A phosphonate–lanthanoid polyoxometalate coordination polymer: {Ce2P2W16O60L2}n zipper chains

Wenyan Wang; Natalya V. Izarova; Jan van Leusen; Paul Kögerler

doi:10.1039/D1CE00896J

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A phosphonate–lanthanoid polyoxometalate coordination polymer: {Ce₂P₂W₁₆O₆₀L₂}_n zipper chains†

Wenyan Wang,

^a Natalya V. Izarova,

*^ab Jan van Leusen

^a and Paul Kögerler

*^ab

Author affiliations

* Corresponding authors

^a Institute of Inorganic Chemistry, RWTH Aachen University, D-52074 Aachen, Germany
E-mail: natalya.izarova@ac.rwth-aachen.de, paul.koegerler@ac.rwth-aachen.de

^b Jülich-Aachen Research Alliance (JARA-FIT), Peter Grünberg Institute 6, Forschungszentrum Jülich, D-52425 Jülich, Germany

Abstract

{α₂, Image ID:d1ce00896j-t2.gif -P₂W₁₆O₆₀} polyoxotungstate cluster units featuring phenylphosphonates and Ce^III ions embedded into the segregated lacunary sites of the cluster shell organize into the first coordination polymer of a polyoxometalate functionalized by both organophosphonate and lanthanoid. Inter-cluster Ce–O [double bond, length as m-dash] W links result in double-chains, with {Ce^III₂(α₂, Image ID:d1ce00896j-t3.gif -P^V₂W^VI₁₆O₆₀)L₂} cluster units oriented alternatingly perpendicular to the chain propagation direction, akin to the protruding teeth of a zipper.

This article is part of the themed collection: Coordination Networks

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Article information

DOI: https://doi.org/10.1039/D1CE00896J
Article type: Communication
Submitted: 08 Jul 2021
Accepted: 23 Aug 2021
First published: 23 Aug 2021

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CrystEngComm, 2021,23, 5989-5993

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A phosphonate–lanthanoid polyoxometalate coordination polymer: {Ce₂P₂W₁₆O₆₀L₂}_n zipper chains

W. Wang, N. V. Izarova, J. van Leusen and P. Kögerler, CrystEngComm, 2021, 23, 5989 DOI: 10.1039/D1CE00896J

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