Abstract—
The effect of lithium on the structural-phase state of aerospace aluminum alloy 1421 of the Al–Mg–Li system prepared by rapid solidification is studied. Analysis of the composition of the surface layers of alloy samples carried out by means of nuclear reaction analysis establishes that lithium diffuses to the surface at elevated treatment temperatures and its concentration in a thin surface layer (0.1 μm) reaches 38 at %, which is 4.8 times higher than the calculated Li content in the alloy. By measuring the microhardness, strengthening of the samples is determined upon isothermal annealing at a temperature of 400°C, which is caused by the precipitation of metastable lithium-containing phases. The results of X-ray diffraction analysis indicate an increase in the fraction of Li2O2 peroxide on the foil surface upon annealing.
Similar content being viewed by others
REFERENCES
T. N. Antipova, A. A. Labutin, and A. Yu. Oleshko, Quality Management of Technological Processes (Nauchnyi Konsul’tant, Korolev, 2015), p. 165.
T. Dorin, A. Vahid, and J. Lamb, Fundamentals of Aluminum Metallurgy, Ed. by R. N. Lumley (Woodhead, Cambridge, 2018).
A. M. Kuzei, Structural Phase Transformations in Rapidly Quenched Aluminum Alloys (Belaruskaya Navuka, Minsk, 2011) [in Russian].
V. G. Shepelevich, I. A. Bushkevich, E. Wendler, and I. I. Tashlykova-Bushkevich, J. Surf. Invest.: X-Ray, Synchrotron Neutron Tech. 13, 555 (2019). https://doi.org/10.1134/S1027451019030327
L. C. Feldman and J. W. Mayer, Fundamentals of Surface and Thin Film Analysis (Elsevier, New York, 1986; Mir, Moscow, 1989).
C. Jeynes and J. L. Colaux, Analyst 141, 5944 (2016). https://doi.org/10.1039/c6an01167e
I. S. Miroshnichenko, Quenching from a Liquid State (Metallurgiya, Moscow, 1982) [in Russian].
M. Mayer, SIMNRA, a Simulation Program for the Analysis of NRA, RBS and ERDA (Am. Inst. Phys., New York, 1999).
IBANDL. https://www-nds.iaea.org/exfor/ibandl.htm.
S. Bashkin, Phys. Rev. 84, 1124 (1951). https://Doi.org/10.1103/PhysRev.84.1124
D. Abriola, A. F. Gurbich, M. Kokkoris, A. Lagoyannis, and V. Panneta, Nucl. Instrum. Methods Phys. Res., Sect. B 269, 2011 (2011). https://doi.org/10.1016/j.nimb.2011.06.002
A. F. Gurbich, Nucl. Instrum. Methods Phys. Res., Sect. B 268, 1703 (2010). https://doi.org/10.1016/j.nimb.2010.02.011
W. Wesch, J. Rensberg, M. Schmidt, and E. Wendler, J. Appl. Phys. 126, 125105 (2019). https://doi.org/10.1063/1.5116667
M. A. Abuzeid, F. M. Aly, Y. P. Antoufiev, A. T. Baranik, T. M. Nower, and P. V. Sorokin, Nucl. Phys. 45, 123 (1963). https://doi.org/10.1016/0029-5582(63)90788-0
E. Schmidt, K. Ritter, K. Gartner, and E. Wendler, Nucl. Instrum. Methods Phys. Res., Sect. B 409, 126 (2017). https://doi.org/10.1016/j.nimb.2017.03.111
Materials Project. https://materialsproject.org.
I. A. Bushkevich, V. G. Shepelevich, E. Wendler, I. I. Tashlykova-Bushkevich, N. V. Adintsov, and M. V. Kocherga, in Proceedings of 13th International Conference on Interaction of Radiation with a Solid (Minsk, 2019), p. 505.
V. G. Davydov, L. B. Ber, V. I. Elagin, M. V. Samarina, N. I. Kolobnev, and L. B. Khokhlatova, Tekhnol. Legk. Splavov, No. 1, 9 (1996).
L. A. Davis, S. K. Das, J. C. M. Li, and M. S. Zedalis, Int. J. Rapid Solid 8, 73 (1994).
I. I. Novikov, Theory of Heat Treatment of Metals (Metallurgiya, Moscow, 1978) [in Russian].
W. A. Lanford, M. Parenti, B. J. Nordell, et al., Nucl. Instrum. Methods Phys. Res., Sect. B 371, 211 (2016). https://doi.org/10.1016/j.nimb.2015.10.052
N. N. Greenwood and A. Earnshaw, Chemistry of the Elements (Butterworth-Heinemann, Oxford, 1998).
I. A. Bushkevich and V. G. Shepelevich in Proceedings of 12th International Conference on Interaction of Radiation with a Solid (Minsk, 2017), p. 211.
I. I. Tashlykova-Bushkevich, Vacuum 78, 529 (2005). https://doi.org/10.1016/J.VACUUM.2005.01.080
I. I. Tashlykova-Bushkevich, J. Alloys Compd. 478, 229 (2009). https://doi.org/10.1016/j.jallcom.2008.12.006
V. V. Likutin, A. V. Krainikov, and G. E. Thompson, Fiz. Met. Metalloved. 97, 58 (2004).
A. V. Krainikov, Poroshk. Metall., Nos. 7–8, 34 (2010).
P. Yu. Kikin, V. N. Perevezentsev, and E. E. Rusin, Phys. Met. Metallogr. 118, 180 (2015).
I. I. Tashlykova-Bushkevich, V. G. Shepelevich, M. Amati, L. Gregoratti, and M. Kiskinova, J. Surf. Invest.: X-Ray, Synchrotron Neutron Tech. 14, 66 (2020).
I. N. Fridlyander, V. S. Sandler, and T. I. Nikol’skaya, Metalloved. Term. Obrab. Met., No. 2, 20 (1983).
A. I. Vorob’ev, Sb. Ref. Nauchno-Issled. Opytno-Konstrukt. Rabot, Ser. 9:53. Metall. 3 (3), 43 (2007).
A. F. Dresvyannikov and M. E. Kolpakov, Vestn. Kazan. Tekhnol. Univ. 19 (9), 36 (2016).
P. Yu. Kikin, V. N. Perevezentsev, E. E. Rusin, and N. V. Zemlyakova, Metalloved. Term. Obrab. Met., No. 8, 43 (2012).
P. Yu. Kikin, V. N. Perevezentsev, and E. E. Rusin, Phys. Met. Metallogr. 118, 180 (2015).
T. Schoeberl and S. Kumar, J. Alloys Compd. 255, 135 (1997). https://doi.org/10.1016/S0925-8388(96)02818-6
Y. Minamino, T. Yamane, and H. Araki, Metall. Mater. Trans. A 18, 1536 (1987). https://doi.org/10.1007/BF02646667
M. S. Udyavar and E. S. Dwarakadasa, J. Mater. Sci. Lett. 11, 490 (1992). https://doi.org/10.1007/BF00731114
J. M. Papazian and R. L. Schulte, Metall. Mater. Trans. A 21, 39 (1990). https://doi.org/10.1007/BF02656422
I. A. Bushkevich, A. V. Borodyn, Yu. E. Fishkina, and I. I. Tashlykova-Bushkevich in Proceedings of the VIII International Conference on Actual Problems of Solid State Physics (Minsk, 2018), Vol. 1, p. 134.
Yu. Buranova, V. Kulitskkiy, M. Peterlechner, A. Mogucheva, R. Kaibyshev, S. V. Divinski, and G. Wilde, Acta Mater. 124, 210 (2017). https://doi.org/10.1016/j.actamat.2016.10.064
R. Kaibyshev, K. Shipilova, F. Musin, and Y. Motohashi, Mater. Sci. Technol. 21, 408 (2005). https://doi.org/10.1179/174328405X36610
R. K. Islamgaliev, N. F. Yunusova, R. Z. Valiev, N. K. Tsenev, V. N. Perevezentsev, and T. G. Langdon, Scr. Mater. 49, 467 (2003). https://doi.org/10.1016/S1359-6462(03)00291-4
Author information
Authors and Affiliations
Corresponding authors
Additional information
Translated by D. Kharitonov
Rights and permissions
About this article
Cite this article
Stoliar, I.A., Shepelevich, V.G., Wendler, E. et al. Effect of Lithium on the Structural-Phase State of Rapidly Solidified Al–Mg–Li Alloy During Heat Treatment. J. Surf. Investig. 15, 752–758 (2021). https://doi.org/10.1134/S1027451021040194
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1027451021040194