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Synthesis and Luminescent Property of One New Three-Dimensional {Cd4} Cluster Coordination Polymer Constructed From Multi-Carboxylate Bridging Ligand

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Abstract

Solvothermal reactions of 1-benzyl-1,2,3-triazole-4,5-dicarboxylic acid (H2btda) and 5-[4-(1-imidazolyl)phenyl]-2H-tetrazole(ipt) with Cd(Ac)2·2H2O afford one novel coordination polymer, namely, [Cd2(btda)(ipt)2]n(1). Complex 1 contains {Cd4} clusters, exhibiting a 3D metal–organic framework with pcu topology. Furthermore, Powder X-ray diffraction analysis, thermal degeneration and luminescent property of complex 1 is also investigated. Fluorescence measurement show that the target complex 1 has weak luminescent performance.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 21571093).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal University, Luoyang, 471934, Henan, China

    Xiao-Ling Li, Meng-Lei Zhao, Xu-Jia Yang, Yi-Dan Qiao & Guang-Zhen Liu

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  1. Xiao-Ling Li
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  2. Meng-Lei Zhao
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  3. Xu-Jia Yang
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  5. Guang-Zhen Liu
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Correspondence to Guang-Zhen Liu.

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Li, XL., Zhao, ML., Yang, XJ. et al. Synthesis and Luminescent Property of One New Three-Dimensional {Cd4} Cluster Coordination Polymer Constructed From Multi-Carboxylate Bridging Ligand. J Clust Sci 33, 2305–2310 (2022). https://doi.org/10.1007/s10876-021-02160-y

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