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Influence of Acid-Base Properties of Mg-Al Oxide Systems on their Catalytic Characteristics in the Process of Gas-Phase Conversion of Ethanol to 1-Butanol

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Theoretical and Experimental Chemistry Aims and scope

The influence of acid-base properties of MgO-Al2O3 systems obtained by the decomposition of hydrotalcites with ratio of Mg/Al = 1÷3 on their activity and selectivity in the process of ethanol conversion to 1-butanol is studied.The highest values of selectivity and specific rate of BuOH formation are achieved with ratio Mg/Al = 2 for the sample, which according to the test results is characterized by the largest number of acid and basic sites in the dehydrogenation/dehydration reactions of isopropanol.

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References

  1. B. Ndaba, I. Chiyanzu, and S. Marx, Biotechnol. Rep., 8, 1-9 (2015).

    Article  CAS  Google Scholar 

  2. D. Gabriels, W. Y. Hernandez, B. Sels, et al., Catal. Sci. Technol., 5, 3876-3902 (2015).

    Article  CAS  Google Scholar 

  3. M. O. S. Dias, L. G. Pereira, T. L. Junqueira, et al., Chem. Eng. Res. Des., 92, 1441-1451 (2014).

    Article  CAS  Google Scholar 

  4. O. V. Larina, K. V. Valihura, P. I. Kyriienko, et al., Appl. Catal. A, 588, 117265 (2019).

    Article  Google Scholar 

  5. K. V. Valihura, O. V. Larina, P. I. Kyriienko, et al., Theor. Exp. Chem., 55, 337-344 (2019), doi.https://doi.org/10.1007/s11237-019-09626-1.

    Article  CAS  Google Scholar 

  6. K. V. Valihura and S. O. Soloviev, Catal. Petrochem., 29, 32-51 (2020).

    Article  Google Scholar 

  7. J. Shen, M. Tu, and C. Hu, J. Solid State Chem., 301, 295-301 (2000).

    Google Scholar 

  8. L. Silvester, J. F. Lamonier, C. Lamonier, et al., ChemCatChem., 9, 2250-2261 (2017).

    Article  CAS  Google Scholar 

  9. P. I. Kyriienko, O. V. Larina, D. Y. Balakin, et al., Appl. Catal. A., 616, 118081 (2021).

    Article  CAS  Google Scholar 

  10. C. N. Perez, C. A. Perez, C. A. Henriques, and J. L. F. Monteiro, Appl. Catal. A, 272, 229-240 (2004).

    Article  Google Scholar 

  11. K. V. Valihura, O. V. Larina, P. I. Kyriienko, et al., Theor. Exp. Chem., 56, 404-411 (2021).

    Article  CAS  Google Scholar 

  12. S. Ardizzone, C. L. Bianchi, M. Fadoni, and B.Vercelli, Appl. Surf. Sci., 119, 253-259 (1997).

    Article  CAS  Google Scholar 

  13. D. G. Cantrell, L. J. Gillie, A. F. Lee, and K. Wilson, Appl. Catal. A, 287, 183-190 (2005).

    Article  CAS  Google Scholar 

  14. J. I. Di Cosimo, V. K. Diez, M.Xu, et al., J. Catal., 178, 499-510 (1998).

    Article  Google Scholar 

  15. B. R. Strohmeier, Surf. Sci. Spectra, 3, 121-127 (1994).

    Article  CAS  Google Scholar 

  16. T. L. Barr, S. Seal, K. Wozniak, and J. Klinowski, J. Chem. Soc. Faraday Trans., 93, 181-186 (1997).

    Article  CAS  Google Scholar 

  17. L. Xu, H. Song, and L.Chou, Int. J. Hydrog. Energy, 38, 7307-7325 (2013).

    Article  CAS  Google Scholar 

  18. M. Farooq, A. Ramli, and D. Subbarao, J. Chem. Eng. Data, 57, 26-32 (2012).

    Article  CAS  Google Scholar 

  19. J. S.Valente, E. Lima, J. A. Toledo-Antonio, et al., J. Phys. Chem. C, 114, 2089-2099 (2010).

    Article  CAS  Google Scholar 

  20. M. M. Rao, B. R. Reddy, M. Jayalakshmi, et al., Mater. Res. Bull., 40, 347-359 (2005).

    Article  CAS  Google Scholar 

  21. S. K. Yun and T. J. Pinnavaia, Chem. Mater., 7, 348-354 (1995).

    Article  CAS  Google Scholar 

  22. N. Pathak, P. S. Ghosh, S. K. Gupta, et al., RSC Adv., 6, 96398-96415 (2016).

    Article  CAS  Google Scholar 

  23. N. M. Eagan, M. D. Kumbhalkar, J. S. Buchanan, et al., Nat. Rev. Chem., 3, 223-249 (2019).

    Article  CAS  Google Scholar 

  24. S. Ogo, A. Onda, Y. Iwasa, et al., J. Catal., 296, 24-30 (2012).

    Article  CAS  Google Scholar 

  25. N. V. Vlasenko, P. I. Kyriienko, K. V. Valihura, et al., Theor. Exp. Chem., 55, 43-49 (2019).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. L. V. Pysarzhevsky Institute of Physical Chemistry, NAS of Ukraine, Kyiv, Ukraine

    K. V. Valihura, P. I. Kyriienko, O. V. Larina & S. O. Soloviev

  2. Institute for Sorption and Problems of Endoecology, NAS of Ukraine, Kyiv, Ukraine

    A. K. Melnyk

Authors
  1. K. V. Valihura
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  2. P. I. Kyriienko
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  3. A. K. Melnyk
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  4. O. V. Larina
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  5. S. O. Soloviev
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Correspondence to K. V. Valihura.

Additional information

Translated from Teoretychna ta Eksperymentalna Khimiya, Vol. 57, No. 3, pp. 173-179, May-June, 2021.

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Valihura, K.V., Kyriienko, P.I., Melnyk, A.K. et al. Influence of Acid-Base Properties of Mg-Al Oxide Systems on their Catalytic Characteristics in the Process of Gas-Phase Conversion of Ethanol to 1-Butanol. Theor Exp Chem 57, 205–212 (2021). https://doi.org/10.1007/s11237-021-09689-z

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  • DOI: https://doi.org/10.1007/s11237-021-09689-z

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