Skip to main content
SpringerLink
Log in

Sargassum latifolium Extract as a Safe Corrosion Inhibitor for Aluminum in 1 M Hydrochloric Acid Medium: Surface Analysis and Biological Effect

  • Published:
Surface Engineering and Applied Electrochemistry Aims and scope Submit manuscript

Abstract

Sargassum latifolium extract was used as new extract for the protection of Al dissolution using chemical and electrochemical methods. It was extracted, tested, and its high inhibition quality with addition of 1 × 10–2 M KI at 298 K for 300 ppm in 1M hydrochloric acid was recorded. The adsorption mechanism agreed with the Temkin isotherm from the weight loss procedure. From Tafel extrapolations showed that the used extract acts as mixed inhibitor. The thermodynamic parameters were organized and clarified. The attenuated total reflectance-Fourier transform infrared spectroscopy and atomic forced microscopy were performed for the Al surface analyses and a good decrease in the surface roughness was reached. The used extract has also demonstrated a satisfying biological activity against bacterial growth.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.
Fig. 9.
Fig. 10.
Fig. 11.
Fig. 12.
Fig. 13.
Fig. 14.
Fig. 15.

Similar content being viewed by others

REFERENCES

  1. Eladio, L. and Guillen, V., Prospective of the Al industry in Venezuela and its role in building sustainable future, Ecodiseno Sostenibilidad, 2011, vol. 3, p. 175.

    Google Scholar 

  2. Polmear, I.J., Light Alloys: Metallurgy of the Light Metals, London: Edward Arnold, 1995, 3rd ed.

    Google Scholar 

  3. Raghavendra, N. and Bhat, J.I., Anti-corrosion properties of Areca palm leaf extract on aluminium in 0.5 M HCl environment, S. Afr. J. Chem., 2018, vol. 71, p. 30.

    Article  Google Scholar 

  4. Ennouri, A., Lamiri, A., and Essahli, M., Corrosion inhibition of Al in acidic media by different extracts of Trigonella foenum-graecum L. seeds, Port. Electrochim. Acta, 2017, vol. 35, no. 5, p. 279.

    Article  Google Scholar 

  5. Olawale, O., Ogunsemi, B.T., Josiah, B., Ikubanni, P., and Ogundipe, S., Optimization and modeling of Aluminum corrosion inhibition using almond (Prunus amydgdalus) fruit leaves extract as green inhibitor in HCl acidic medium, Int. J. Mech. Eng. Technol., 2018, vol. 9, no. 13, p. 1274.

    Google Scholar 

  6. James, A.O. and Akaranta, O., Corrosion inhibition of Al in 2.0 M hydrochloric acid solution by the acetone extract of red onion skin, Afr. J. Pure Appl. Chem., 2009, vol. 3, no. 12, p. 262.

    Google Scholar 

  7. El-Azaly, A.M., Influence of soybean (Glycine max) plant extract on corrosion of Al in 1 M HCl, Int. J. Electrochem. Sci., 2019, vol. 14, p. 2714.

    Article  Google Scholar 

  8. Imane, H., Mohamed, E., and Abdeslam, L., Inhibition of Al corrosion in 0.1 M Na2CO3 by Mentha pulegium, Port. Electrochim. Acta, 2019, vol. 37, no. 6, p. 335.

    Article  Google Scholar 

  9. Kadras, G. and Solmaz, R., Electrochemical investigation of barbiturates as green corrosion inhibitors for mild steel protection, Corros. Rev., 2006, vol. 24, p. 151.

    Google Scholar 

  10. Umoren, S.A., Obot, I.B., Akpabio, L.E., and Etuk, S.E., Adsorption and corrosive inhibitive properties of Vigna unguiculata in alkaline and acidic media, Pigm. Resin Technol., 2008, vol. 37, p. 98.

    Article  Google Scholar 

  11. Fouda, A.S., Etaiw, S.H., Bakr, M.M., and Shalabi, K., Ashwagandha extract as green sustainable corrosion inhibitor for Al in acidic solutions, Biointerface Res. Appl. Chem., 2021, vol. 11, no. 2, p. 9719.

    Google Scholar 

  12. Fouda, A.S., El-Gharkawy, E., Ramadan, H., and El-Hossiany, A., Corrosion resistance of mild steel in hydrochloric acid solutions by Clinopodium acinos as a green inhibitor, Biointerface Res. Appl. Chem., 2021, vol. 11, no. 2, p. 9786.

    Google Scholar 

  13. Li, Y., Zhao, P., Liang, Q., and Hou, B., Berberine as a natural source inhibitor for mild steel in 1 M H2SO4, Appl. Surf. Sci., 2005, vol. 252, p. 1245.

    Article  Google Scholar 

  14. Radojčić, I., Berković, K., Kovač, S., and Vorkapić-Furač, J., Natural honey and black radish juice as tin corrosion inhibitors, Corros. Sci., 2008, vol. 50, p. 1498.

    Article  Google Scholar 

  15. Abdallah, M., Al-Abdali, F.H., Kamar, E.M., El-Sayed, R., et al., Corrosion inhibition of Al in 1.0 M HCl solution by some nonionic surfactant compounds containing five membered heterocyclic moiety, Chem. Data Collect., 2020, vol. 28, p. 100407.

    Article  Google Scholar 

  16. Umoren, S.A., Inhibition of aluminium and mild steel corrosion in acidic medium using Gum Arabic, Cellulose, 2008, vol. 15, p. 751.

    Article  Google Scholar 

  17. Abdallah, M., Gad, E.A.M., Sobhi, M., Al-Fahemi, Jabir H., et al., Performance of tramadol drug as a safe inhibitor for aluminum corrosion in 1.0 M HCl solution and understanding mechanism of inhibition using DFT, Egypt. J. Petrol., 2019, vol. 28, no. 2, p. 173.

    Article  Google Scholar 

  18. Fouda, A.S., Tilp, A.H., and Al-Bonayan, A.M., Conocarpus erectus extract as an eco-friendly corrosion inhibitor for Al in hydrochloric acid solution, Biointerface Res. Appl. Chem., 2021, vol. 10, no. 3, p. 10325.

    Google Scholar 

  19. Al-Abdali, F.H., Abdallah, M., and El-Sayed, R., Corrosion inhibition of aluminum using nonionic surfactant compounds with a six membered heterocyclic ring in 1.0 M HCl solution, Int. J. Electrochem. Sci., 2019, vol. 14, p. 3509.

    Article  Google Scholar 

  20. Fouda, A.S., Abd El-Maksoud, S.A., El-Habab, A.T., and Ibrahim, A.R., Synthesis and characterization of new ethoxylated carbohydrate based surfactants for corrosion inhibition of low LCS steel in aqueous solutions, Biointerface Res. Appl. Chem., 2021, vol. 11, no. 2, p. 9382.

    Google Scholar 

  21. Singh, K., Agrawa, K.K., Mishra, V., Mubeen, U.S., et al., A review on Thevetia peruviana, Int. Res. J. Pharm., 2012, vol. 3, no. 4, p. 74.

    Google Scholar 

  22. Mohsen, M.S., Asker, S.F., Mohamed, F.M.A., and El-Sayed, O.H., Chemical structure and antiviral activity of water-soluble sulfated polysaccharides from Surgassum latifolium, J. Appl. Sci. Res., 2007, vol. 3, no. 10, p. 1178.

    Google Scholar 

  23. Yende, S.R., Harle, U.N., and Chaugule, B.B., Therapeutic potential and health benefits of Sargassum species, Pharmacogn. Rev., 2014, vol. 5, p. 1.

    Article  Google Scholar 

  24. Fouda, A.S., Abo-Shohba, R., Husien, W.M., and Ahmed, E.S., Chemical and electrochemical study on the effectively of Melilotus officinalis extract as save corrosion inhibitor for aluminum in 1 M hydrochloric acid solutions, Global J. Res. Eng., 2015, vol. 15, no. 3, p. 9.

    Google Scholar 

  25. Onuchukwu, A.I. and Adamu, A.A.I., The kinetics and mechanism of hydrogen evolution on corroding aluminum in alkaline medium, Mater. Chem. Phys., 1990, vol. 25, no. 3, p.227. https://doi.org/10.1016/0254-0584(90)90067-K

    Article  Google Scholar 

  26. Adejo, S.O., Yiase, S.G., Leke, L., Onuche, M., et al., Corrosion studies of mild steel in sulphuric acid medium by acidimetric method, Int. J. Corros. Scale Inhib., 2019, vol. 8, no. 1, p. 50.

    Google Scholar 

  27. Fouda, A.S., Rashwan, S.M., Mohammed, A.E., and Ibrahim, A.M., Salicornia begolovi as eco-friendly corrosion inhibitor for aluminum in hydrochloric acid solution, Egypt. J. Chem., 2017, vol. 60, no. 4, p. 491.

    Google Scholar 

  28. Fouda, A.S., El-Taweel, F.M., and Elgamil, M., Corrosion inhibition of aluminum in hydrochloric acid solution using some pyrazolocarbothioamide derivatives, Int. J. Electrochem. Sci., 2017, vol. 12, p. 11397. https://doi.org/10.20964/2017.12.55

    Article  Google Scholar 

  29. Nithya, A., Shanthy, P., Vijaya, N., Rathish, R.J., et al., Inhibition of corrosion of Al by an aqueous extract of beetroot (betanin), Int. J. Nano. Corros. Sci. Eng., 2015, vol. 2, no. 1, p. 1.

    Google Scholar 

  30. Nnaji, N., Nwaji, N., Mack, J., and Nyokong, T., Corrosion resistance of aluminum against acid activation: impact of benzothiazole-substituted gallium phthalocyanine, Molecules, 2019, vol. 24, p. 1.

    Article  Google Scholar 

  31. Raghavendra, N. and Bhat, J.I., Anti-corrosion properties of Areca palm leaf extract on Al in 0.5 M HCl environment, S. Afr. J. Chem., 2018, vol. 71, p. 30.

    Article  Google Scholar 

  32. Fares, M.M., Maayta, A.K., and Al-Qudah, M.M., Pectin as promising green corrosion inhibitor of Al in hydrochloric acid solution, Corros. Sci., 2012, vol. 60, p. 112.

    Article  Google Scholar 

  33. Li, X. and Deng, S., Inhibition effect of Dendrocalamus brandisii leaves extract on Al in HCl, H3PO4 solutions, Corros. Sci., 2012, vol. 65, p. 299.

    Article  Google Scholar 

  34. Diki, N.Y.S., Bohoussou, K.V., Kone, M.G.-R., Ouedraogo, A., and Trokourey, A., Cefadroxil drug as corrosion inhibitor for Al in 1 M HCl medium: Empirical and theoretical studies, IOSR J. Appl. Chem., 2018, vol. 11, no. 4, p. 24.

    Google Scholar 

  35. Ashassi-Sorkhabi, H., Shabani, B., Aligholipour, B., and Seifzadeh, D., The effect of some Schiff base on the corrosion of Al in HCl solution, Appl. Surf. Sci., 2006, vol. 252, p. 4039.

    Article  Google Scholar 

  36. El-Haddad, M.N. and Fouda, A.S., Electroanalytical, quantum and surface characterization studies on imidazole derivatives as corrosion inhibitors for Al in acidic media, J. Mol. Liq., 2015, vol. 209, p. 480.

    Article  Google Scholar 

  37. El-Katori, E., Fouda, A.S., and Mohamed, R., The synergistic impact of the aqueous Valerian extract and zinc ions for the correction protection of mild steel in acidic environment, Z. Phys. Chem., 2019, vol. 1, p. 1.

    Google Scholar 

  38. Aramaki, K. and Hackerman, N., Inhibition mechanism of medium-sized polymethyleneimine, J. Electrochem. Soc., 1969, vol. 116, no. 5, p. 568.

    Article  Google Scholar 

  39. Rajendran, A. and Karthikeyan, C., The inhibitive effect of extract of flowers of Cassia auriculata in 2 M HCl on the corrosion of Al and mild steel, J. Plant Res., 2012, vol. 2, no. 1, p. 9.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, El-Mansoura University, 35516, El-Mansoura, Egypt

    A. S. Fouda & N. M. Elbahrawi

  2. Chemistry Department, College of Science, Qassim University, Qassim, Buraydah, Saudi Arabia

    A. H. Tilp

  3. Faculty of Girls for Arts, Science and Education, Ain Shams University, Cairo, Egypt

    A. H. Tilp

Authors
  1. A. S. Fouda
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. H. Tilp
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. M. Elbahrawi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. S. Fouda.

Ethics declarations

The authors declare that they have no conflicts of interest.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Fouda, A.S., Tilp, A.H. & Elbahrawi, N.M. Sargassum latifolium Extract as a Safe Corrosion Inhibitor for Aluminum in 1 M Hydrochloric Acid Medium: Surface Analysis and Biological Effect. Surf. Engin. Appl.Electrochem. 57, 473–486 (2021). https://doi.org/10.3103/S1068375521040025

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1068375521040025

Keywords:

Search

Navigation