Abstract
Knoevenagel condensation of betulonic aldehyde with malononitrile afforded 2-[3-oxolup-20(29)-ene-28-ylidene]malononitrile and product of partial hydrolysis of the dinitrile moiety, 2-cyano-3-[3-oxo-28-norlup-20(29)-en-17-yl]prop-2-enamide whose structure was determined by NMR spectroscopy using two-dimensional correlation techniques.
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ACKNOWLEDGMENTS
The NMR spectra were recorded at the Chemistry joint center (Ufa Institute of Chemistry, Russian Academy of Sciences) and Agidel regional joint center (Ufa Federal Research Center, Russian Academy of Sciences).
Funding
This study was performed in the framework of state assignment nos. AAAA-A19-119020890014-7 and AAAAA17-117011910027-0.
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Translated from Zhurnal Organicheskoi Khimii, 2021, Vol. 57, No. 7, pp. 1042–1046 https://doi.org/10.31857/S0514749221070168.
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Petrova, A.V., Lobov, A.N. Knoevenagel Reaction of Betulonic Aldehyde. Russ J Org Chem 57, 1184–1187 (2021). https://doi.org/10.1134/S1070428021070216
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DOI: https://doi.org/10.1134/S1070428021070216