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Dominant nature of 7-hydroxy 4-methyl coumarin dye on thermal, fluorescence and antimicrobial properties of PVA/OMS blend films

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Abstract

This article focused on the fabrication of 7-hydroxy 4- methyl coumarin (7H4MC) dye doped Polyvinyl alcohol/Oxidized Maize Starch (PVA/OMS) blend films by employing user friendly solvent casting technique. The thermal stability, crystallanity, surface morphology and optical properties of the films were investigated by using Thermogravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC), X-ray Diffraction (XRD), Atomic Force Microscopy (AFM), Fluorescence (FL) and Ultraviolet–Visible (UV–Vis) Spectroscopy respectively. The TGA and DSC results illustrate that the blend films are thermally stable and miscible over the entire composition. The XRD analysis confirmed the semi crystalline nature of all the obtained films with the intense peak at 2θ = 19. 49°. The AFM topographic images had shown a smoother and homogeneous surface at the higher weight percentage of 7H4MC of blend films. The UV–Visible spectra display the absorption peaks at 325 nm for control PVA/OMS and two peaks at 329 nm, 370 nm arises after doping of 7H4MC in PS blend associated with π-π* electronic transition may be due to the charge transfer (CT) groups. The optical band gap is reduced on the addition of 7H4MC dye in the control blend. The fluorescence spectra revealed that the fabricated films exhibited good blue light emission under ultraviolet light and shows maximum fluorescence emission at 442 nm for 0.008 wt. % of 7H4MC. Moreover PSC blend films exhibited superior antimicrobial properties as compare to control blend film. Hence, the obtained outcomes are suggested that the PVA/OMS (PSC) blend films are appropriate materials for optical and biological application.

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Acknowledgements

The authors are grateful for instrumental facilities provided by University Scientific Instruments Centre (USIC), DST Sophisticated Analytical Instrument Facilities (SAIF), DST PURSE Phase II project (Program Grant No. SR/PURSE PHASE-2/13), Karnataka University, Dharwad, Karnataka, India. The authors express their heartfelt gratitude to Mr. Mahantesh Kurbet, Manager, Quality Control Department, Millennium Starch India, Pvt. Ltd., Athani, Karnataka, India, for a generous gift of oxidized maize starch. One of the author, Mr. Vishram D. Hiremani, would like to thank Karnatak University, Dharwad, Karnataka, India. for providing University Research Studentship. 

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Authors and Affiliations

  1. P G Department of Studies in Chemistry, Karnatak University, 580003, Dharwad, India

    Vishram D. Hiremani, Tilak Gasti, Praveen K. Bayannavar & Ravindra B. Chougale

  2. Department of Physics, Karnatak University, 580003, Dharwad, India

    Mallikarjun H. Anandalli & R. F. Bhajantri

  3. Department of Biotechnology and Microbiology, Karnatak University, 580003, Dharwad, India

    Shruti Dixit & Shyam Kumar Vootla

  4. Department of Chemistry, Karnatak Science College, 580001, Dharwad, India

    Saraswati P. Masti

  5. Department of Computer Science, Maharani Cluster University, Bangalore, 560001, India

    Bhagyavana. S. Mudigoudra

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  1. Vishram D. Hiremani
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Hiremani, V.D., Anandalli, M.H., Gasti, T. et al. Dominant nature of 7-hydroxy 4-methyl coumarin dye on thermal, fluorescence and antimicrobial properties of PVA/OMS blend films. J Polym Res 28, 353 (2021). https://doi.org/10.1007/s10965-021-02720-w

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