organicheskoi Khimii, 2021, Vol. 57, No. 7, pp. 1012–1018 https://doi.org/10.31857/S0514749221070119.

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Chunikhin, S.S., Ershov, O.V. Synthesis and Optical Properties of Ethyl 2-Cyano-2-[3,4-dicyanopyridin-2(1H)-ylidene]acetate Derivatives. Russ J Org Chem 57, 1103–1108 (2021). https://doi.org/10.1134/S1070428021070113

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