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CRYSTAL STRUCTURES OF POLYBROMIDE SALTS OF BIS(PYRIDYL)ALKANE DICATIONS

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Abstract

Reactions of solutions of 1,1′-(alkane-1,х-diyl)-bis(pyridinium) dibromides ((PyCx)Br2) with 1M Br2 in HBr result in the formation of tribromides (PyCx)(Br3)2 (x = 3 (1), 4 (2), 5 (3)) and pentabromide (PyC6)(Br5)2 (4). Their structures are investigated by X-ray crystallography. The structure of 4 contains noncovalent Br⋯Br interactions linking \(\text{Br}_{5}^{-}\) anions into two-dimensional supramolecular associates.

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Funding

The work was supported by the Russian Science Foundation (project No. 18-73-10040).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. A. Adonin

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  1. S. A. Adonin
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Correspondence to S. A. Adonin.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 7, pp. 1116-1120.https://doi.org/10.26902/JSC_id76135

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Adonin, S.A. CRYSTAL STRUCTURES OF POLYBROMIDE SALTS OF BIS(PYRIDYL)ALKANE DICATIONS. J Struct Chem 62, 1038–1042 (2021). https://doi.org/10.1134/S0022476621070076

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  • DOI: https://doi.org/10.1134/S0022476621070076

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