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The Effect of Sulfonate Groups in the Structure of Porous Aromatic Frameworks on the Activity of Platinum Catalysts Towards Hydrodeoxygenation of Biofuel Components

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Abstract

Platinum catalysts based on porous aromatic frameworks (PAF-30 and PAF-30–SO3H) have been synthesized. Properties of the obtained catalysts have been assessed via hydrogenation of guaiacol, veratrole, and pyrocatechol at 250°С and hydrogen pressure 3.0 MPa in isopropanol medium. It has been shown that the presence of acidic sites in the catalyst significantly increases the yield of deoxygenation products. The effect of the substrate structure on the rate of its hydrodeoxygenation and the mechanism of the occurring processes have been studied.

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Funding

This study was financially supported by the Russian Science Foundation (project no. 20-19-00380).

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Correspondence to M. A. Kalinina.

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A.L. Maximov is the editor-in-chief of Petroleum Chemistry Journal. The other authors declare no conflict of interest requiring disclosure in this article.

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Translated from Neftekhimiya, 2021, Vol. 61, No. 5, pp. 692–703 https://doi.org/10.31857/S0028242121050129.

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Kalinina, M.A., Kulikov, L.A., Cherednichenko, K.A. et al. The Effect of Sulfonate Groups in the Structure of Porous Aromatic Frameworks on the Activity of Platinum Catalysts Towards Hydrodeoxygenation of Biofuel Components. Pet. Chem. 61, 1061–1070 (2021). https://doi.org/10.1134/S0965544121090115

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