Elsevier

Current Applied Physics

Volume 31, November 2021, Pages 132-140
Current Applied Physics

A tunable hybrid graphene-metal metamaterial absorber for sensing in the THz regime

https://doi.org/10.1016/j.cap.2021.07.020Get rights and content

Highlights

  • Design and study a high-Q tunable hybrid graphene-metal metamaterial absorber.

  • Propose an accurate circuit model for the structure based on the transmission-line theory.

  • Investigation of the proposed structure as a potential label-free sensor in the THz regime.

Abstract

In this paper, a graphene-based metamaterial absorber is proposed and investigated numerically, in which the interaction between a split ring resonator (SRR) and graphene results in a high-Q absorption. To make a better understanding of the resonance mechanism, the electric and the magnetic fields, and the surface currents at the resonance frequency are investigated. In order to ease the analysis of the structure, an equivalent circuit model is introduced using the transmission line theory, and the accuracy of the proposed model is verified by the full-wave simulation. Finally, different aspects of the designed metamaterial are discussed as a potential label-free sensor for chemical and biomedical sensing. It is shown that by using this structure, a sensor with a sensitivity of 597 GHz/RIU can be achieved.

Introduction

Metamaterials are artificially manufactured materials designed to obtain unique electromagnetic properties, which can not be found in conventional materials existing in nature. Metamaterials have enabled many amazing applications, such as negative refraction [1], super-resolution lenses [2,3], and cloaking [4]. One of the most beneficial features of metamaterials is the capability of electromagnetic absorption, which makes them a strong candidate for being used in EMC/EMI shielding [5]. Recently, using 2D materials has opened up the possibility of creating metamaterials in much smaller dimensions than conventional ones, having the capability of being dynamically tuned by biasing them using optical or electrical sources [6]. Graphene, as a 2D material, due to its high electron mobility, has a great thermal and electrical conductivity [7,8]. By controlling the electron mobility, one can manage a graphene sheet to have the desired conductivity, which can be achieved either by controlling the chemical doping or the gate voltage of graphene. Using graphene to create metamaterials, due to the compressed surface plasmon wavelength of graphene, has opened the way of absorption in the THz frequencies and fabricating compact devices in this frequency range, which was not possible with conventional materials [[9], [10], [11]].

THz absorbers are illustrated to have a great potential to be used in emitters [12], stealth applications [13], photodetectors [14], and photovoltaic [15]. Sensing is one of the most important applications of metamaterial absorbers [[16], [17], [18]], which is the basic concept of this paper. Sensing is a crucial procedure in order to provide information for biology and chemistry; hence, introducing a novel method with high sensitivity, robustness, and low cost has always been a matter of interest in recent research. A marker is required in conventional sensing methods, either physical or chemical, potentially altering the original properties of the material under test [19]. The response of a metamaterial strongly depends on the refractive index of the environment; this property can be used to develop label-free sensors. Defining an unknown analyte on the surface of the absorber and measuring the shift in the resonance frequency resulted from the change in the effective refractive index of the environment is the measurement procedure in metamaterial label-free sensors. Therefore, to reach a high sensing rate, the metamaterial is supposed to have a sharp response with a high quality factor.

Recently, there has been numerous research on the concept of label-free sensors [[20], [21], [22]], with different aspects of limitations [23]. Graphene, as discussed earlier, due to its strong dispersion, can be used to reach a narrow-band impedance matching between the free-space and the metamaterial structure, which is the main absorption procedure in this paper. A graphene-based structure is much smaller than those introduced in Refs. [[24], [25], [26]] and can be dynamically tuned to change the frequency range of the measurement. Furthermore, hybrid graphene-metal structures, due to their unique offered characteristics, hold noticeable research attention on different applications [[27], [28], [29]]. To give more illustration, based on the combination of graphene and gold slits, a tunable Fano resonator with a high quality factor is introduced in Ref. [30]. Besides, a tunable graphene-metal hybrid chiral metamaterial is proposed in Ref. [31] to generate mid-infrared circular dischroism with an intensity of more than 10%. This paper introduces a hybrid graphene-metal narrowband absorber with miniaturization in size and improvement in quality factor. The small size of the absorber brings out a localized surface plasmon resonance (LSPR), guaranteeing the appropriate function as a label-free sensor. Due to its small size, the proposed sensor provides a reliable sensing rate in the presence of small amounts of analytes. Besides, a precise circuit model is derived from the transmission line theory, showing a good agreement with the full-wave simulation results. The point in using a circuit model for the structure is that one can analyse and modify the introduced structure expeditiously by adding different components to the derived circuit model [32].

This paper is structured as follows: The properties of graphene are studied in Section 2, the structure of the absorber is introduced in Section 3, the circuit model is derived in Section 4, and the structure is investigated as a potential biosensor in Section 5.

Section snippets

Graphene conductivity

To better understand the absorber's performance, it is necessary to review graphene properties in the THz frequency range briefly. Using the Kubo formula, the surface conductivity of graphene can be derived as follows [33,34]:σ(ω,τ,μc,T)=ie2(ω+iτ1)πh̄21(ω+iτ1)0fd(ϵ)ϵfd(ϵ)ϵϵdϵ0fd(ϵ)fd(ϵ)(ω+iτ1)24ϵh̄2dϵwhere e, ω, h̄, and ϵ represent charge of electron, angular frequency, reduced Planck's constant, and the energy respectively. And fd(ϵ)=1+exp(ϵμcKBT)1 is the Fermi-Dirac

Simulation and analysis

In this paper, the combination of graphene and metal [38] is used to reach a narrowband absorption peak with a high quality factor. Using graphene makes it possible to reach absorption peaks in the THz frequency range in much smaller dimensions than metal-only resonators.

The schematic of the proposed structure is shown in Fig. 2. The unit cell consists of a substrate made of SiO2 with relative permittivity of εr = 4.41, a double-gap SRR and a slab made of gold with the conductivity of σG

Deriving the model

The interaction of graphene with metal can be explained using an appropriate circuit model [42,43]. The proposed circuit model is illustrated in Fig. 8. It consists of a series RLC circuit that models the frequency selective surface (FSS) and a short-circuited transmission line to model the substrate with the ground plane.

The input impedance of a short-circuited transmission line can be calculated using the formula given below:Zins=jZstan(ksd)in which Zs=Z0εSiO2 is the intrinsic impedance of

The label-free sensor

Metamaterial absorbers with sharp resonances are suitable candidates for label-free sensing [44,45]. By introducing an unknown analyte on top of the metamaterial structure, due to modifying the effective refractive index of the environment, a blue shift of the resonance occurs. This frequency shift can be utilized to recognize the type of analyte. One of the most challenging problems in label-free sensing is the amount of the used analyte [23]. The proposed graphene-based absorber, due to its

Conclusion

In this paper, a tunable narrow-band absorber has been introduced. Besides, it has been shown numerically that the perfect absorption can be achieved in the THz frequency range in tiny dimensions using graphene. An accurate circuit model has been proposed based on the LC behaviour of the resonance, and it has been demonstrated that the results of the full-wave simulation are in perfect agreement with the results obtained by the proposed circuit model. Furthermore, the proposed absorber has been

Declaration of competing interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Acknowledgements

The authors would like to to give their concrete acknowledgement to Erfan Seif for his helpful graphical designs.

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