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Effect of the Sterical Factor on the Kinetics of Octa(4-tert-butylphenyl)tetrapyrazinoporphyrazine in a Nitrogen-Containing Base–Dimethylsulfoxide System

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Abstract

A study is performed for the state of octa(4-tert-butylphenyl)tetrapyrazinoporphyrazine in dimethylsulfoxide. The formation of a stable complex with proton transfer is observed. It is shown that addition of n-butylamine and diethylamine to dimethylsulfoxide results in the destruction of this complex and the tetrapyrazinoporphyrazine macrocycle. The effect the tert-butyl substituents in octaphenyltetrapyrazinoporphyrazine have on the kinetic parameters of the process is established.

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Funding

The study was performed with financial support of Council on Grants of the President of the Russian Federation (project no. МК-3863.2021.1.3).

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Authors and Affiliations

  1. Ivanovo State University of Chemical Technology, 153000, Ivanovo, Russia

    O. A. Petrov & M. V. Shilovskaya

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  1. O. A. Petrov
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  2. M. V. Shilovskaya
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Correspondence to O. A. Petrov.

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Petrov, O.A., Shilovskaya, M.V. Effect of the Sterical Factor on the Kinetics of Octa(4-tert-butylphenyl)tetrapyrazinoporphyrazine in a Nitrogen-Containing Base–Dimethylsulfoxide System. Russ. J. Phys. Chem. 95, 1569–1573 (2021). https://doi.org/10.1134/S0036024421080227

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  • DOI: https://doi.org/10.1134/S0036024421080227

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