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Structural Studies of TeO2–SeO2–Na2O Glass System

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Abstract

The growth of nanocrystalization in TeO2–SeO2–Na2O glasses is achieved by the conventional heat treatment method. The influence of Na2O concentration on the physical properties of glass is evaluated. The glass transition (Tg) and onset crystallization (Tc) temperature decrease when Na2O concentration increases. Raman results show that the addition of Na2O to TeO2–SeO2 glasses may result in cleavage of Te–O–Te and Se–O–Se linkages and formation of Te\({\text{O}}_{3}^{ - }\) and Se\({\text{O}}_{3}^{ - }\) terminal groups in the glass system. FTIR results show that peaks corresponding to TeO4 units are decreased and peaks related to TeO3/TeO3 + 1 unit are increased. The crystal phases detected are TeO2, Na2Te4O9, Te3SeO8, Na2Te2O5, Na2Se2O7, NaSe2, Te0.5Se0.5, and Te3SeO8 (IV) in the glass system. FESEM revels from surface morphology that nanorods are exits in the glass samples. The nanoparticles are agglomerated into a shape of nanorod having nanosize in the range of 28.2–140 nm.

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REFERENCES

  1. Bachvarova-Nedelcheva, A., Iordanova, R., Kostov, KL., Yordanov, St., and Ganev, V., Structure and properties of a non-traditional glass containing TeO2, SeO2 and MoO3, Opt. Mater., 2012, vol. 34, pp. 1781–1787.

    Article  CAS  Google Scholar 

  2. Niyaz, A., Shintaro, M.M., Takayuki, K., and Varma, K.B.R., Nanocrystalline patterning of K3Li2Nb5O15 on TeO2 glasses by an excimer laser, J. Cryst. Growth, 2007, vol. 304, pp. 270–274.

    Article  Google Scholar 

  3. Kim, Ch., Hwan Kim, D., Han, Y.S., Chung, J.Sh., Park, S.H., Park, S., and Kim, H., Development of bismuth tellurium selenide nanoparticles for thermoelectric applications via a chemical synthetic process, Mater. Res. Bull., 2011, vol. 46, pp. 407–412.

    Article  CAS  Google Scholar 

  4. Bachvarova-Nedelcheva, A., Iordanova, R., Dimitriev, Y., and Yordanov, S., Nano crystallization in non-traditional oxide glasses, J. Univ. Chem. Tech. Metal., 2010, vol. 45, no. 1, pp. 43–46.

    CAS  Google Scholar 

  5. Sayed Yousef, El. and Badriah Al-Qaisi, Kinetics and fabrication nanocrystallization of optical tellurophosphate glasses in system as: TeO2–P2O5–ZnO–LiNbO3, J. Alloys Compd., 2012, vol. 538, pp. 193–200.

    Article  Google Scholar 

  6. Jiang, Zh.-Yu., Xie, Zh.-X., Zhang, X.-H., Xie, S.-Yu., Huang, R.-B., and Zheng, L.-S., Synthesis of α-tellurium dioxide nanorods from elemental tellurium by laser ablation, Inorg. Chem. Commun., 2004, vol. 7, pp. 179–181.

    Article  CAS  Google Scholar 

  7. Satya Gopal Rao, P., Rajesh S., and Suresh S., Structural study of TeO2–SeO2–Li2O ternary glass system using Raman and IR, Phys. Chem. Glasses: Eur. J. Glass Sci. Technol., B, 2018, vol. 59, no. 2, pp. 88–92.

  8. Kutlu, B., Kavakloglu, Suheyla, A., Miray, C., and Erçin, E.A., The TeO2–Na2O system: Thermal behavior, structural properties, and phase equilibria, Int. J. Appl. Glass. Sci., 2012, vol. 6, no. 4, pp. 406–418.

    Google Scholar 

  9. Miray, C., Ercin, E.A., and Suheyla, A., Glass formation and characterization studies in the TeO2–WO3–Na2O system, J. Am. Ceram. Soc., 2013, vol. 96, pp. 1470–1476.

    Article  Google Scholar 

  10. Pascuta, P., Pop, L., Rada, S., Bosca, M., and Culea, E., The local structure of bismuth borate glasses doped with europium ions evidenced by FT-IR spectroscopy, J. Mater. Sci. Mater. Electron., 2008, vol. 19, pp. 424–428.

    Article  CAS  Google Scholar 

  11. Satya Gopal Rao, P., Rajesh, S., and Sripada, S., Structural evaluation of TeO2–SeO2–R2O ternary glass system using Raman and IR, Emer. Mater. Res., 2015, vol. 5, no. 1, pp. 95–99.

  12. Satya Gopal Rao, P., Rajesh, S., and Sripada, S., Structural and optical properties of TeO2–SeO2–Na2O glass system, Indian J. PureAppl. Phys., 2020, vol. 58, pp. 50–62.

    Google Scholar 

  13. Ruvalcaba-Cornejo, C., Zayas, Ma.E., Castillo, S.J., and Lozada-Morales, R., Perez-Tello, Diaz, C.G., and Rincon, J.Ma., Optical and thermal analysis of ZnO–CdO–TeO2 glasses doped with Nd3+, Opt. Mater., 2011, vol. 33, pp. 823–826.

    Article  CAS  Google Scholar 

  14. Chowdari, V.R. and Kumari, P., Raman spectroscopic study of ternary silver tellurite glasses, Mater. Res. Bull., 1999, vol. 34, no. 2, pp. 327–342.

    Article  CAS  Google Scholar 

  15. Li, H., Su, Y., and Sundaran, S.K., Raman spectroscopic study of Nd-doped 10Na2O–90TeO2 glasses, J. Non-Cryst. Solids, 2001, vol. 293, pp. 402–409.

    Article  Google Scholar 

  16. Duveger, C., Bouazaoui, M., and Turrel, S., Raman spectroscopic investigations of the effect of the doping metal on the structure of binary tellurium-oxide glasses, J. Non-Cryst. Solids, 1997, vol. 220, pp. 169–177.

    Article  Google Scholar 

  17. Suresh, S., Gayathi, PavaniP., and Chadra, MouliV., ESR, optical absorption, IR and Raman studies of xTeO2 + (70 – x)B2O3 + 5TiO2 + 24R2O:1CuO (x = 10, 35 and 60 mol %; R = Li, Na and K) quaternary glass system, Mater. Res. Bull., 2012, vol. 47, pp. 724–731.

    Article  CAS  Google Scholar 

  18. Takao, S., Norio, M., and Susumu, K., Structure of GaO3/2-TeO2 glasses, J. Ceram. Soc. Jpn., 2000, vol. 108, pp. 236–240.

    Article  Google Scholar 

  19. Upender, G., Vardhani, C.P., Suresh, S., Awasthi, A.M., and Chandra, M.V., Structure, physical and thermal properties of WO3–GeO2–TeO2 glasses, Mater. Chem. Phys., 2010, vol. 121, pp. 335–341.

    Article  CAS  Google Scholar 

  20. Tatsumisago, M., Kato, S., Minami, T., and Kowada, K.Y., High-temperature structure and crystallization kinetics of Li2O–TeO2 glasses, J. Non-Cryst. Solids, 1995, vol. 192, pp. 478–481.

    Article  Google Scholar 

  21. Dimitriev, Y., Ivanova, I., and Dimitrov, V., Glass formation range in the SeO2–TeO2–V2O5–MoO3 system, J. Mater. Sci., 1986, vol. 21, pp. 142–146.

    Article  CAS  Google Scholar 

  22. Hager, I.Z. and El-Mallawany, R., Preparation and structural studies in the (70 – x) TeO2–20WO3–10Li2O–xLn2O3 glasses, J. Mater. Sci., 2010, vol. 45, pp. 897–905.

    Article  CAS  Google Scholar 

  23. Lefterova, E.D. and Angelov, P.V., Glasses from the system AgI-Ag2O-TeO2-B2O3, Phys. Chem. Glasses, 2000, vol. 41, pp. 362–364.

    CAS  Google Scholar 

  24. Siripuram, R., Satya Gopal Rao, P., and Sripada, S., Physical, optical, structural and thermal studies of xWO3 + (30 – x) As2O3 + 70TeO2 (where x = 10, 20, 30 mol %) glasses by UV-vis, Raman, IR and DSC studies, optik, Int. J. Light Electron Opt., 2020, vol. 224, p. 165450.

    Article  CAS  Google Scholar 

  25. Bachvarova-Nedelcheva, A., Iordanova, A., Kostov, K.L., Ganev, V., and Yordanov, St., Synthesis, characterization and optical properties of non-traditional tellurite-selenite glasses, Opt. Mater., 2014, vol. 36, pp. 1319–1328.

    Article  CAS  Google Scholar 

  26. Zayas, M.E., Arizpe, H., Castillo, S.J., Medrano, F., Diaz, G.C., Rincon, J.M., Romero, M., and Espinoza Beltrán, F.J., Glass formation area and structure of glassy materials obtained from the ZnO–CdO–TeO2 ternary system, Phys. Chem. Glasses, 2005, vol. 46, no. 1, pp. 46–50.

    CAS  Google Scholar 

  27. Shashwati, S., Madhvi, Sh., Kumar, V., Muthe, K.P., Satyam, P.V., Umananda Bhatta, M., Roy, M., Gaur, N.K., Gupta, S.K., and Yakhmia, J.V., Chlorine gas sensors using one-dimensional tellurium nanostructures, Talanta, 2009, vol. 77, pp. 1567–1572.

    Article  Google Scholar 

  28. Satya Gopal Rao, P., Rajesh, S., and Suresh, S., Impedance analysis of TeO2–SeO2–Li2O nano glass system, Resul. Phys., 2019, vol. 13, p. 102133.

    Article  Google Scholar 

  29. Deshpande, V.K. and Ramesh Taikar, N., Effect of cerium oxide addition on electrical and physical properties of alkali borosilicate glasses, Mater. Sci. Eng. B, 2010, vol. 172, pp. 6–8.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Physics, Gokaraju Rangarju Institute of Engineering and Technology, 500090, Bachupally, Kukatpally, Telangana, India

    P. Satya Gopal Rao

  2. Department of Physics, Jawaharlal Nehru Technological University College of Engineering, 505501, Nachupally (Kondagattu), Kodimyal Mandal, Telangana, India

    K. Venkatehwarlu, Rajesh Siripuram & Suresh Sripada

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Satya Gopal Rao, P., Venkatehwarlu, K., Siripuram, R. et al. Structural Studies of TeO2–SeO2–Na2O Glass System. Glass Phys Chem 47, 308–320 (2021). https://doi.org/10.1134/S1087659621040155

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