Abstract
In this work, hierarchical porous magnetic activated carbon aerogels (aCA)/polypyrrole (PPy) composites were synthesized by a facile and cost effective in situ oxidation polymerization. Three-dimensional (3D) interconnected porous aCA with a high specific surface area (820.1 m2 g−1) was prepared by a sol–gel process via carbonization and KOH activation by using sodium carboxymethyl cellulose (CMC) and ferric trichloride as carbon precursors and cross-linking agents. The aCA served as a good skeleton for the growth of PPy particles on the surface. Via the cooperative effect of an interconnected porous network structure from aCA and the high capacitive property provided by PPy, the aCA/PPy electrode exhibited a high specific capacitance of 433 F g−1 at a current density of 0.5 A g−1. Moreover, it also exhibited outstanding long-period cycling performance of ~ 87.2% capacitance retention after 5,000 cycles of consecutive charge/discharge tests. Additionally, the asymmetric supercapacitor demonstrated high energy density of 2.59 W h kg−1 at the power density of 1266 W kg−1. This work provides a novel path for preparing aCA/PPy composites with great potential as a candidate high performance electrode material on energy storage.
Similar content being viewed by others
References
L. Zuo, W. Fan, Y. Zhang, Y. Huang, W. Gao, T. Liu, Nanoscale 9, 4445–4455 (2017)
K. Chen, D. Xue, Nanotechnology 29, 024003 (2017)
P. Hao, Z. Zhao, L. Li, C.-C. Tuan, H. Li, Y. Sang, H. Jiang, C. Wong, H. Liu, Nanoscale 7, 14401–14412 (2015)
Y.M. Fan, W.L. Song, X. Li, L.Z. Fan, Carbon 111, 658–666 (2017)
W. Liu, X. Li, M. Zhu, X. He, J. Power Sour. 282, 179–186 (2015)
X. Tian, S. Zhu, J. Peng, Y. Zuo, G. Wang, X. Guo, N. Zhao, Y. Ma, L. Ma, Electrochim. Acta 241, 170–178 (2017)
K. Wang, N. Zhao, S. Lei, R. Yan, X. Tian, J. Wang, Y. Song, D. Xu, Q. Guo, L. Liu, Electrochim. Acta 166, 1–11 (2015)
X. Liang, K. Chen, D. Xue, Adv. Energy Mater. 8, 1703329 (2018)
Y. Zhang, L. Zuo, L. Zhang, J. Yan, H. Lu, W. Fan, T. Liu, Nano Res. 9, 2747–2759 (2016)
Y. Zhang, F. Wang, H. Zhu, L. Zhou, X. Zheng, X. Li, Z. Chen, Y. Wang, D. Zhang, D. Pan, Appl. Surf. Sci. 426, 99–106 (2017)
G. Sun, L. Ma, J. Ran, X. Shen, H. Tong, J. Mater. Chem. A 4, 9542–9554 (2016)
K. Chen, F. Liang, D. Xue, Dalton Trans. 49, 1107–1115 (2020)
K. Chen, D. Xue, Chem. Rec. 18, 282–292 (2018)
Y. Hou, L. Chen, L. Zhang, J. Kang, T. Fujita, J. Jiang, M. Chen, J. Power Sour. 225, 304–310 (2013)
R. Chen, M. Yu, R.P. Sahu, I.K. Puri, I. Zhitomirsky, Adv. Energy Mater. 10, 1903848 (2020)
T.E. Rufford, D. Hulicova-Jurcakova, K. Khosla, Z. Zhu, G.Q. Lu, J. Power Sour. 195, 912–918 (2010)
R. Farma, M. Deraman, A. Awitdrus, I. Talib, E. Taer, N. Basri, J. Manjunatha, M. Ishak, B. Dollah, S. Hashmi, Biores. Technol. 132, 254–261 (2013)
J.G. Wang, H. Liu, H. Sun, W. Hua, H. Wang, X. Liu, B. Wei, Carbon 127, 85–92 (2018)
C. Liu, J. Wang, J. Li, M. Zeng, R. Luo, J. Shen, X. Sun, W. Han, L. Wang, ACS Appl. Mater. Interfaces. 8, 7194–7204 (2016)
M. Li, J. Xue, J. Phys. Chem. C 118, 2507–2517 (2014)
H. Zhuo, Y. Hu, X. Tong, L. Zhong, X. Peng, R. Sun, Ind. Crops Prod. 87, 229–235 (2016)
G. Zu, J. Shen, L. Zou, F. Wang, X. Wang, Y. Zhang, X. Yao, Carbon 99, 203–211 (2016)
X.L. Wu, T. Wen, H.L. Guo, S. Yang, X. Wang, A.W. Xu, ACS Nano 7, 3589–3597 (2013)
Z.Y. Sui, Y.N. Meng, P.W. Xiao, Z.Q. Zhao, Z.X. Wei, B.H. Han, ACS Appl. Mater. Interfaces. 7, 1431–1438 (2015)
X. Sun, P. Cheng, H. Wang, H. Xu, L. Dang, Z. Liu, Z. Lei, Carbon 92, 1–10 (2015)
J. Yu, W. Lu, S. Pei, K. Gong, L. Wang, L. Meng, Y. Huang, J.P. Smith, K.S. Booksh, Q. Li, ACS Nano 10, 5204–5211 (2016)
C. Choi, J.A. Lee, A.Y. Choi, Y.T. Kim, X. Lepró, M.D. Lima, R.H. Baughman, S.J. Kim, Adv. Mater. 26, 2059–2065 (2014)
S. Lehtimäki, S. Tuukkanen, J. Pörhönen, P. Moilanen, J. Virtanen, M. Honkanen, D. Lupo, Appl. Phys. A 117, 1329–1334 (2014)
X. Zhang, J. Zhao, X. He, Q. Li, C. Ao, T. Xia, W. Zhang, C. Lu, Y. Deng, Carbon 127, 236–244 (2018)
Y.J. Lee, J.C. Jung, J. Yi, S.H. Baeck, J.R. Yoon, I.K. Song, Curr. Appl. Phys. 10, 682–686 (2010)
Y. Zhu, H. Hu, W.C. Li, X. Zhang, J. Power Sour. 162, 738–742 (2006)
R. Pekala, J. Farmer, C. Alviso, T. Tran, S. Mayer, J. Miller, B. Dunn, J. Non-Cryst. Solids 225, 74–80 (1998)
R. Fu, B. Zheng, J. Liu, M.S. Dresselhaus, G. Dresselhaus, J.H. Satcher Jr., T.F. Baumann, Adv. Func. Mater. 13, 558–562 (2003)
B. Wang, D. Li, M. Tang, H. Ma, Y. Gui, X. Tian, F. Quan, X. Song, Y. Xia, J. Alloy. Compd. 749, 517–522 (2018)
Z.Y. Wu, C. Li, H.W. Liang, J.F. Chen, S.H. Yu, Angew. Chem. 125, 2997–3001 (2013)
Z.Y. Wu, H.W. Liang, C. Li, B.C. Hu, X.X. Xu, Q. Wang, J.F. Chen, S.H. Yu, Nano Res. 7, 1861–1872 (2014)
P. Hao, Z. Zhao, J. Tian, H. Li, Y. Sang, G. Yu, H. Cai, H. Liu, C. Wong, A. Umar, Nanoscale 6, 12120–12129 (2014)
R. Lin, A. Li, L. Lu, Y. Cao, Carbohyd. Polym. 118, 126–132 (2015)
M. Yu, Y. Han, J. Li, L. Wang, Int. J. Biol. Macromol. 115, 185–193 (2018)
M. Xu, Y. Ao, S. Wang, J. Peng, J. Li, M. Zhai, Carbohyd. Polym. 128, 171–178 (2015)
Y. Xu, Y. Zhang, Mater. Lett. 139, 145–148 (2015)
X. Li, H. Lu, Y. Zhang, F. He, Chem. Eng. J. 316, 893–902 (2017)
D. Luo, S. Liu, F. Lin, L. Yu, J. Zhang, Solid State Ionics 321, 1–7 (2018)
J. Zhao, S. Zhang, W. Liu, Z. Du, H. Fang, Electrochim. Acta 121, 428–433 (2014)
A. Sonavane, A. Inamdar, D. Dalavi, H. Deshmukh, P. Patil, Electrochim. Acta 55, 2344–2351 (2010)
J. Deng, J. Guo, J. Li, M. Zeng, Z. Yang, Mater. Lett. 234, 35–37 (2019)
L. Wang, H. Yang, X. Liu, R. Zeng, M. Li, Y. Huang, X. Hu, Angew. Chem. Int. Ed. 56, 1105–1110 (2017)
S. Lyu, H. Chang, F. Fu, L. Hu, J. Huang, S. Wang, J. Power Sour. 327, 438–446 (2016)
X. Gong, S. Li, P.S. Lee, Nanoscale 9, 10794–10801 (2017)
G. Sun, H. Xie, J. Ran, L. Ma, X. Shen, J. Hu, H. Tong, J. Mater. Chem. A 4, 16576–16587 (2016)
W.H. Qu, Y.Y. Xu, A.H. Lu, X.Q. Zhang, W.C. Li, Biores. Technol. 189, 285–291 (2015)
G. Ma, Q. Yang, K. Sun, H. Peng, F. Ran, X. Zhao, Z. Lei, Biores. Technol. 197, 137–142 (2015)
Acknowledgements
The authors would like to thank the financial support of the Fundamental Research Funds for Central Universities (E2572017EB05) and Heilongjiang Province outstanding youth science fund (JC201301).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Yu, M., Li, Y., Xu, S. et al. Growing spherical polypyrrole nanoparticles onto the magnetic carbon aerogel for improving electrochemical performance for supercapacitors. J Porous Mater 28, 1999–2011 (2021). https://doi.org/10.1007/s10934-021-01115-y
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10934-021-01115-y