Abstract
The heat treatment of a hard magnetic Fe–30Cr–16Co powder alloy is optimized by experimental design using the Statgraphics and Statistica software. The alloy is prepared by a traditional powder metallurgy procedure using domestic powders. The optimization allows us to reach magnetic hysteretic properties (remanence Br, coercive force HcB, maximum energy product (BH)max) for the ternary alloy free from any additional alloying elements, which are higher than those for an industrial YuNDK24 alloy (GOST 17809–71) with a cobalt content higher by 30%.
Similar content being viewed by others
REFERENCES
H. Kaneko, M. Homma, and K. Nakamura, “New ductile permanent magnet of Fe–Cr–Co system,” Magn. Magn. Mat. AIP Conf. Proc. No. 5, 1088–1092 (1971).
I. M. Pavlov, G. N. Mekhed, L. A. Kavalerova, I. M. Milyaev, and Zh. A. Vasil’eva, “Mechanical properties of Fe–Cr–Co alloys in cast and deformable states,” in Plastic Deformation of Metals and Alloys: Collected Papers of Baikov Institute of Metallurgy, Academy of Sciences of USSR (Nauka, Moscow, 1979), pp. 208–213.
G. N. Mekhed, I. M. Milyaev, I. E. Musorina, L. A. Kavalerova, and E. D. Savkov, “Mechanical properties of the KhK15 alloy upon tension and torsion,” in Plasticity of Metals and Alloys: Collected Papers of Baikov Institute of Metallurgy, Academy of Sciences of USSR (Nauka, Moscow, 1982), pp. 90–93.
I. M. Milyaev, V. S. Yusupov, S. I. Stel’mashok, and A. I. Milyaev, “Magnetic and mechanical properties of hard magnetic 22Kh15K, 30Kh8K2M, and 30Kh20K2M2V powder alloys,” Pribory, No. 7, 34–36 (2016).
State Standard GOST 24897–81. Materials Hard Magnetic Deformable. Grades, Specification, and Testing Methods (Gos. Kom. SSSR po Standartam, Moscow, 1989).
S. Jin, G. Y. Chin, and B. C. Wonsiewicz, “A low cobalt ternary Cr–Co–Fe alloy for telephone receiver magnet use,” IEE Trans. Magn. MAG-16 (1), 139–146 (1980).
H. Kaneko, M. Homma, T. Fukunaga, and M. Okada, “Fe–Cr–Co permanent magnet alloys containing Nb and Al,” IEEE Trans. Magn. MAG-11 (5), 1440–1442 (1975).
H. Kaneko, M. Homma, K. Nakamura, and M. Miura, “Fe–Cr–Co permanent magnet alloys containing silicon,” IEEE Trans. Magn. 12, 347–348 (1972).
S. Szymura and L. Sojka, “The effect of silicon on the structure and properties of Fe–Cr–Co permanent magnet alloys,” J. Magn. Magn. Mater. 53, 379–389 (1986).
S. Sugimoto, M. Okada, Y. Ohtani, and M. Homma, “The effect of titanium on microstructure and magnetic properties of Fe–Cr–Co hard magnetic materials,” J. Appl. Phys. 5 (1), 4167–4169 (1985).
Yu. I. Kozlov and Z. A. Rakitina, “Efect of titanium on the magnetic properties and structure of iron–chromium–cobalt alloys,” Fiz. Met. Metalloved. 55 (6), 1223–1225 (1983).
Z. Ahmad, A. ul Haq, S.W. Husain, and T. Abbas, “Influence of Ti content on magnetic and microstructural properties of Fe–28Cr–15Co–3.5Mo permanent magnets,” J. Magn. Magn. Mater. 257, 397–402 (2003).
I. M. Milyaev, V. S. Yusupov, S. I. Stel’mashok, and A. I. Milyaev, “Magnetic and mechanical properties of hard magnetic Fe–Cr–Co alloys alloyed with molybdenum and tungsten,” in Innovative Metallic Materials (Magnitogorsk Gos. Tekhnol. Univ., Magnitogorsk, 2016), Chapter 3, pp. 59–75.
L. M. Magat, G. V. Ivanova, T. P. Lapina, L. V. Solina, and Ya. S. Shur, “Structural transformations and magnetic properties of a high-coercivity Fe–Cr–Co–Si alloy,” Fiz. Met. Metaloved. 40 (1), 55–60 (1975).
G. V. Ivanova, N. N. Shchegoleva, V. V. Serikov, N. M Kleinerman, E. V. Belozerov, M. A. Uimin, V. S. Gaviko, and N. V. Mushnikov, “Structural transformations in high-strength magnetically hard Fe–Cr–Co–W–Ga alloys,” Phys. Met. Metalloved. 109 (5), 438–446 (2010).
Yu. D. Ustinovshchikov, B. E. Pushkarev, D. G. Ul’yanov, and D. G. Fokin, “Microstructure and magnetic properties of the Fe60Cr30Co10 alloy,” Russ. Metall. (Metally), No. 4, 343–349 (2004).
X. H. Han, S. J. Bu, X. Wu, J. B. Sun, Y. Zhang, and C. X. Cui, “Effect of multistage aging on the microstructure, domain structure and magnetic properties of Fe–24Cr–12Co–1.5Si ribbon magnets,” J. Alloys Comp. 694, 103–110 (2017).
A. V. Korznikov, I. M. Milyaev, V. I. Aksenov, V. S. Yusupov, A. V. Korneva, and G. F. Korznikova, “Evolution of the structure, magnetic characteristics, and mechanical properties of the Fe–22Cr–15Co alloy upon rolling,” Perspekt. Mater., Spets. Vyp., 244–248 (2011).
I. M. Milyaev, D. M. Abashev, M. I. Alymov, I. N. Buryakov, V. S. Yusupov, and V. A. Zelenskii, “Magnetic properties of hard magnetic Fe–27Cr–10Co (27Kh10KA) powder alloy,” Metalloved. Term. Obrab. Mater., No. 3 (765), 17–21 (2019).
V. V. Nalimov and N. A. Chernova, Statistical Methods of Extreme Experiment Design. Statgraphics Centurion XVI (Nauka, Moscow, 1965).
I. M. Milyaev, A. I. Milyaev, and V. S. Yusupov, “Mechanism of formation of the high-coercivity state in nanostructured hard magnetic Fe–Cr–Co and Fe–Ni–Al–Co–Cu alloys,” Russ. Metall. (Metally), No. 3, 253–262 (2009).
Funding
This study was performed in terms of state assignment no. 075-00328-21-00.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by N. Kolchugina
Rights and permissions
About this article
Cite this article
Milyaev, I.M., Alymov, M.I., Milyaev, A.I. et al. Optimization of the Heat Treatment of a Hard Magnetic Fe–30Cr–16Co Powder Alloy. Russ. Metall. 2021, 892–897 (2021). https://doi.org/10.1134/S0036029521070077
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036029521070077