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Superhydrophobic Myristic Acid/TiO2-Nickel Coating with Improved Corrosion Inhibition Property Created by Facile Electrodeposition and Modification Methods

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Abstract

In this article, nickel (Ni) coating was constructed on brass substrate by a simple electrodeposition technique, and myristic acid/TiO2 composite (MTC) modifier was used to modify Ni coating. The chemical composition and surface morphology of MTC confirm that myristic acid (MA) was successfully grafted on TiO2 nanoparticles. As a comparison, the structures of the Ni coatings were modified by MTC or MA. We found that both modified Ni coatings exhibit strong durability, self-cleaning and superhydrophobicity ability and have good prospect of decontamination. After Ni coating had been modified by MTC, the water contact angle and sliding angle of MTC-Ni were > 170° and < 5°, respectively. In addition, the MTC-Ni coating shows improved corrosion resistance, which can effectively retard the corrosion of brass. This novel and facile electrodeposition-modification route is believed to be widely applied to preparing superhydrophobic surfaces on metallic materials.

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Acknowledgements

This research was supported by the Natural Science Foundation of Chongqing (No. cstc2020jcyj-msxmX0826), the Opening Project of Material Corrosion and Protection Key Laboratory of Sichuan province (No. 2021CL15), the Research Project on Higher Education Teaching Reform of Chongqing Three Gorges University (No. JGYB2108), Undergraduate Training Program for Innovation and Entrepreneurship of Chongqing Three Gorges University (No. 2021010), and the Science and Technology Research Program of Chongqing Municipal Education Commission (Nos. KJQN201901228, KJQN201901223, KJQN202001234). The authors also acknowledge the Chongqing Key Laboratory of Water Environment Evolution and Pollution Control in the Three Gorges Reservoir for supplying the equipment for the work.

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Authors and Affiliations

  1. Key Laboratory of Water Environment Evolution and Pollution Control in Three Gorges Reservoir, School of Environmental and Chemical Engineering, Chongqing Three Gorges University, Chongqing, 404100, China

    Xin Zhang, Huawei Yin, Jianting Tang, Chuanbo Hu & Tingzhen Li

  2. Department of Chemistry, Hong Kong Baptist University, Hong Kong, 999077, China

    Chuanbo Hu

  3. Material Corrosion and Protection Key Laboratory of Sichuan province, Zigong, 643000, China

    Chuanbo Hu

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  1. Xin Zhang
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  2. Huawei Yin
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Correspondence to Chuanbo Hu or Tingzhen Li.

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Zhang, X., Yin, H., Tang, J. et al. Superhydrophobic Myristic Acid/TiO2-Nickel Coating with Improved Corrosion Inhibition Property Created by Facile Electrodeposition and Modification Methods. JOM 73, 3111–3120 (2021). https://doi.org/10.1007/s11837-021-04814-8

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  • DOI: https://doi.org/10.1007/s11837-021-04814-8

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